Abstract: A well treatment additive includes a siloxane surfactant, a solvent and an aqueous phase. The solvent is preferably a terpene hydrocarbon. Also disclosed is a method for using the well treatment additive to form and enhance the properties of terpene solvent based additives useful for the treatment of oil and gas wells. Methods of using the novel well treatment additives include using the additives in a variety of well treatment processes including, but not limited to, acidizing operations, hydraulic fracturing operations, well remediation operations and water removal operations.
Type:
Grant
Filed:
March 13, 2020
Date of Patent:
April 25, 2023
Assignee:
Flotek Chemistry, LLC
Inventors:
Glenn S. Penny, Keith Ingram Dismuke, Richard Nelson Fox, Andrei Zelenev, Randal M. Hill
Abstract: Compositions and methods comprising certain microemulsions and certain clay control additives for enhancing clay swelling protection and persistency in treating swelling clay of a subterranean formation of oil and/or gas wells are generally provided. The combination of certain microemulsions and certain clay control additives exhibit synergistic effects by enhancing clay swelling protection and persistency in treating swelling clay. The well treatment composition may use up to four times less concentration of clay control additive compared to using the same clay control additive alone, while still providing the same, similar, or higher degree of clay swelling protection and enhanced persistency.
Abstract: Methods and compositions comprising an emulsion or a microemulsion for use treating an oil and/or gas well are provided. In some embodiments, the emulsion or the microemulsion comprises an aqueous phase, a solvent, a surfactant comprising alkyl polyglycoside, an alcohol, and, optionally, one or more additives.
Abstract: Microemulsions comprising an alkyl propoxylated sulfate surfactant and related methods, including methods of use in the treatment of subterranean formations, such as oil and condensate wells, are provided. In some embodiments, the microemulsions and/or methods of use achieve ultra-low interfacial tensions (i.e. less than or equal to 0.01 mN/m) between a wide variety of crude oils and well treatment fluids at various reservoir conditions. In some embodiments, the microemulsion comprises water, an anionic alkyl propoxylated sulfate surfactant, a solvent (e.g., a terpene solvent), and a co-solvent. In some embodiments, the microemulsion further comprises a second and/or third surfactant (e.g., a nonionic and/or an anionic surfactant).
Abstract: A well treatment composition designed for the simultaneous enhancement of the production of both liquid and gaseous hydrocarbons from the same reservoir on a non-selective basis. The well treatment composition includes a first surfactant and a second surfactant, wherein the second surfactant is selected from the group consisting of ethylenediaminealkoxylate, diethylenetriaminealkoxylate, ethoxylated alkylene amines, ethoxylated alkyl amines, propoxylated alkylene amines, propoxylated alkyl amines, ethoxylated-propoxylated alkylene amines and ethoxylated-propoxylated alkyl amines. The well treatment composition also includes a first solvent, a second solvent and water. Methods for using the well treatment composition include the steps of emplacing the well treatment composition into wells having high and low gas-to-oil ratios.
Type:
Grant
Filed:
November 30, 2018
Date of Patent:
August 9, 2022
Assignee:
Flotek Chemistry, LLC
Inventors:
Andrei Zelenev, Lakia M. Champagne, Bill Zhou, Nathan L. Lett, Keith Ingram Dismuke, Glenn S. Penny
Abstract: Microemulsions comprising an alkyl propoxylated sulfate surfactant and related methods, including methods of use in the treatment of subterranean formations, such as oil and condensate wells, are provided. In some embodiments, the microemulsions and/or methods of use achieve ultra-low interfacial tensions (i.e. less than or equal to 0.01 mN/m) between a wide variety of crude oils and well treatment fluids at various reservoir conditions. In some embodiments, the microemulsion comprises water, an anionic alkyl propoxylated sulfate surfactant, a solvent (e.g., a terpene solvent), and a co-solvent. In some embodiments, the microemulsion further comprises a second and/or third surfactant (e.g., a nonionic and/or an anionic surfactant).
