Abstract: Excess oxygen in the combustion process of a facility that bums carbon-based fuels may cause a visible plume in the atmosphere at the stack of the facility. Traditional optical based opacity monitors may be unable to detect this plume or the plume may form at a location downstream from the opacity monitor toward the stack. The present invention discloses methods to utilize common combustion control variables to detect and signal the presence of a visible plume of exhaust gasses. Also disclosed are systems that detect the visible plume and provide a signal so that the combustion process may be manually or automatically adjusted to reduce or eliminate the visible plume.