Abstract: Copper oxide particles having particular starting size and surface area characteristics can be processed by heat and milling to achieve sizes and particle size distributions that give the copper oxide properties as an infrared reflective pigment without addition of other metals or oxides.
Type:
Grant
Filed:
March 19, 2015
Date of Patent:
June 20, 2017
Assignee:
Ferro Corporation
Inventors:
Elena D. Milliken, Terry J. Detrie, George E. Sakoske
Abstract: The present subject matter provides a transitional layer and related methods, used to increase the transmission or reflection of light between two mediums having different indices of refraction. The transitional layer is disposed between the two mediums and the transmission or reflection of light is increased by the interaction of light with the transitional layer. The transitional layer has light scattering particles dispersed therein, a single-layer gradient index-of-refraction, a multi-layer gradient index-of-refraction, alternating layers of high and low index-of-refraction, or a combination thereof, in order to increase the transmission or reflectance of light between the two mediums.
Type:
Grant
Filed:
August 1, 2013
Date of Patent:
June 6, 2017
Assignee:
Ferro Corporation
Inventors:
George E. Sakoske, Enos A. Axtell, III, James D. Walker
Abstract: Various agents for improving adhesion of cold end coatings on glass surfaces are described Also described are agents for improving bonding between cold end coatings and organic inks. And, methods and related detection solutions for detecting the presence of cold end coatings on a substrate such as a glass bottle are disclosed. Additionally, particular additives and primers are described that can be applied onto cold end coatings for improving adhesion thereto.
Type:
Grant
Filed:
January 21, 2011
Date of Patent:
May 23, 2017
Assignee:
Ferro Corporation
Inventors:
Cindy Pankiewicz, Thirumalai Duraisamy, Bertram Gardner, Ian Dudas, David C. Kapp, Enos A. Axtell, III, George E. Sakoske
Abstract: A glass composition comprising B2O3, Na2O, Al2O3, Li2O, TiO2, ZnO, Ta2O5, Nb2O3, BaO, ZrO2 and SiO2, and devoid of lead, bismuth, and vanadium. Pastes comprising the glass composition and devices including seals comprising such pastes are contemplated.
Abstract: The present subject matter provides for a multi-layer conductive trace. The trace can be formed by digital printing the individual layers and firing. The individual layers each impart functional characteristics to the conductive trace and each layer has components that can be adjusted to affect the performance characteristics of that particular layer without detrimentally affecting the performance characteristics of the remaining layers.
Type:
Grant
Filed:
July 22, 2014
Date of Patent:
February 7, 2017
Assignee:
Ferro Corporation
Inventors:
George E. Sakoske, Phil Maitland, Dietrich Speer, Frank Walter, Robert P. Blonski, Srinivasan Sridharan
Abstract: Solder can be used to wet and bind glass substrates together to ensure a hermetic seal that superior (less penetrable) than conventional polymeric (thermoplastic or thermoplastic elastomer) seals in electric and electronic applications.
Type:
Grant
Filed:
November 4, 2015
Date of Patent:
January 17, 2017
Assignee:
Ferro Corporation
Inventors:
Srinivasan Sridharan, Robert P. Blonski, Chandrashekhar S. Khadilkar, John J. Maloney
Abstract: Glasses comprising Bi203, ZnO B203 and optionally a colorant including an oxide of a metal such as iron, cobalt, manganese, nickel, copper and chromium are suitable to form hermetic seals in solar cell modules, architectural glass windows and MEMS devices. Glass frit and paste compositions suitable for flow and bonding to various substrates—glass, metal, silicon, in the temperature range of 400-500 degrees Centigrade. The broad compositional range in mole % is 25-70% Bi203, up to 65% ZnO, and 1-70% B203. Such glasses do not have batched in alumina or silica. Such glasses lack alumina and silica.
Type:
Grant
Filed:
April 15, 2011
Date of Patent:
January 10, 2017
Assignee:
Ferro Corporation
Inventors:
Srinivasan Sridharan, John J. Maloney, Chandrashekhar Khadilkar, Robert P. Blonski, David L. Widlewski
Abstract: Broadband infrared radiation is used to heat and fuse an enamel paste to form an enamel seal between at least two solid substrates such as glass, ceramic or metal.
Type:
Grant
Filed:
July 22, 2013
Date of Patent:
November 22, 2016
Assignee:
Ferro Corporation
Inventors:
John J. Maloney, Andrew M. Rohn, Jr., Chandrashekhar S. Khadilkar, Srinivasan Sridharan, Robert P. Blonski, George E. Sakoske
Abstract: Heavy-metal-free glass enamels are applied to glass and fired. After firing, the coated glass can subsequently be ion exchanged to give a chemically strengthened, decorated glass article.
Abstract: Various laser marking compositions and related methods are described. The laser marking compositions utilize one or more populations of particles having certain average particle sizes or a range of sizes. Marks or other indicia formed using the compositions and methods exhibit increased contrast, improved substrates bonding, and greater dispersability.
Type:
Grant
Filed:
July 25, 2013
Date of Patent:
November 8, 2016
Assignee:
Ferro Corporation
Inventors:
George E. Sakoske, Joseph E. Sarver, Dennis R. Gilmore, Stephen Rozwood, Sean T. Weir
Abstract: The present subject matter provides for a multi-layer conductive trace. The trace can be formed by digital printing the individual layers and firing. The individual layers each impart functional characteristics to the conductive trace and each layer has components that can be adjusted to affect the performance characteristics of that particular layer without detrimentally affecting the performance characteristics of the remaining layers.
