Abstract: A metal cored wire for submerged arc welding, the wire comprising a steel sheath with a core comprising powders of: carbon in a range of about 0.3 wt. % to about 1.2 wt. %; silicon in a range of about 0.1 wt. % to about 3.0 wt. %; manganese in a range of about 9.0 wt. % to about 30 wt. %; chromium in an amount less than about 8 wt. %; nickel in an amount less than about 6 wt. %; molybdenum in an amount less than about 6 wt. %; tungsten in an amount less than about 5 wt. %; copper in an amount less than about 4 wt. %; niobium in an amount less than about 2 wt. %; vanadium in an amount less than about 2 wt. %; titanium in an amount less than about 2 wt. %; nitrogen in an amount less than about 0.4 wt. %; boron in an amount less than about 1 wt. %; at least one of: (i) sulfur in an amount less than about 0.3 wt. %; (ii) phosphorous in an amount less than about 0.03 wt. %; or a combination thereof; and the balance with iron.

Abstract: A module assembly is provided including a fuel cell stack assembly, a heat exchanger, and a housing enclosing the fuel cell stack assembly and the heat exchanger. The heat exchanger is configured to receive process gas from an external source and output said process gas to the fuel cell stack assembly, and configured to receive process gas from the fuel cell stack assembly and output said process gas. A fuel cell power plant is provided including a module assembly with a first end, a racking structure configured to hold the module assembly, balance of plant equipment, and ducting configured to provide fluid communication between the balance of plant equipment and the first end of the module assembly. The module assembly and the racking structure are configured such that the module assembly may be removed from the racking structure in a direction away from the first end of the module assembly.

Abstract: Provided herein are hydrocarbon compositions suitable for use as a lubricant comprising sulfur between about 30 ppm to about 220 ppm, and aromatics between about 0.2 wt. % to about 3 wt. %. The present hydrocarbon compositions comprise a blend of one or more base stocks and a high-sulfur containing material and can demonstrate an improved oxidation performance as a lubricant in weighted piston deposit merits and/or by viscosity increase.

Abstract: Compositions include ether ester compounds derived from neo-alcohols, lubricating oil base stocks containing such ester compounds, and lubricating oil compositions containing such ester compounds. Methods can include making and formulating compositions containing ether ester compounds derived from neo-alcohols.

Abstract: Systems and methods are provided for improving the operation of a divided wall column for performing distillations. The systems and methods include using a separation stage in a fluid flow pathway for transporting an enriched intermediate stream from a first side of a dividing wall to a second side of a dividing wall. By using a separation stage, the benefit of transporting an enriched intermediate stream can be achieved without requiring precise knowledge of the local concentration profile on the first side of the dividing wall.

Abstract: Processes for producing alcohols from biomass are provided. The processes utilize supercritical methanol to depolymerize biomass with subsequent conversion to a mixture of alcohols. In particular the disclosure relates to continuous processes which produce high yields of alcohols through recycling gases and further employ dual reactor configurations which improve overall alcohol yields. Processes for producing higher ethers and olefins from the so-formed alcohols, through alcohol coupling and subsequent dehydration are also provided. The resulting distillate range ethers and olefins are useful as components in liquid fuels, such as diesel and jet fuel.

Abstract: A fluidization measurement system for a gas phase reactor containing a fluidized bed includes a measurement probe coupled to a sidewall of the gas phase reactor. The measurement probe includes a support bar penetrating the sidewall and extending into the fluidized bed to a distance of at least 12% of a diameter of the gas phase reactor, and a plurality of sensors arranged along a length of the support bar to obtain measurements of at least one of temperature, pressure, and electrostatic charge at multiple points within the fluidized bed. A base plant control system is in communication with measurement probe to receive and process the measurements to determine real-time physical conditions and flow patterns of the fluidized bed.

Abstract: An upgraded crude composition is provided, along with systems and methods for making such a composition. The upgraded crude composition can include an unexpectedly high percentage of vacuum gas oil boiling range components while having a reduce or minimized amount of components boiling above 593° C. (1100° F.). In some aspects, based in part on the hydroprocessing used to form the upgraded crude composition, the composition can include unexpectedly high contents of nitrogen. Still other unexpected features of the composition can include, but are not limited to, an unexpectedly high nitrogen content in the naphtha fraction; and an unexpected vacuum gas oil fraction including an unexpectedly high content of polynuclear aromatics, an unexpectedly high content of waxy, paraffinic compounds, and/or an unexpectedly high content of n-pentane asphaltenes.

Abstract: Catalytic compositions and sequential catalytic methods are generally described. in some embodiments, a composition comprises a first catalyst comprising a Cu-modified zeolite, and a second catalyst capable of a coupling reaction between (a) an intermediate resulting from a reaction of a reactant at the first catalyst, and (b) a co-reagent, wherein a rate of diffusion of the co-reagent within one or more cages and/or pores of the first catalyst is lower than a rate of diffusion of the intermediate within the one or more cages and/or pores of the first catalyst.

