Patents Assigned to FLOSFIA INC.
  • Patent number: 12289917
    Abstract: Provided is a semiconductor device in which a leakage current is reduced, the semiconductor device which is particularly useful for power devices. A semiconductor device including at least: an n+-type semiconductor layer, which contains a crystalline oxide semiconductor as a major component; an n?-type semiconductor layer that is placed on the n+-type semiconductor layer, the n?-type semiconductor layer containing a crystalline oxide semiconductor as a major component; a high-resistance layer with at least a part thereof being embedded in the n?-type semiconductor layer, a depth d (?m) of the part embedded in the n?-type semiconductor layer satisfying d?1.4; and a Schottky electrode that forms a Schottky junction with the n?-type semiconductor layer, the Schottky electrode having an edge located on the high-resistance layer.
    Type: Grant
    Filed: June 7, 2022
    Date of Patent: April 29, 2025
    Assignee: FLOSFIA INC.
    Inventors: Mitsuru Okigawa, Fujio Okui, Yasushi Higuchi, Koji Amazutsumi, Hidetaka Shibata, Yuji Kato, Atsushi Terai
  • Patent number: 12284822
    Abstract: There is provided a semiconductor device comprising at least, a crystalline oxide semiconductor layer which has a band gap of 4.5 eV or more; and a field-effect mobility of 10 cm2/V·s or higher.
    Type: Grant
    Filed: May 27, 2022
    Date of Patent: April 22, 2025
    Assignee: FLOSFIA INC.
    Inventors: Masahiro Sugimoto, Yasushi Higuchi
  • Patent number: 12195844
    Abstract: There is provided a thin film manufacturing method which allows both a reduction in the carbon impurity concentration and a high film forming speed, as well as allows separate formation of stable crystal structures. There is provided a method for manufacturing an oxide crystal thin film. The method includes carrying raw material fine particles to a film forming chamber by means of a carrier gas, the raw material fine particles being formed from a raw material solution including water and at least one of a gallium compound and an indium compound, and forming an oxide crystal thin film on a sample on which films are to be formed, the sample being placed in the film forming chamber. At least one of the gallium compound and the indium compound is bromide or iodide.
    Type: Grant
    Filed: October 29, 2021
    Date of Patent: January 14, 2025
    Assignee: FLOSFIA INC.
    Inventors: Masaya Oda, Toshimi Hitora
  • Patent number: 12191372
    Abstract: A crystal that is useful for semiconductor element and a semiconductor element that has enhanced electrical properties are provided. A crystal, including: a corundum structured crystalline oxide, the crystalline oxide including gallium and/or indium, and the crystalline oxide further including a metal of Group 4 of the periodic table. The crystal is used to make a semiconductor element, and the obtained semiconductor element is used to make a semiconductor device such as a power card. Also, the semiconductor element and the semiconductor device are used to make a semiconductor system.
    Type: Grant
    Filed: September 23, 2022
    Date of Patent: January 7, 2025
    Assignee: FLOSFIA INC.
    Inventors: Ryohei Kanno, Osamu Imafuji, Kazuyoshi Norimatsu, Yuji Kato
  • Patent number: 12176436
    Abstract: A semiconductor device including at least one inversion channel region includes an oxide semiconductor film containing a crystal that has a corundum structure at the inversion channel region.
    Type: Grant
    Filed: July 11, 2019
    Date of Patent: December 24, 2024
    Assignee: FLOSFIA INC.
    Inventors: Masahiro Sugimoto, Isao Takahashi, Takashi Shinohe
  • Patent number: 12159940
    Abstract: Provided are a multilayer structure in which crystal defects due to stress concentration in a semiconductor layer caused by an insulator film are prevented and a semiconductor device using the multilayer structure, the multilayer structure and the semiconductor device that are particularly useful for power devices. A multilayer structure in which an insulator film is arranged on a part of a semiconductor film, wherein the semiconductor film has a corundum structure and contains a crystalline oxide semiconductor containing one or two or more metals selected from groups 9 and 13 of the periodic table, and wherein the insulator film has a taper angle of 20° or less.
    Type: Grant
    Filed: January 14, 2022
    Date of Patent: December 3, 2024
    Assignee: FLOSFIA INC.
    Inventors: Mitsuru Okigawa, Yasushi Higuchi, Yusuke Matsubara, Osamu Imafuji, Takashi Shinohe
  • Patent number: 12148804
    Abstract: A semiconductor device with enhanced semiconductor characteristics that is useful for power devices. A semiconductor device, including: an n-type semiconductor layer; one or more p-type semiconductors; an electrode, the one or more p-type semiconductors that are provided between the n-type semiconductor layer and the electrode, and at least a part of the one or more p-type semiconductors is protruded in the electrode.
    Type: Grant
    Filed: July 10, 2019
    Date of Patent: November 19, 2024
    Assignee: FLOSFIA INC.