Type:
Application
Filed:
July 22, 2014
Publication date:
June 16, 2016
Applicant:
Ferro Corporation
Inventors:
George E. Sakoske, Phil Maitland, Dietrich Speer, Frank Walter, Robert P. Blonski, Srinivasan Sridharan
Abstract: This invention relates to lead free and cadmium free copper-containing glass frits that can be used as pigments to color other glass frits or to impart color to solid substrates such as glass, ceramic or metals, or to impart color to a thermoplastic mass. The compositions comprise silica, alkali metal oxides, alkaline earth metal oxides, tin oxide and copper oxide. The resulting compositions can be used to decorate and protect automotive, beverage, architectural, pharmaceutical and other glass substrates, generally imparting a red color.
Type:
Grant
Filed:
November 7, 2014
Date of Patent:
May 10, 2016
Assignee:
Ferro Corporation
Inventors:
Enos A. Axtell, III, George E. Sakoske, Andreas Schulz, Juergen Hanich, Lothar Heck, Dietrich Speer, Martin Baumann
Abstract: Various laser marking compositions and related methods are described. The laser marking compositions include a molybdenum metal complex, a tungsten metal complex, or combinations thereof. Marks or other indicia formed on a substrate using the compositions and methods exhibit increased contrast and improved substrate bonding.
Type:
Grant
Filed:
March 1, 2013
Date of Patent:
April 26, 2016
Assignee:
Ferro Corporation
Inventors:
Joseph E. Sarver, Stephen Rozwood, George E. Sakoske, Terry J. Detrie
Abstract: This invention relates to glass and enamel compositions. The glass compositions include SiO2, Nb2O5, Na2O, B2O3, ZnO, Bi2O3, TiO2, MoO3, ZrO2, Y2O3, Al2O3, Li2O, and K2O. The glass compositions can be used to form an enamel on a substrate, for example, to decorate and/or protect the substrate.
Type:
Grant
Filed:
February 20, 2013
Date of Patent:
April 19, 2016
Assignee:
Ferro Corporation
Inventors:
Sandeep K. Singh, George E. Sakoske, David A. Klimas
Abstract: A glass-flake loaded organic sealant system is useful for sealing active layers such as those in electronic devices and solar cells.
Type:
Grant
Filed:
July 22, 2011
Date of Patent:
March 1, 2016
Assignee:
Ferro Corporation
Inventors:
Chandrashekhar S. Khadilkar, Robert P. Blonski, Srinivasan Sridharan, Jackie D. Davis, John J. Maloney, James D. Walker, Andrew M. Rohn, Jr.
Abstract: Pigment compositions are described that advantageously increase total solar reflectance. Also described are methods of making pigment compositions. The pigment compositions can contain copper oxide; copper antimony oxides, copper bismuth oxides, or combinations thereof; and alkaline earth metal oxides, early-transition metal oxides, post-transition metal oxides, metalloid (semi-metal) oxides, rare-earth metal oxides, or combinations thereof.
Abstract: Solder can be used to wet and bind glass substrates together to ensure a hermetic seal that superior (less penetrable) than conventional polymeric (thermoplastic or thermoplastic elastomer) seals in electric and electronic applications.
Type:
Grant
Filed:
July 22, 2011
Date of Patent:
December 8, 2015
Assignee:
Ferro Corporation
Inventors:
Srinivasan Sridharan, Robert P. Blonski, Chandrashekhar Khadilkar, John J. Maloney
Abstract: A green pigment is a blend of metal oxides including a [124] spinel which can contain certain combinations of lithium, sodium, cobalt, zinc, calcium, magnesium, copper, titanium, manganese, tin, and germanium, and a [134] spinel which can contain certain combinations of lithium, sodium, chromium, boron, iron, manganese aluminum, titanium, tin and germanium. The pigment lacks nickel.
Type:
Grant
Filed:
June 4, 2014
Date of Patent:
November 17, 2015
Assignee:
Ferro Corporation
Inventors:
Hans-Peter Letschert, Stephan Ludwig, Terry J. Detrie, George E. Sakoske
Abstract: Durable hermetic seals between two inorganic substrates are produced using a high-intensity electromagnetic energy source, such as laser, to heat and seal enamel layers with controlled absorption of high-intensity energy source. Durable hermetic seals incorporating electrical feedthroughs are also produced.
Type:
Grant
Filed:
April 27, 2011
Date of Patent:
October 13, 2015
Assignee:
Ferro Corporation
Inventors:
John J. Maloney, Robert P. Blonski, Chandrashekhar S. Khadilkar, Srinivasan Sridharan
Abstract: An acrylate-based curable printing medium is disclosed. Acrylates, in the form of monomers, dimers, trimers and oligomers, as well as resins, form an interpenetrating polymer network by crosslinking, which is effected by heat, and optionally peroxide curing agents. Formulations can be tailored to achieve desired properties of the cured polymer including film hardness, burnout properties, and adhesion to glass. Such properties are adjusted by manipulating the relative proportions of the acrylic monomers, oligomers and resins that are used as a ceramic medium or vehicle.
Type:
Grant
Filed:
July 17, 2014
Date of Patent:
October 6, 2015
Assignee:
Ferro Corporation
Inventors:
Terry J. Brown, Kimberly Stewart, Thirumalai Duraisamy