Abstract: A hybrid model for predicting corrosion in a system integrates a physics-based model developed using laboratory data and a machine-learning model developed using in-field data. Said hybrid model may be used, for example, in methods by: determining a physics-based measurement of corrosion using a physics-based model for a fluid's corrosion of a substrate based, at least in part on, lab-based measurements; determining a machine learning-based measurement of corrosion using a machine learning-based model for the fluid's corrosion of the substrate based, at least in part on, in-field-based measurements; and applying an ensemble method to the physics-based measurement of corrosion and the machine learning-based measurement of corrosion to yield an estimated measure of corrosion of the substrate. The hybrid model may be applied to corrosion mechanisms that occur in, for example, hydrocarbon transportation systems, hydrocarbon production systems, hydrocarbon refining systems, and alkylation systems.

Abstract: An absorbent for the selective removal of hydrogen sulfide over carbon dioxide from a fluid stream, wherein the absorbent contains an aqueous solution, comprising an amine of formula (I) and/or an amine of formula (II) wherein U—V—W is CH—O—CHR5, N—CO—CHR5 or N—CO—NR5; U?—V?—W is C—O—CR5; R1 is independently C1-C5-alkyl; R2 is selected from hydrogen and C1-C5-alkyl; R3 is independently selected from hydrogen and C1-C5-alkyl; R4 is independently selected from hydrogen and C1-C5-alkyl; R5 is selected from hydrogen, C1-C5-alkyl, (C1-C5-alkoxy)-C1-C5-alkyl, and hydroxy-C1-C5-alkyl; and x is an integer from 1 to 10. The absorbent has a reduced tendency for phase separation at temperatures falling within the usual range of regeneration temperatures for the aqueous amine mixtures and a low volatility in aqueous solvents.

Abstract: A lubricants value chain (LVC) may be managed by a computer-implemented method comprising: providing a plurality of data representative of a LVC and a plurality of hypothetical inputs representative of changes to the data into an isolated data processing environment; converting the plurality of data into one or more scenarios based upon the plurality of hypothetical inputs in the isolated data processing environment; filtering the scenarios based upon one or more properties thereof to create one or more filtered scenarios; processing the filtered scenarios to generate one or more optimized scenarios using a two-stage optimization algorithm in which first and second stages of the optimization algorithm are conducted in sequence and separately from each other, the first stage of the optimization algorithm comprising recipe optimization and the second stage of the optimization algorithm comprising value chain optimization; and determining from the optimized scenarios outputs that optimize profit within the LVC.

Abstract: Methods for building models that estimate compositional properties of a process may include (a) receiving data relating to a process; (b) cleaning the data by identifying and removing outlying data points from the data; and conditioning the data; (c) identifying inferential model parameters comprising a parameter selected from the group consisting of: a compositional property of the process as a model output that is not part of the data, operational constraints of the process, interactions between process variables of the chemical process, and any combination thereof; (d) building one or more inferential models based on the cleaned data and the inferential model parameters; and (e) outputting the one or more models and the corresponding validation metric.

Abstract: Disclosed are zeolitic imidazolate framework (ZIF) compositions in which at least a portion of the ligands in its shell have been exchanged with other ligands, and methods of making such shell-ligand-exchanged ZIFs. Also disclosed is the use of such shell-ligand-exchanged ZIFs in hydrocarbon separation processes.

Abstract: An elevated target amount of electrolyte is used to initially fill a molten carbonate fuel cell that is operated under carbon capture conditions. The increased target electrolyte fill level can be achieved in part by adding additional electrolyte to the cathode collector prior to start of operation. The increased target electrolyte fill level can provide improved fuel cell performance and lifetime when operating a molten carbonate fuel cell at high current density with a low-CO2 content cathode input stream and/or when operating a molten carbonate fuel cell at high CO2 utilization.

Abstract: Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.

Abstract: Processes are provided for preparing molecular sieves. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of nonionic surfactants, anionic surfactants, sugars and combinations thereof.

Abstract: Ceramic compositions with catalytic activity are provided, along with methods for using such catalytic ceramic compositions. The ceramic compositions correspond to compositions that can acquire increased catalytic activity by cyclic exposure of the ceramic composition to reducing and oxidizing environments at a sufficiently elevated temperature. The ceramic compositions can be beneficial for use as catalysts in reaction environments involving swings of temperature and/or pressure conditions, such as a reverse flow reaction environment. Based on cyclic exposure to oxidizing and reducing conditions, the surface of the ceramic composition can be converted from a substantially fully oxidized state to various states including at least some dopant metal particles supported on a structural oxide surface.

Abstract: Processes are provided for preparing molecular sieves of framework structure MEI, TON, MRE, MWW, MFS, MOR, FAU, EMT, or MSE. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of cationic surfactants having a quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars and combinations thereof.

Abstract: An example method can comprise creating a non-linear neural network based model of a system based on historical operational data of the system and receiving first sensor data from a plurality of sensors associated with the system. Predicted next sensor data can be determined based on the received first sensor data and the non-linear network model. Second sensor data can be received from the plurality of sensors, and a measure of deviation between the predicted next sensor data and the received second sensor data is calculated. In response to the measured deviation exceeding a predefined threshold; it can be determined that a fault has occurred.