Abstract: This disclosure provides improved processes for converting benzene/toluene via methylation with methanol/dimethyl ether for producing, e.g., p-xylene. In an embodiment, a process utilizes a methylation catalyst system comprising a molecular sieve catalyst and an auxiliary catalyst. The auxiliary catalyst comprises a metal element selected from Group 2, Group 3, the lanthanide series, the actinide series, and mixtures and combinations thereof. The auxiliary catalyst may comprise the oxide of the metal element. Deactivation of the molecular sieve catalyst can be reduced with the inclusion of the auxiliary catalyst in the methylation catalyst system.

Abstract: Communication networks, relay nodes for communication networks, and methods of transmitting data among a plurality of relay nodes utilizing non-dispersive guided acoustic waves are disclosed herein. The communication networks include an elongate tubular body and a wireless data transmission network including a plurality of relay nodes. The relay nodes include an electro-acoustic transmitter array and an electro-acoustic receiver. The methods include inducing a first acoustic wave within the elongate tubular body with a first relay node, conveying the first acoustic wave along the elongate tubular body to a second relay node, and receiving the first acoustic wave with the second relay node. The methods further include inducing a second acoustic wave within the elongate tubular body with the second relay node, conveying the second acoustic wave along the elongate tubular body to a third relay node, and receiving the second acoustic wave with the third relay node.

Abstract: Processes and systems for producing isomeric mixtures of aromatic amine monomers from aromatic feeds. An example process for producing isomeric mixtures of aromatic amine monomers from aromatic feeds may include nitrating at least a portion of an aromatic feed to produce a mixture of nitrated aromatic compounds. The example process may further include hydrogenating at least a portion of the nitrated aromatic compounds to produce an isomeric mixture of aromatic amine monomers. The example process may further include processing the isomeric mixture of aromatic amine monomers to form a product selected from an aromatic compound with a different functional group than the aromatic amine monomers, a polymerized product, or a reaction product of the aromatic amine monomers and H2S.

Abstract: The present invention relates to ferrous alloys with high strength, cost-effective corrosion resistance and cracking resistance for refinery service environments, such as amine service under sweet or sour environments. More specifically, the present invention pertains to a type of ferrous manganese alloyed steels for high strength and cracking resistance and methods of making and using the same.

Abstract: The present invention relates to ferrous alloys with high strength, cost-effective corrosion resistance and cracking resistance for refinery service environments, such as amine service under sweet or sour environments. More specifically, the present invention pertains to a type of ferrous manganese alloyed steels for high strength and cracking resistance and methods of making and using the same for applications including, but not limited to, amine units used in oil and gas production, petroleum refining, and chemical production.

Abstract: A remote survey system includes an unmanned surface vehicle that includes a body, a propulsion system coupled to the body to provide mobility to the unmanned surface vehicle to traverse a surface of a waterbody, and a thickness detection assembly mounted to a hull of the body and including one or more thickness detection cameras. A central computer system is located at a command center and in wireless communication with the unmanned surface vehicle via a communication module. The one or more thickness detection cameras are positioned to obtain one or more images or videos of an air-oil-water interface on the surface of the waterbody, and a thickness of a released substance present on the surface of the waterbody is determined based on the one or more images or videos of the air-oil-water interface.

Abstract: A method of assigning an octane number to a sample fuel based on the knock intensities obtained from a plurality of reference fuels each having a different assigned octane number while operating an engine at an established compression ratio. The knock intensities obtained from the plurality of reference fuels are plotted relative to the assigned octane numbers of the fuels. A line is fit to the plotted knock intensities. The octane number for a sample fuel is assigned based on the knock intensity obtained for the sample fuel, the knock intensity obtained from a prototype fuel having an assigned octane number, and the fitted line. In embodiments, an R squared value is obtained for the fitted line and compared with a minimum acceptable R squared value and the fitted line is validated if the R squared value is at least the minimum acceptable R squared value.

