Abstract: Systems and a method for manufacturing a base stock from a hydrocarbon stream are provided. An example method includes cracking the hydrocarbon stream to form a raw product stream, separating an ethylene stream from the raw product stream, and oligomerizing the ethylene stream to form a raw oligomer stream. A Light olefinic stream is distilled from the raw oligomer stream and oligomerized the light olefinic stream with the ethylene stream. A heavy olefinic stream is distilled from the raw oligomer stream. The heavy olefinic stream is to form a hydro-processed and distilled to form the base stock.

Abstract: Gas separation modules and methods for use including an integrated adsorbent and membrane. In certain refining applications, it is paramount to obtain high purity product gases. Adsorbent beds are effective at removing certain contaminants, such as CO2, from gas streams containing product and contaminant constituents to form a product-rich stream. The integrated membrane permits a further separation of products from any unadsorbed contaminant to produce a high purity product, such as hydrogen, stream. The gas separation modules described herein include stacked, radial, and spiral arrangements. Each modules includes a configuration of feed and cross-flow channels for the collection of contaminant gases and/or high purity product gases.

Abstract: The zeolite UTD-1 may be formed under hydrothermal synthesis conditions using a directing agent that does not include a metal atom therein. Methods for synthesizing the zeolite UTD-1 may comprise: combining at least a silicon atom source and a directing agent having a structure of in an aqueous medium; forming the zeolite in the aqueous medium under hydrothermal synthesis conditions, such that the zeolite has a framework silicate with a cationic portion of the directing agent occluded within pores or channels of the framework silicate; and isolating the zeolite from the aqueous medium. The zeolite has a powder x-ray diffraction pattern with at least the following 2?scattering angles: 6.0±0.12, 7.6±0.1, 14.66±0.15, 19.7±0.15, 21.27±0.15, 22.13±0.15, 22.61±0.15, and 24.42±0.10 for a borosilicate form zeolite, or 6.0±0.12, 7.6±0.15, 14.55±0.15, 19.64±0.15, 21.01±0.20, 21.90±0.20, 22.34±0.20, and 24.38±0.20 for an aluminosilicate form zeolite.

Abstract: High temperature antioxidant additives and methods that improve a liquid fuel composition's thermal oxidative stability are disclosed. A liquid fuel composition may comprise a liquid fuel and a high temperature antioxidant additive. The high temperature antioxidant additive may comprise an indoline compound with a bicyclic ring structure, wherein the indoline compound comprises a six-membered aromatic ring and a five-membered aliphatic ring that share a carbon-carbon aromatic bond. The five-membered aliphatic ring may be heterocyclic and may comprise a nitrogen positioned in an alpha position to the six-membered aromatic ring.

Abstract: Methods are provided for forming lubricant base stocks from feeds such as vacuum resid or other 510° C.+ feeds. A feed can be deasphalted and then catalytically and/or solvent processed to form lubricant base stocks, including bright stocks that are resistant to haze formation.

Abstract: Base stocks having Group III/III+ characteristics are prepared from certain advantageous crude oils via simplified process configurations and/or under less severe process conditions. Crude oils comprising a vacuum gas oil (VGO) fraction having a ratio of a sum of paraffin content plus 1-Ring species content to multi-ring species content that is greater than or equal to about 1.5 are advantageous in this context. Other parameters such as API gravity and crude compositional ranges may also be considered for identifying advantageous crudes. In some instances, advantageous crudes are processed into Group III base stocks via a process configuration in which the crude oil is directly supplied to a hydroprocessing unit.

Abstract: Power train architectures with low-loss lubricant bearings and low-density materials are disclosed. The gas turbine used in these architectures can include a compressor section, a turbine section, and a combustor section. A generator, coupled to the rotor shaft, is driven by the turbine section. The compressor section, the turbine section, and the generator each include rotating components, at least one of the rotating components in at least one of the compressor section, the turbine section, and the generator including a low-density material. Bearings support the rotor shaft within the compressor section, the turbine section and the generator, wherein at least one of the bearings is a low-loss bearing having a low-loss lubricant.

