Abstract: Siloxane compounds are removed from the atmospheres by silica supporting an organic sulfonic acid compound. The silica with the organic sulfonic acid compound has a specific surface area down to 500 m2/g and up to 750 m2/g and a pore volume down to 0.8 m3/g and up to 1.2 m3/g, both measured by nitrogen gas adsorption method and has a pore diameter down to 4 nm and up to 8 nm, at the peak of differential pore volume measured by nitrogen gas adsorption method. The durability of gas sensing element against siloxanes is improved.

Abstract: A gas detector comprises a gas detection unit and a filter introducing surrounding atmosphere to the gas detection unit. The filter comprises a gas-permeable organic polymer membrane having an acidic group or a basic group.

Abstract: A gas detector comprises a metal oxide semiconductor gas sensor whose resistance decreases in reducing gases and a digital information processing device that treats the output of the gas sensor and compares the output with a comparison value for gas detection. The digital information processing device extracts data representing the resistance of the gas sensor in air from the output of the gas sensor and generates the comparison value such that the larger the resistance of the gas sensor in air is, the larger the ratio between the resistance of the gas sensor in air and a resistance value corresponding to the comparison value is.

Abstract: The filter of a gas sensor comprises an inorganic porous support supporting both an organic sulfonic acid compound including sulfo group (—SO3H) and a Lewis acid having at least a metal element of transitional metal elements, Al element, Ga element, In element, Ge element, and Sn element. The Lewis acid loaded in the inorganic porous support adsorbs low concentration siloxanes. The organic sulfonic acid compound including sulfo group polymerizes adsorbed siloxanes in the filter so as not to desorb from the filter.

Abstract: A gas detector uses a MEMS gas sensor having: a substrate provided with a cavity and an insulating film over the cavity; a metal oxide semiconductor and a heater both provided on the insulating film. A drive circuit operates the heater with a predetermined period for a predetermined pulse duration in order to heat the metal oxide semiconductor. The drive circuit halts operation of the heater or elongates the period when a humidity sensor detects that the atmosphere is humid.

Abstract: A gas detector includes metal-oxide semiconductor gas sensors and their driving circuit. The gas detector stores the ratio of initial gas sensor resistance in air and that in an atmosphere including Freon gas, for the gas sensors. The gas detector learns sensor resistance in air for a gas sensor in use and detects Freon gas by comparing the sensor resistance of the gas sensor in use with the learned resistance in air divided by the ratio. When the first gas sensor has been used for a predetermined period, both the first gas sensor and a second gas sensor are used for a learning period to continue detection of Freon by the first gas sensor and to learn the resistance in air of the second gas sensor. After completion of the learning period, Freon is detected by the second gas sensor.

Abstract: A gas sensor and the drive circuit for the sensor are installed within a mobile electronic device. The gas sensor is intermittently heated to an operating temperature for detecting gases and kept at an ambient temperature for other periods. When a sensor of the mobile electronic device detects that the device is placed in a closed space, the heating of the metal oxide semiconductor is halted. When the sensor detects that the mobile electronic device has been taken out from the closed space, the heating of the metal oxide semiconductor is resumed. The poisoning of the gas sensor by siloxanes or the like is prevented.

Abstract: An electrochemical gas sensor has a planar ceramic housing having a recess, a MEA, first and second electrically conductive gas diffusion membranes, and a metal lid fixed on the housing so as to cover the recess. The MEA is provided with an ionic conductive membrane, a first electrode on a surface of the membrane, and a second electrode on the opposite surface of the membrane. The first electrically conductive gas diffusion membrane is electrically connected to the first electrical connection. The second electrically conductive gas diffusion membrane is electrically connected to the second electrical connection. The lid presses the second electrically conductive gas diffusion membrane toward the MEA, and in the lid or in the bottom of the housing, a gas inlet is provided. The electrochemical gas sensor is easily made compact, small in the variations in the performances, and easily installed on a print circuit board.

Abstract: The output of the electrochemical gas sensor is amplified, and the ambient temperature is measured by means of a temperature sensor. When the ambient temperature is above or equal to a predetermined temperature, a standard value is generated and stored and is increased when the output of the amplification circuit is larger than the standard value, and a gas is detected according to the difference between the output of said amplification circuit and the standard value.

Abstract: An electrochemical gas sensor has a planar ceramic housing having a recess, a MEA, first and second electrically conductive gas diffusion membranes, and a metal lid fixed on the housing so as to cover the recess. The MEA is provided with an ionic conductive membrane, a first electrode on a surface of the membrane, and a second electrode on the opposite surface of the membrane. The first electrically conductive gas diffusion membrane is electrically connected to the first electrical connection. The second electrically conductive gas diffusion membrane is electrically connected to the second electrical connection. The lid presses the second electrically conductive gas diffusion membrane toward the MEA, and in the lid or in the bottom of the housing, a gas inlet is provided. The electrochemical gas sensor is easily made compact, small in the variations in the performances, and easily installed on a print circuit board.

