Patents Assigned to Ferro France - S.A.R.L.
  • Patent number: 7244502
    Abstract: The present invention provides a composition for use in forming an abrasion-resistant easy-to-clean coating on a substrate. The composition according to the invention includes a mixture of a fluorocarbon polymer component and an enamel-forming component. The enamel-forming component includes at least a first lead-free and cadmium-free glass frit. The first lead-free and cadmium-free glass frit includes from about 30% to about 50% P2O5, from about 15% to about 30% Al2O3, and from about 2% to about 40% X2O where X=Na and/or K. The present invention also provides a method of forming an abrasion-resistant easy-to-clean coating on a substrate. The method includes applying the composition according to the invention to a substrate and sintering the applied composition to fuse an abrasion-resistant easy-to-clean coating to the substrate.
    Type: Grant
    Filed: February 9, 2005
    Date of Patent: July 17, 2007
    Assignee: Ferro France - S.A.R.L.
    Inventors: Alain Aronica, David Coutouly, Damian Macaya, Remy Caisse
  • Patent number: 7005396
    Abstract: The present invention provides a composition for use in forming an enamel cover coat from which baked-on foods can be removed without the need for pyrolysis or highly alkaline cleaners. The enamel cover coat preferably exhibits no chipping or other surface defects subsequent to a 2.0 mm Plum Jam Test and an acid resistance of A or better according to ISO 2722. The composition according to the invention includes a glass component including at least a first glass frit comprising a low SiO2 glass frit. Preferably, the glass component includes a blend of the first glass frit and at least a second glass frit. Preferably, the first glass frit includes by weight from about 30% to about 45% P2O5, from about 20% to about 40% Al2O3, from about 15% to about 35% Li2O+Na2O+K2O, up to about 15% B2O3, up to about 15% MgO+CaO+SrO+BaO+ZnO, up to about 10% TiO2+ZrO2, and up to about 10% SiO2.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: February 28, 2006
    Assignee: Ferro France-S.A.R.L.
    Inventors: Sophie Espargillière, Andreas Schanné, Francois Roques
  • Publication number: 20050148722
    Abstract: The present invention provides a composition for use in forming an abrasion-resistant easy-to-clean coating on a substrate. The composition according to the invention includes a mixture of a fluorocarbon polymer component and an enamel-forming component. The enamel-forming component includes at least a first lead-free and cadmium-free glass frit. The first lead-free and cadmium-free glass frit includes from about 30% to about 50% P2O5, from about 15% to about 30% Al2O3, and from about 2% to about 40% X2O where X=Na and/or K. The present invention also provides a method of forming an abrasion-resistant easy-to-clean coating on a substrate. The method includes applying the composition according to the invention to a substrate and sintering the applied composition to fuse an abrasion-resistant easy-to-clean coating to the substrate.
    Type: Application
    Filed: February 9, 2005
    Publication date: July 7, 2005
    Applicant: Ferro France S.A.R.L.
    Inventors: Alain Aronica, David Coutouly, Damian Macaya, Remy Caisse
  • Patent number: 6896934
    Abstract: The present invention provides a composition for use in forming an abrasion-resistant easy-to-clean coating on a substrate. The composition according to the invention includes a mixture of a fluorocarbon polymer component and an enamel-forming component. The enamel-forming component includes at least a first lead-free and cadmium-free glass frit. The first lead-free and cadmium-free glass frit includes from about 30% to about 50% P2O5, from about 15% to about 30% Al2O3, and from about 2% to about 40% X2O where X=Na and/or K. The present invention also provides a method of forming an abrasion-resistant easy-to-clean coating on a substrate. The method includes applying the composition according to the invention to a substrate and sintering the applied composition to fuse an abrasion-resistant easy-to-clean coating to the substrate.
    Type: Grant
    Filed: May 14, 2001
    Date of Patent: May 24, 2005
    Assignee: Ferro France - S.A.R.L.