Abstract: Methods are provided for forming noble metal catalysts comprising both platinum and a second Group VIII metal, such as palladium, with improved aromatic saturation activity. Instead of impregnating a catalyst with both platinum and another Group VIII metal at the same time, a sequential impregnation can be used, with the Group VIII metal being impregnated prior to platinum. It has been discovered that by forming a Group VIII metal-impregnated catalyst first, and then impregnating with platinum, the distribution of platinum throughout the catalyst can be improved. The improved distribution of platinum can result in a catalyst with enhanced aromatic saturation activity relative to a catalyst with a similar composition formed by simultaneous impregnation.

Abstract: A method for improving wear control, while maintaining or improving solubility and fuel efficiency, in an engine or other mechanical component lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component; and at least one metal salt of a carboxylic acid, as a minor component; wherein the metal salt of the carboxylic acid contains no sulfur or phosphorus; wherein the metal is selected from the group consisting of palladium (Pd), silver (Ag), gold (Au), zinc (Zn), and mixtures thereof; wherein the carboxylic acid is selected from the group consisting of an aliphatic carboxylic acid, a cycloaliphatic carboxylic acid, an aromatic carboxylic acid, and mixtures thereof; wherein the molar ratio of (zinc+palladium+silver+gold)/phosphorus of said formulated oil is greater than 1.0. The lubricating oils are useful in internal combustion engines.

Abstract: Heavy hydrotreated gas oil compositions are provided, along with marine fuel oil compositions and marine gas oil compositions that include a substantial portion of a hydrotreated heavy atmospheric gas oil. The hydrotreated heavy atmospheric gas oil can correspond to a gas oil with a relatively low viscosity and an elevated paraffin content in a narrow boiling range which results in a relatively high cloud point and/or pour point.

Abstract: Achieving the selective and reversible adsorption of CO2 from humid, low partial pressures streams such as the flue gas resulting from the combustion of natural gas in combined cycle power plants (4% CO2) is challenging due to the need for high thermal, oxidative, and hydrolytic stability as well as moderate regeneration conditions to reduce the energy of adsorption/desorption cycling. Appending cyclic primary, secondary diamines, exemplified by 2-(aminomethyl)piperidine (2-ampd), to the metal-organic frameworks Mg2(dobpdc) (dobpdc4?=4,4-dioxidobiphenyl-3,3-dicarboxylate), Mg2(dotpdc) (dotpdc4?=4,4?-dioxido-[1,1?:4?,1?-terphenyl]-3,3?-dicarboxylate) or Mg2(pc-dobpdc) (pc-dobpdc4?=dioxidobiphenyl-4,4?-dicarboxylate) produces adsorbents of the classes EMM-44, EMM-45, and EMM-46, respectively, that display step-shaped adsorption of CO2 at the partial pressures required for 90% capture from natural gas flue gas at temperatures up to or exceeding 60° C.

Abstract: Marine fuel oil compositions are provided that exhibit unexpectedly high cetane numbers after addition of a cetane improver. Methods of making such compositions are also provided. The unexpected nature of the marine fuel oil compositions is based in part on the ability to achieve a substantial improvement in estimated cetane number by addition of a cetane improver to a hydrocarbonaceous composition with a natural estimated cetane number of less than 35. These unexpectedly high increases in estimated cetane number for fuels or fuel blending components with low natural estimated cetane numbers can allow for production of fuel compositions with desirable combustion characteristics while also maintaining a higher level of aromatic compounds and/or reducing or minimizing the amount of distillate boiling range components in the fuel or fuel blending component.