Abstract: Compositions relating to microemulsions or diluted microemulsions for treating gas wells having wellbores and methods related to treating gas wells having wellbores using the same are generally provided. In some embodiments, the microemulsions or diluted microemulsions have an especially low surface tension at a gas well bottom hole temperature and pressure.
Type:
Application
Filed:
November 19, 2021
Publication date:
March 10, 2022
Applicant:
Flotek Chemistry, LLC
Inventors:
Natalie Forbes, James Silas, Randal M. Hill
Abstract: Methods and compositions comprising an emulsion or a microemulsion for use in various aspects of the life cycle of an oil and/or gas well are provided. In some embodiments, the emulsion or the microemulsion comprises water, a solvent, and a surfactant, and optionally, one or more additives.
Type:
Grant
Filed:
June 30, 2020
Date of Patent:
February 22, 2022
Assignee:
Flotek Chemistry, LLC
Inventors:
Randal M. Hill, Lakia M. Champagne, Nathan L. Lett, Keith Ingram Dismuke, David Germack, Melinda Soeung, Nicole Mast
Abstract: Compositions and methods comprising certain microemulsions and certain clay control additives for enhancing clay swelling protection and persistency in treating swelling clay of a subterranean formation of oil and/or gas wells are generally provided. The combination of certain microemulsions and certain clay control additives exhibit synergistic effects by enhancing clay swelling protection and persistency in treating swelling clay. The well treatment composition may use up to four times less concentration of clay control additive compared to using the same clay control additive alone, while still providing the same, similar, or higher degree of clay swelling protection and enhanced persistency.
Abstract: Compositions relating to microemulsions or diluted microemulsions for treating gas wells having wellbores and methods related to treating gas wells having wellbores using the same are generally provided. In some embodiments, the microemulsions or diluted microemulsions have an especially low surface tension at a gas well bottom hole temperature and pressure.
Type:
Grant
Filed:
June 4, 2019
Date of Patent:
November 23, 2021
Assignee:
Flotek Chemistry, LLC
Inventors:
Natalie Forbes, James Silas, Randal M. Hill
Abstract: Emulsion or microemulsion for treating an oil or gas well having a wellbore are provided, and related methods. In some embodiments, the emulsion or microemulsion comprises an aqueous phase; a surfactant; and a non-aqueous phase comprising a first type of solvent and a second type of solvent. In some embodiments, the first type of solvent is a long chain hydrocarbon. In some embodiments, the second type of solvent is an oxygenated solvent. The emulsion or microemulsion may comprise additional components (e.g., at least one type of co-solvent).
Type:
Application
Filed:
May 19, 2021
Publication date:
November 4, 2021
Applicant:
Flotek Chemistry, LLC
Inventors:
Randal M. Hill, Paul Ashcraft, Angus Fursdon-Welsh, Lakia M. Champagne, Natalie Forbes
Abstract: A well treatment additive includes a siloxane surfactant, a solvent and an aqueous phase. The solvent is preferably a terpene hydrocarbon. Also disclosed is a method for using the well treatment additive to form and enhance the properties of terpene solvent based additives useful for the treatment of oil and gas wells. Methods of using the novel well treatment additives include using the additives in a variety of well treatment processes including, but not limited to, acidizing operations, hydraulic fracturing operations, well remediation operations and water removal operations.
Type:
Grant
Filed:
May 4, 2016
Date of Patent:
October 19, 2021
Assignee:
Flotek Chemistry, LLC
Inventors:
Glenn S. Penny, Keith Ingram Dismuke, Richard Nelson Fox, Andrei Zelenev, Randal M. Hill
Abstract: Compositions and methods comprising certain microemulsions and certain clay control additives for enhancing clay swelling protection and persistency in treating swelling clay of a subterranean formation of oil and/or gas wells are generally provided. The combination of certain microemulsions and certain clay control additives exhibit synergistic effects by enhancing clay swelling protection and persistency in treating swelling clay. The well treatment composition may use up to four times less concentration of clay control additive compared to using the same clay control additive alone, while still providing the same, similar, or higher degree of clay swelling protection and enhanced persistency.