    Inventors: Masahiro Sugimoto, Isao Takahashi, Takashi Shinohe, Koji Amazutsumi
  • Patent number: 12107137
    Abstract: Provided is a semiconductor device in which a leakage current is reduced, the semiconductor device which is particularly useful for power devices. A semiconductor device including at least: an n+-type semiconductor layer, which contains a crystalline oxide semiconductor as a major component; an n?-type semiconductor layer that is placed on the n+-type semiconductor layer, the n?-type semiconductor layer containing a crystalline oxide semiconductor as a major component; a high-resistance layer with at least a part thereof being embedded in the n?-type semiconductor layer, the high-resistance layer having a bottom surface located at a distance of less than 1.5 ?m from an upper surface of the n+-type semiconductor layer; and a Schottky electrode that forms a Schottky junction with the n?-type semiconductor layer, the Schottky electrode having an edge located on the high-resistance layer.
    Type: Grant
    Filed: June 7, 2022
    Date of Patent: October 1, 2024
    Assignee: FLOSFIA INC.
    Inventors: Mitsuru Okigawa, Fujio Okui, Yasushi Higuchi, Koji Amazutsumi, Hidetaka Shibata, Yuji Kato, Atsushi Terai
  • Patent number: 12107125
    Abstract: A first raw material solution containing at least aluminum is atomized to generate first atomized droplets and a second raw material solution containing at least gallium and a dopant is atomized to generate second atomized droplets, and subsequently, the first atomized droplets are carried into a film forming chamber using a first carrier gas and the second atomized droplets are carried into the film forming chamber using a second carrier gas, and then the first atomized droplets and the second atomized droplets are mixed in the film forming chamber, and the mixed atomized droplets are thermally reacted in the vicinity of a surface of the base to form an oxide semiconductor film on the base, the oxide semiconductor film including, as a major component, a metal oxide containing at least aluminum and gallium, wherein the oxide semiconductor film has a mobility of no less than 5 cm2/Vs.
    Type: Grant
    Filed: January 12, 2022
    Date of Patent: October 1, 2024
    Assignee: FLOSFIA INC.
    Inventor: Ryohei Kanno
  • Patent number: 12100769
    Abstract: An object of the disclosure is to provide a semiconductor device with low-loss and suppressed leakage current, which is particularly useful for power devices. A semiconductor device including a semiconductor layer including an oxide semiconductor having a corundum structure as a main component, and a Schottky electrode including a first electrode layer and a second electrode layer having a higher conductivity than the first electrode layer, wherein an outer edge portion of the second electrode layer is electrically connected to the semiconductor layer at an electrical connection region through the first electrode layer, and an outer edge portion of the first electrode layer is located outside an outer edge portion of the electrical connection region.
    Type: Grant
    Filed: May 22, 2020
    Date of Patent: September 24, 2024
    Assignee: FLOSFIA INC.
    Inventor: Mitsuru Okigawa
  • Patent number: 12100760
    Abstract: A semiconductor device includes an oxide semiconductor film having a corundum structure or containing as a major component gallium oxide or a mixed crystal of gallium oxide, and the semiconductor device is a normally-off semiconductor device with a threshold voltage that is 3V or more.
    Type: Grant
    Filed: July 11, 2019
    Date of Patent: September 24, 2024
    Assignee: FLOSFIA INC.
    Inventors: Masahiro Sugimoto, Isao Takahashi, Takashi Shinohe
  • Patent number: 12033869
    Abstract: In a first aspect of a present inventive subject matter, a method of etching includes etching an object at a temperature that is higher than 200° C. with atomized droplets of an etching liquid.
    Type: Grant
    Filed: June 24, 2020
    Date of Patent: July 9, 2024
    Assignee: FLOSFIA INC.
    Inventor: Isao Takahashi
  • Publication number: 20240170285
    Abstract: Provided is a crystalline oxide film including an oxide of germanium, an area percentage of abnormal grains determined by surface SEM observation being 3% or less.
    Type: Application
    Filed: January 29, 2024
    Publication date: May 23, 2024
    Applicants: FLOSFIA INC., KYOTO UNIVERSITY
    Inventors: Kentaro KANEKO, Hitoshi TAKANE, Toshimi HITORA
  • Patent number: 11967618
    Abstract: A crystalline oxide semiconductor film with an enhanced electrical property is provided. By use of a mist CVD apparatus, a crystalline oxide semiconductor film with a corundum structure and a principal plane that is an a-plane or an m-plane was obtained on a crystalline substrate by atomizing a raw-material solution containing a dopant that is an n-type dopant to obtain atomized droplets, carrying the atomized droplets by carrier gas onto the crystalline substrate that is an a-plane corundum-structured crystalline substrate or an m-plane corundum-structured crystalline substrate placed in a film-formation chamber, and the atomized droplets were thermally reacted to form the crystalline oxide semiconductor film on the crystalline substrate.