Abstract: A method of producing bifunctional catalysts by extrusion may include mixing an acid catalyst, a metal catalyst, optionally a binder, and a fluid to produce a dough; extruding the dough to form an extrudate; producing a powder from the extrudate; and calcining the powder to produce an acid/metal bifunctional catalyst. Such acid/metal bifunctional catalysts may be useful in, among other things, converting syngas to dimethyl ether in a single reactor.

Abstract: A method for detecting and analyzing olefins in petroleum by electrospray ionization mass spectrometry can include obtaining a hydrocarbon sample comprising at least about 90 wt % of saturate compounds; producing a solution comprising the hydrocarbon sample and a metal salt, the metal salt comprising a metal ion; forming olefin-metal ion complexes by electrospray ionization; and detecting the olefin-metal ion complexes using mass spectrometry.

Abstract: Systems comprising electromagnetic radiation source; dielectric contrast analysis structure comprising: bulk dielectric substance and a plurality of receptacles in the bulk dielectric substance, wherein the plurality of receptacles allow a material to flow through the receptacles from a first side of the bulk dielectric substance to a second side of the dielectric substance; first flow line connected to the first side of the bulk dielectric substance; second flow line connected to the second side of the bulk dielectric substance; flow path for the material comprising the first flow line, the plurality of receptacles, and the second flow line. A flow path for a material to flow through the receptacles; a first pressure sensor with the first flow line; a second pressure sensor with the second flow line; and an electromagnetic radiation detector, wherein the dielectric contrast analysis structure is between the electromagnetic radiation source and the electromagnetic radiation detector.

Abstract: A method of attenuating annular pressure buildup within a wellbore. The method includes accessing a wellbore, with the wellbore having an annulus disposed between first and second strings of casing. The method also includes placing a column of cement around the second string of casing generally below the first string of casing. The method further includes pumping a fluid mixture into the annulus, forming a fluid column. The fluid mixture comprises a carrier fluid, and a plurality of compressible particles dispersed in the carrier fluid. Each of the compressible particles is fabricated to partially collapse in response to thermal expansion of the fluid mixture. The method also includes placing a wellhead over the wellbore, thereby forming a trapped annulus in the wellbore. The method additionally includes at least partially sealing the annular region along at least one depth above the column of cement to inhibit vertical migration of the compressible particles.

Abstract: A method for determining the porosity of a core sample can include: saturating a core sample with a nuclear magnetic resonance (NMR) saturation fluid, wherein the core sample has a permeability of 100 milliDarcy (mD) or less, to achieve a saturated core sample; taking a NMR measurement of fluids in the saturated core sample; determining a porosity of the core sample based on a correlation between the NMR measurement and a NMR signal to fluid volume calibration.

Abstract: A method and apparatus for producing liquefied natural gas. A portion of a natural gas stream is cooled in a first heat exchanger and re-combined with the natural gas stream, and heavy hydrocarbons are removed therefrom to generate a separated natural gas stream and a separator bottom stream. Liquids are separated from the separator bottom stream to form an overhead stream, which is cooled and separated to form a recycle gas stream. The recycle gas stream is compressed. A first portion of the compressed recycle gas stream is directed through the first heat exchanger and directed to the separator as a column reflux stream. The separated to natural gas stream is used as a coolant in the first heat exchanger to thereby generate a pretreated natural gas stream, which is compressed and liquefied.

Abstract: Methods for inversion of seismic data to infer subsurface physical property parameters, comprising constructing an inhomogeneous anisotropy model and/or inhomogeneous VS/VP or VP/VS model; and inverting the seismic data in a sequential or simultaneous approach to obtain at least one subsurface physical property parameter using an elastic inversion algorithm and the inhomogeneous anisotropy model and/or inhomogeneous VS/VP or VP/VS model. Constructing an inhomogeneous anisotropy model may comprise deriving geobodies from at least one of seismic facies analysis, regional geologic information, or seismically derived earth models; and adjusting at least one of ?, ?, ?, or parameters of the elastic stiffness tensor matrix in a homogeneous anisotropy model in areas corresponding to the geobodies. Constructing an inhomogeneous VS/VP or VP/VS model may comprise deriving geobodies and adjusting values in a homogeneous VS/VP or VP/VS model in areas corresponding to the geobodies.