Abstract: Emulsion or microemulsion for treating an oil or gas well having a wellbore are provided, and related methods. In some embodiments, the emulsion or microemulsion comprises an aqueous phase; a surfactant; and a non-aqueous phase comprising a first type of solvent and a second type of solvent. In some embodiments, the first type of solvent is a long chain hydrocarbon. In some embodiments, the second type of solvent is an oxygenated solvent. The emulsion or microemulsion may comprise additional components (e.g., at least one type of co-solvent).
Type:
Grant
Filed:
November 30, 2018
Date of Patent:
July 6, 2021
Assignee:
Flotek Chemistry, LLC
Inventors:
Randal M. Hill, Paul Ashcraft, Angus Fursdon-Welsh, Lakia M. Champagne, Natalie Forbes
Abstract: Methods and compositions comprising an emulsion or a microemulsion for use treating an oil and/or gas well are provided. In some embodiments, the emulsion or the microemulsion comprises an aqueous phase, a solvent, a surfactant comprising alkyl polyglycoside, an alcohol, and, optionally, one or more additives.
Abstract: Compositions comprising non-halogenated solvents for use in various aspects of a life cycle of an oil and/or gas well, and related methods, are provided. In some embodiments, the composition comprises a solvent blend and one or more surfactants. In some embodiments, the solvent blend comprises a first type of solvent (e.g., a terpene) and a second type of solvent (e.g., a non-halogenated solvent). The composition may comprise about 90 wt % to 99.9 wt % of the solvent blend, and about 0.1 wt % to 10 wt % of one or more surfactants, versus the total weight of the composition. In some embodiments, compositions can be used in methods for treating an oil and/or gas well, having a wellbore that comprises one or more fluids. A composition may be delivered into the wellbore, passing through the one or more fluids to reduce residues comprising asphaltenes, paraffins or combinations thereof on or near the wellbore.
Abstract: Methods and compositions comprising an emulsion or a microemulsion for use in various aspects of the life cycle of an oil and/or gas well are provided. In some embodiments, the emulsion or the microemulsion comprises water, a solvent, and a surfactant, and optionally, one or more additives.
Type:
Grant
Filed:
June 3, 2019
Date of Patent:
June 15, 2021
Assignee:
Flotek Chemistry, LLC
Inventors:
Lakia M. Champagne, Angus Fursdon-Welsh, Randal M. Hill
Abstract: A method begins with the step of preparing a drag-reducing additive by mixing a dispersion polymer with a surfactant and a solvent. The method continues with the step of forming a drag-reducing composition by combining the drag-reducing additive with an aqueous treatment fluid. The method further involves the step of injecting the drag-reducing composition into a subterranean formation, a pipeline or a gathering line.
Type:
Grant
Filed:
November 30, 2018
Date of Patent:
May 11, 2021
Assignee:
Flotek Chemistry, LLC
Inventors:
Andrei Zelenev, Lakia Champagne, David Philpot
Abstract: Compositions and methods comprising certain microemulsions and certain clay control additives for enhancing clay swelling protection and persistency in treating swelling clay of a subterranean formation of oil and/or gas wells are generally provided. The combination of certain microemulsions and certain clay control additives exhibit synergistic effects by enhancing clay swelling protection and persistency in treating swelling clay. The well treatment composition may use up to four times less concentration of clay control additive compared to using the same clay control additive alone, while still providing the same, similar, or higher degree of clay swelling protection and enhanced persistency.
Abstract: Methods and compositions comprising an emulsion or a microemulsion for use treating an oil and/or gas well are provided. In some embodiments, the emulsion or the microemulsion comprises an aqueous phase, a solvent, a surfactant comprising alkyl polyglycoside, an alcohol, and, optionally, one or more additives.