Abstract: The present disclosure provides a grease composition with improved water resistance and mechanical stability at high-temperatures, including: at least one base oil; a water insoluble thickener; and a low molecular weight thixotropic polyamide composition having molecular weight distribution characteristics meeting the requirement described by the relationship: ( A + D ) ( B + C ) ? 0.05 where A=the % mass of the polyamide composition with a molecular weight greater than 1700 AMU; B=the % mass of the polyamide composition with a molecular weight between 1100 AMU and 1300 AMU; C=the % mass of the polyamide composition with a molecular weight between 700 AMU and 1000 AMU; and D=the % mass of the polyamide composition with a molecular weight of 600 AMU or lower (determined by GPC). The grease composition of the present disclosure provides a less than 50 penetration point change as determined by ASTM-D7342, a less than 10 mg weight loss as determined by ASTM-D4170, or both.

Abstract: Compositions corresponding to marine diesel fuels, fuel oils, jet fuels, and/or blending components thereof are provided that include at least a portion of a natural gas condensate fraction. Natural gas condensate fractions derived from a natural gas condensate with sufficiently low API gravity can provide a source of low sulfur, low pour point blend stock for formation of marine diesel and/or fuel oil fractions. Natural gas condensate fractions can provide these advantages and/or other advantages without requiring prior hydroprocessing and/or cracking.

Abstract: Compositions corresponding to marine diesel fuels, fuel oils, jet fuels, and/or blending components thereof are provided that include at least a portion of a natural gas condensate fraction. Natural gas condensate fractions derived from a natural gas condensate with sufficiently low API gravity can provide a source of low sulfur, low pour point blend stock for formation of marine diesel and/or fuel oil fractions. Natural gas condensate fractions can provide these advantages and/or other advantages without requiring prior hydroprocessing and/or cracking.

Abstract: Fuel compositions for advanced combustion engines that include a naphtha boiling range portion are provided, where the fuel compositions can have a reduced ignition delay and/or an improved derived cetane number. The improved combustion properties can be achieved by adding a portion of a light naphtha (boiling range) composition to a heavy naphtha boiling range composition. The addition of up to about 10 vol % of a light naphtha composition to a heavy naphtha composition can result in a mixture having a reduced ignition delay relative to the heavy naphtha composition.

Abstract: Systems and methods are provided for upgrading catalytic slurry oil. The upgrading can be performed by deasphalting the catalytic slurry oil to form a deasphalted oil and a residual or rock fraction. The deasphalted oil can then be hydroprocessed to form an upgraded effluent that includes fuels boiling range products.

Abstract: Systems and methods are provided for improving the processing of heavy or challenged feeds in a refinery based on integrated use of deasphalting, coking, and hydroprocessing. An optional fluid catalytic cracking unit can be included in the integrated system to allow for further improvements. The improved processing can be facilitated based on a process configuration where the vacuum resid fractions and/or other difficult fractions are deasphalted to generate a deasphalted oil and a deasphalter residue or rock fraction. The deasphalted oil can be passed into a hydroprocessing unit for further processing. The rock fraction can be used as the feed to a coking unit. Although deasphalter residue or rock is typically a feed with a high content of micro carbon residue, a high lift deasphalting process can allow a portion of the micro carbon residue in the initial feed to remain with the deasphalted oil.

Abstract: A petroleum desalting process is improved by introducing the an alkaline compound such as sodium carbonate into the water phase, preferably in the vicinity of the water/oil interface which forms between the oil and water layers. This makes the rapid and effective separation of the oil and water phases from the emulsion layer possible.

Abstract: A petroleum desalting process in which the role played by the oil/bulk-resolved-water interface in the dehydration of the stabilized emulsion which forms in the desalter is recognized. The desalting process is improved by introducing the demulsifier and chemical high voltage electrodes. Water droplets in the mixture coalesce and settle towards the bottom of the vessel. A stabilized emulsion layer formed from the oil and the water with additives into the water phase and/or injecting chemical additives directly in the vicinity of the water/oil interface. This improved methodology that makes the rapid and effective delivery of chemical demulsifiers to the rag layer and/or oil/bulk-resolved-water interface possible. In operation, the desalting is carried out by mixing a crude oil to be desalted with water and passing the mixture of oil and water to the desalter vessel.