    Inventors: Alain Aronica, David Coutouly, Damian Macaya, Remy Caisse
  • Patent number: 6566289
    Abstract: The present invention provides a composition for use in forming a white porcelain enamel coating on aluminized or galvanized steel. The composition according to the present invention includes a solids portion including a glass component and a white pigment. The glass component includes one or more glass frits including by weight from about 30% to 50% P2O5, from about 15% to about 30% Al2O3, from about 8% to about 40% X2O where X=Na and/or K, up to about 30% TiO2, up to about 12% B2O3, up to about 10% K2O, up to about 10% ZnO, up to about 8% SiO2, up to about 7% La2O3, up to about 5% Li2O, and up to about 15% F. The white pigment include TiO2.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: May 20, 2003
    Assignee: Ferro France - S.A.R.L.
    Inventors: Alain Aronica, Emmanuel Marinho, David Coutouly, Luc Allemeersch, Christophe Reb
  • Publication number: 20030064874
    Abstract: The present invention provides a composition for use in forming an opaque porcelain enamel coating on a metal substrate. A porcelain enamel coating formed using a composition according to the invention readily adheres to metal substrates such as, for example, steel, that are degreased-only. Furthermore, such a porcelain enamel coating displays an acid resistance of A according to ISO 2722 and good easy-to-clean properties. The composition according to the invention includes a glass component including by weight from about 45% to about 55% SiO2, from about 8% to about 17% B2O3, from about 1.8% to about 17.7% SrO+BaO, from about 1.9% to about 10% Li2O, up to about 6% ZrO2, from about 2% to about 11% TiO2, from about 1.5% to about 6% K2O, from about 1% to about 4% MoO3, from about 0.3% to about 13% Na2O, up to about 2% NiO, up to about 3% Al2O3, up to about 2.9% MnO, up to about 0.8% CoO, up to about 3% MgO, up to about 5% CaO, and up to about 2% Sb2O3.
    Type: Application
    Filed: April 8, 2002
    Publication date: April 3, 2003
    Applicant: Ferro France - S.A.R.L.
    Inventors: Jean-Christophe Eckmann, Moha Ait Ali Oumoumene, Francois Roques
  • Patent number: 6475939
    Abstract: The present invention provides a composition for use in forming an adherent, brilliant white, chemically and mechanically resistant porcelain enamel coating on aluminized steel. The composition includes a self-opacifying glass frit component which includes high levels of titanium dioxide, lithium oxide, sodium oxide, and potassium oxide. The composition is able to produce a brilliant white finish on aluminized steel in one coat without the addition of titanium oxide during milling.
    Type: Grant
    Filed: November 22, 2000
    Date of Patent: November 5, 2002
    Assignee: Ferro France - S.A.R.L.
    Inventors: Thierry Souchard, Alain Aronica
  • Patent number: 6429161
    Abstract: The present invention provides a new and improved porcelain enamel coating composition for use in forming a self-cleanable coating upon aluminized steel. The coating composition comprises a glass component having a composition comprising from about 30% to about 55% SiO2, from about 11% to about 20% TiO2, from about 0% to about 10% B2O3, from about 20% to about 40% alkali metal oxides, less than about 5% rare earth metal oxides, from about 0% to about 10% CaO, from about 0% to about 10% BaO, from about 0% to about 10% MnO, from about 2% to about 12% CuO, from about 0% to about 10% Sb2O3, from about 1.5% to about 10% Fe2O3, from about 0% to about 10% SnO2, from about 0% to about 10% P2O5, less than about 2% MoO3, and less than about 5% V2O5.
    Type: Grant
    Filed: August 7, 2000
    Date of Patent: August 6, 2002
    Assignee: Ferro France S.A.R.L.
    Inventors: Thierry Souchard, Alain Aronica
  • Publication number: 20020061809
    Abstract: The present invention provides a composition for use in forming a white porcelain enamel coating on aluminized or galvanized steel. The composition according to the present invention includes a solids portion including a glass component and a white pigment. The glass component includes one or more glass frits including by weight from about 30% to 50% P2O5, from about 15% to about 30% Al2O3, from about 8% to about 40% X2O where X=Na and/or K, up to about 30% TiO2, up to about 12% B2O3, up to about 10% K2O, up to about 10% ZnO, up to about 8% SiO2, up to about 7% La2O3, up to about 5% Li2O, and up to about 15% F. The white pigment include TiO2.
    Type: Application
    Filed: August 17, 2001
    Publication date: May 23, 2002
    Applicant: Ferro France S.A.R.L.
    Inventors: Alain Aronica, Emmanuel Marinho, David Coutouly, Luc Allemeersch, Christophe Reb