    Type: Grant
    Filed: June 6, 2022
    Date of Patent: April 23, 2024
    Assignee: FLOSFIA INC.
    Inventors: Isao Takahashi, Takashi Shinohe, Rie Tokuda, Masaya Oda, Toshimi Hitora
  • Patent number: 11916103
    Abstract: A new and useful p-type oxide semiconductor with a wide band gap and an enhanced electrical conductivity and the method of manufacturing the p-type oxide semiconductor are provided. A method of manufacturing a p-type oxide semiconductor including: generating atomized droplets by atomizing a raw material solution containing at least a d-block metal in the periodic table and a metal of Group 13 of the periodic table; carrying the atomized droplets onto a surface of a base by using a carrier gas; causing a thermal reaction of the atomized droplets adjacent to the surface of the base under an atmosphere of oxygen to form the p-type oxide semiconductor on the base.
    Type: Grant
    Filed: July 18, 2022
    Date of Patent: February 27, 2024
    Assignees: FLOSFIA INC., KYOTO UNIVERSITY
    Inventors: Shizuo Fujita, Kentaro Kaneko, Toshimi Hitora, Tomochika Tanikawa
  • Patent number: 11855135
    Abstract: An object of the disclosure is to provide a semiconductor device having enhanced adhesion of the electrode while improving the reverse direction breakdown voltage, which is especially useful for power devices. A semiconductor device including a semiconductor layer and an electrode layer provided on the semiconductor layer and including at least a first electrode layer and a second electrode layer provided on the first electrode layer, wherein an outer edge portion of the second electrode layer is located outside an outer edge portion of the first electrode layer, wherein the semiconductor layer includes an electric field relaxation region with a different electrical resistivity from that of the semiconductor layer, and wherein the electric field relaxation region overlaps at least a part of a portion of the second electrode layer located outside the outer edge portion of the first electrode layer in plan view.
    Type: Grant
    Filed: October 22, 2021
    Date of Patent: December 26, 2023
    Assignee: FLOSFIA INC.
    Inventors: Mitsuru Okigawa, Hideaki Yanagida, Takashi Shinohe
  • Patent number: 11804519
    Abstract: A crystalline multilayer structure having a high-quality crystalline layer and a semiconductor device employing such a crystalline multilayer structure are provided. A crystalline multilayer structure, including a first crystalline layer having a first crystal, and a second crystalline layer stacked on the first crystalline layer and having a second crystal, wherein the first crystal includes polycrystalline ?-Ga2O3 and the second crystal is a single crystal of a crystalline oxide.
    Type: Grant
    Filed: April 26, 2021
    Date of Patent: October 31, 2023
    Assignees: FLOSFIA INC., NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Yuichi Oshima, Katsuaki Kawara
  • Patent number: 11694894
    Abstract: A high-quality crystalline film having less impurity of Si and the like and useful in semiconductor devices is provided. A crystalline film containing a crystalline metallic oxide including gallium as a main component, wherein the crystalline film includes a Si in a content of 2×1015 cm?3 or less.
    Type: Grant
    Filed: April 26, 2021
    Date of Patent: July 4, 2023
    Assignee: FLOSFIA INC.
    Inventors: Yuichi Oshima, Katsuaki Kawara
  • Patent number: 11682702
    Abstract: A semiconductor film, a sheet like object, and a semiconductor device are provided that have inhibited semiconductor properties, particularly leakage current, and excellent withstand voltage and heat dissipation. A crystalline semiconductor film or a sheet like object includes a corundum structured oxide semiconductor as a major component, wherein the film has a film thickness of 1 ?m or more. Particularly, the semiconductor film or the object includes a semiconductor component of oxide of one or more selected from gallium, indium, and aluminum as a major component. A semiconductor device has a semiconductor structure including the semiconductor film or the object.
    Type: Grant
    Filed: December 7, 2020
    Date of Patent: June 20, 2023
    Assignee: FLOSFIA Inc.
    Inventors: Toshimi Hitora, Masaya Oda, Akio Takatsuka
  • Patent number: 11670688
    Abstract: The disclosure provides a semiconductor apparatus capable of keeping a semiconductor characteristics and realizing excellent semiconductor properties even when using an n type semiconductor (gallium oxide, for example) having a low loss at a high voltage and having much higher dielectric breakdown electric field strength than SiC. A semiconductor apparatus includes a gate electrode and a channel layer formed of a channel directly or through other layers on a side wall of the gate electrode, and wherein a portion of or whole the channel layer may be a p type oxide semiconductor (iridium oxide, for example).
    Type: Grant
    Filed: November 15, 2018
    Date of Patent: June 6, 2023
    Assignee: FLOSFIA INC.
    Inventors: Tokiyoshi Matsuda, Masahiro Sugimoto, Takashi Shinohe