Abstract: A CO sensor includes a solid electrolyte substrate, a sensing electrode, and a reference electrode, and outputs electromotive forces in accordance with CO concentrations. The sensing electrode and the reference electrode are provided on the same surface of the solid electrolyte substrate. The sensing electrode contains a metal oxide such as Bi2O3 that generates a positive electromotive force response when coming into contact with CO. The reference electrode contains a metal oxide such as CeO2 that generates a negative electromotive force response when coming into contact with CO.

Abstract: A gas is detected using a MEMS gas sensor. The electrical power to a heater in the gas sensor is changed between a low level, a high level suitable for detection of detection target gas, and a 0 level, and, therefore, poisonous gas is evaporated or oxidized at the low level, and the detection target gas is detected at the high level.

Abstract: A sensor body of an electrochemical gas sensor having no water reservoir is housed in a metal can including a sensing electrode on one surface of a proton-conducting membrane or a separator retaining an electrolyte and a counter electrode on the opposite surface thereof. The counter electrode is supported by and electrically connected to the metal can via a connecting member. The sensing electrode is connected to a diffusion control plate with the sensing electrode-side ring member, and the ring member is conductive and includes a hole at a center thereof that is connected to a hole of the diffusion control plate.

Abstract: A method and apparatus for diagnosing an electrochemical sensor that detects the concentration of a gas are operative for diagnosing whether or not the sensor is in an error state due to a rise in a resistance in the electrolyte of the sensor. Such detection is made on the basis of a current flowing between a sensing electrode and an opposite electrode or a voltage corresponding to the current. A method for diagnosing an electrochemical sensor having a solid or liquid electrolyte between a sensing electrode and an opposite electrode detects the concentration of the gas to be detected on the basis of a current flowing between the sensing electrode and the opposite electrode, or a voltage corresponding to the current. Whether or not the electrochemical sensor is in an error state is diagnosed on the basis of a resistance of the electrolyte between the two electrodes of the electrolyte.

Abstract: A sensor body of an electrochemical gas sensor having no water reservoir is housed in a metal can including a sensing electrode on one surface of a proton-conducting membrane or a separator retaining an electrolyte and a counter electrode on the opposite surface thereof. The counter electrode is supported by and electrically connected to the metal can via a connecting member. The sensing electrode is connected to a diffusion control plate with the sensing electrode-side ring member, and the ring member is conductive and includes a hole at a center thereof that is connected to a hole of the diffusion control plate.

Abstract: An electrochemical gas sensor includes: a disc-shaped metal bottom member; a cylindrical metal side member that extends along the axial direction of the bottom member to surround the bottom member; a ring-shaped polymer gasket that includes an opening in the center and in which both sides of the opening each have an L-shaped member in cross section, with one section of the L-shaped member being in contact with the inner side of the side member and the other section of the L-shaped member being in contact with the bottom member; a gas sensor body that is located in the opening of the gasket and whose bottom surface is in contact with the bottom member and that includes a pair of electrodes and a solid electrolyte membrane or a separator retaining a liquid electrolyte; and a metal cover that is in contact with the top surface of the gas sensor body.

Abstract: An electrochemical gas sensor includes: a disc-shaped metal bottom member; a cylindrical metal side member that extends along the axial direction of the bottom member to surround the bottom member; a ring-shaped polymer gasket that includes an opening in the center and in which both sides of the opening each have an L-shaped member in cross section, with one section of the L-shaped member being in contact with the inner side of the side member and the other section of the L-shaped member being in contact with the bottom member; a gas sensor body that is located in the opening of the gasket and whose bottom surface is in contact with the bottom member and that includes a pair of electrodes and a solid electrolyte membrane or a separator retaining a liquid electrolyte; and a metal cover that is in contact with the top surface of the gas sensor body.

Abstract: A gas is detected using a MEMS gas sensor. The electrical power to a heater in the gas sensor is changed between a low level, a high level suitable for detection of detection target gas, and a 0 level, and, therefore, poisonous gas is evaporated or oxidized at the low level, and the detection target gas is detected at the high level.

Abstract: An output of a direct current power supply is divided with a pair of resistors, and applied to any of electrodes of an electrochemical gas sensor provided with a detection electrode, a counter electrode and a solid electrolyte membrane through a buffer amplifier. Impedance of the gas sensor is measured by switching with a switch the connection destination of one electrode of the electrochemical gas sensor between a current amplification circuit and an impedance measurement circuit. The impedance measurement circuit is formed of an alternating current power supply that switches a potential of a resistor on a side of one end connected to the switch and a potential on a side of the other end of the resistor, between the output potential and the ground potential of the direct current power supply.

Abstract: A method and apparatus for diagnosing an electrochemical sensor that detects the concentration of a gas are operative for diagnosing whether or not the sensor is in an error state due to a rise in a resistance in the electrolyte of the sensor. Such detection is made on the basis of a current flowing between a sensing electrode and an opposite electrode or a voltage corresponding to the current. A method for diagnosing an electrochemical sensor having a solid or liquid electrolyte between a sensing electrode and an opposite electrode detects the concentration of the gas to be detected on the basis of a current flowing between the sensing electrode and the opposite electrode, or a voltage corresponding to the current. Whether or not the electrochemical sensor is in an error state is diagnosed on the basis of a resistance of the electrolyte between the two electrodes of the electrolyte.