Abstract: An apparatus and method of storing and transporting, in a dual-use cryogenic storage tank, a cryogenic liquid having a liquefaction temperature. A first pump empties the tank of a first portion of the cryogenic liquid, thereby leaving a second portion of the cryogenic liquid in the cryogenic storage tank. A second portion of the cryogenic liquid is focused at a location on a bottom of the cryogenic storage tank. Using a second pump located at the location, the cryogenic storage tank is emptied of the second portion of the cryogenic liquid, whereby a residual portion of the cryogenic liquid is left therein. Using a focused heating structure, heat may be delivered to the location to raise the temperature of the residual portion above the liquefaction temperature, thereby vaporizing all of the residual portion.

Abstract: The hydrocarbon wells include a radioactive tracer system, a production conduit, a lift gas supply conduit, a lift gas supply system configured to provide a lift gas stream to the lift gas supply conduit, and one or more gas lift valves each being configured to selectively permit lift gas to enter the production conduit and mix with reservoir liquid therein to generate a produced fluid stream. The radioactive tracer system is configured to inject a radioactive tracer into the lift gas stream and to detect the radioactive tracer within the produced fluid stream. The methods include injecting the radioactive tracer into the lift gas stream, flowing the radioactive tracer through an open gas lift valve into the production conduit, mixing the radioactive tracer with the reservoir liquid to generate a tracer-marked liquid band within the produced fluid stream, and detecting radiation from the tracer-marked liquid band.

Abstract: A method and apparatus for producing liquefied natural gas. A portion of a natural gas stream is cooled in a heat exchanger and combined with the natural gas stream. Heavy hydrocarbons are removed from the combined natural gas stream, and the resulting separated natural gas stream is partially condensed in the first heat exchanger, with a liquid stream separated therefrom. The natural gas stream is warmed in the first heat exchanger and then is compressed and cooled. The resultant cooled compressed natural gas stream is expanded, thereby forming a chilled natural gas stream that is separated into a refrigerant stream and a non-refrigerant stream. The refrigerant stream recycled to the heat exchanger to be warmed through heat exchange with one or more process streams associated with pretreating the natural gas stream, thereby generating a warmed refrigerant stream. The warmed refrigerant stream and the non-refrigerant stream are liquefied.

Abstract: The present disclosure relates to methods and systems for sweetening natural gas may utilize a water wash to achieve a reduction in raw natural gas stream contaminants (e.g., particulate contaminants and/or chemical contaminants) and/or to recover solvent used for removing H2S and CO2 from the natural gas. For example, a method may include contacting a first natural gas stream with a first water stream in a co-current contacting system to produce a second natural gas stream and a second water stream, wherein the first natural gas stream comprises natural gas, an acid gas, and a contaminate, and wherein a concentration of the contaminate in the second natural gas stream is less than a concentration of the contaminate in the first natural gas stream; and removing at least a portion of the acid gas from the second natural gas stream.

Abstract: A method for producing a deposit resistant fluid includes combining a base stock and one or more additives to form a blended fluid configured to resist forming deposits in an oxidizing environment. The base stock has a viscosity index of at least 80, and either a kinematic viscosity at 40° C. of at least 320 cSt or a kinematic viscosity at 100° C. of at least 14 cSt. The base stock includes greater than or equal to about 90 wt % saturates, less than or equal to about 10 wt % aromatics, and a sum of terminal/pendant propyl groups and terminal/pendant ethyl groups of at least 1.7 per 100 carbon atoms.

Abstract: Methods comprising contacting a residue comprising paraffinic, olefinic, and aromatic hydrocarbons with a polar solvent under conditions effective to extract at least a portion of the aromatic hydrocarbons from the residue into the polar solvent, thereby generating: an extract phase comprising the portion of aromatic hydrocarbons and the polar solvent; and, a raffinate phase comprising a majority of the paraffinic and olefinic hydrocarbons.