Abstract: A self-wrapping textile sleeve that is abrasion, arc and water resistant and method of construction thereof is provided. The sleeve includes a wall having opposite edges extending in a lengthwise direction along a central longitudinal axis of the sleeve between opposite ends. The opposite edges overlap one another to form an inner tubular cavity. The wall has warp yarns extending in the lengthwise direction generally parallel to the central longitudinal axis and weft yarns extending generally transversely to the longitudinal axis between the opposite edges. The warp and weft yarns include expanded PTFE yarns, and the weft yarns further include heat-settable thermoplastic yarns. The heat-settable polymeric yarns impart a bias on the wall to bring the opposite edges into their overlapping relation.