Abstract: The method of the present invention is a novel comprehensive process for maximizing the recovery of valuable mineral values from coal ash. Options may also be included for the production of saleable inorganic chemical by-products. The process employs both physical and chemical extraction techniques that maximize the yield of products while reducing the quantity of waste produced. Valuable minerals and chemicals such as cenospheres (hollow microspheres), carbon, magnetite (Fe.sub.3 O.sub.4), alumina (Al.sub.2 O.sub.3), iron oxide (Fe.sub.2 O.sub.3) and iron chloride (FeCl.sub.3) may be produced. Due to removal of carbon, magnetite, and iron oxide from the coal ash, the processed ash comprises a quality pozzolan.
Type:
Grant
Filed:
January 29, 1986
Date of Patent:
March 24, 1987
Assignee:
Florida Progress Corporation
Inventors:
Robert A. Ashworth, Larry A. Rodriguez, Antonio A. Padilla, Ned B. Spake, W. Wes Berry, Rae A. Schmeda
Abstract: An improved fuel composition is provided comprising in minor proportion a non-dewatered sewage sludge and in major proportion an organic fuel comprised of a hydrocarbon fuel oil. A method is also provided for the incineration of sewage sludge comprised of providing an admixture of a minor proportion of a non-dewatered sewage sludge and a major proportion of an organic fuel comprised of a liquid hydrocarbon fuel oil and incinerating the admixture.
Abstract: A novel method is provided for the production of anhydrous hydrofluoric acid from low-grade metallic fluorides using an intermediate aluminum fluoride compound. The method involves the reaction of low-grade metallic fluorides such as fluorspar with sulfuric acid to produce weak hydrofluoric acid. The weak acid is then reacted with a metallic salt (such as aluminum chloride) to form precipitated aluminum fluoride (AlF.sub.3.3H.sub.2 O). After dewatering, the aluminum fluoride is reacted with strong sulfuric acid to form aluminum sulfate and strong hydrofluoric acid.
Type:
Grant
Filed:
December 15, 1983
Date of Patent:
October 16, 1984
Assignee:
Florida Progress Corporation
Inventors:
William W. Berry, Robert A. Ashworth, Ned B. Spake