Patents Assigned to Freeport-McMoran Corporation
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Publication number: 20130153435Abstract: A cathode assembly, a system including the cathode assembly, and method of using the assembly and system are disclosed. The cathode assembly includes high surface area material to allow efficient recovery of metal at reduced current densities at the cathode, which allows increased rates of metal recovery to be obtained, while maintaining desired properties of the electrowon metal.Type: ApplicationFiled: December 20, 2011Publication date: June 20, 2013Applicant: FREEPORT-MCMORAN CORPORATIONInventors: Scot P. Sandoval, Casey J. Clayton, Jason M. Morgan, Charles L. Bryce, Brett Waterman
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Publication number: 20130126341Abstract: An electrode for use in producing copper in either a conventional electrowinning cell or the direct electrowinning cell is provided. The electrode includes a hanger bar and an electrode body coupled with the hanger bar. The electrode body includes at least one conductor rod having a core and an outer layer surrounding the core and a substrate coupled with the conductor rod.Type: ApplicationFiled: January 11, 2013Publication date: May 23, 2013Applicant: FREEPORT-MCMORAN CORPORATIONInventor: FREEPORT-McMORAN CORPORATION
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Publication number: 20130121910Abstract: The present invention relates generally to a process for controlled leaching and sequential recovery of two or more metals from metal-bearing materials. In one exemplary embodiment, recovery of metals from a leached metal-bearing material is controlled and improved by providing a high grade pregnant leach solution (“HGPLS”) and a low grade pregnant leach solution (“LGPLS”) to a single solution extraction plant comprising at least two solution extractor units, at least two stripping units, and, optionally, at least one wash stage.Type: ApplicationFiled: January 8, 2013Publication date: May 16, 2013Applicant: FREEPORT-MCMORAN CORPORATIONInventor: FREEPORT-MCMORAN CORPORATION
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Publication number: 20130118310Abstract: Various embodiments provide new methods of rhenium recovery. The methods can include subjecting a metal-bearing solution to an activated carbon bed, and adsorbing rhenium onto the activated carbon. The methods can also include heating a basic aqueous elution solution and eluting the rhenium from the activated carbon with the heated elution solution. The methods can also incorporate an ion exchange as a rhenium recovery apparatus.Type: ApplicationFiled: December 21, 2012Publication date: May 16, 2013Applicant: FREEPORT-MCMORAN CORPORATIONInventor: FREEPORT-MCMORAN CORPORATION
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Patent number: 8420048Abstract: The present disclosure relates to a process and system for recovery of one or more metal values using solution extraction techniques and to a system for metal value recovery. In an exemplary embodiment, the solution extraction system comprises a first solution extraction circuit and a second solution extraction circuit. A first metal-bearing solution is provided to the first and second circuit, and a second metal-bearing solution is provided to the first circuit. The first circuit produces a first rich electrolyte solution, which can be forwarded to primary metal value recovery, and a low-grade raffinate, which is forwarded to secondary metal value recovery. The second circuit produces a second rich electrolyte solution, which is also forwarded to primary metal value recovery. The first and second solution extraction circuits have independent organic phases and each circuit can operate independently of the other circuit.Type: GrantFiled: December 20, 2011Date of Patent: April 16, 2013Assignee: Freeport-McMoran CorporationInventors: Anand Raman, Jason M. Morgan, Barbara J Savage, David G Meadows, Wayne W Hazen
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Patent number: 8372360Abstract: The present invention relates generally to a process for controlled leaching and sequential recovery of two or more metals from metal-bearing materials. In one exemplary embodiment, recovery of metals from a leached metal-bearing material is controlled and improved by providing a high grade pregnant leach solution (“HGPLS”) and a low grade pregnant leach solution (“LGPLS”) to a single solution extraction plant comprising at least two solution extractor units, at least two stripping units, and, optionally, at least one wash stage.Type: GrantFiled: July 21, 2011Date of Patent: February 12, 2013Assignee: Freeport-McMoran CorporationInventors: Barbara J. Savage, David G. Meadows, Wayne W. Hazen
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Patent number: 8372254Abstract: An electrode for use in producing copper in either a conventional electrowinning cell or the direct electrowinning cell is provided. The electrode includes a hanger bar and an electrode body coupled with the hanger bar. The electrode body includes at least one conductor rod having a core and an outer layer surrounding the core and a substrate coupled with the conductor rod.Type: GrantFiled: September 29, 2011Date of Patent: February 12, 2013Assignee: Freeport-McMoran CorporationInventors: Scot P Sandoval, Casey J Clayton, Timothy G Robinson, Christopher John Zanotti, Martin Kim Zanotti
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Patent number: 8372361Abstract: The present invention relates generally to a process for controlled leaching and sequential recovery of two or more metals from metal-bearing materials. In one exemplary embodiment, recovery of metals from a leached metal-bearing material is controlled and improved by providing a high grade pregnant leach solution (“HGPLS”) and a low grade pregnant leach solution (“LGPLS”) to a single solution extraction plant comprising at least two solution extractor units, at least two stripping units, and, optionally, at least one wash stage.Type: GrantFiled: November 22, 2011Date of Patent: February 12, 2013Assignee: Freeport-McMoran CorporationInventors: Barbara J. Savage, David G. Meadows, Wayne W. Hazen
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Patent number: 8361192Abstract: Various embodiments provide new methods of rhenium recovery. The methods can include subjecting a metal-bearing solution to an activated carbon bed, and adsorbing rhenium onto the activated carbon. The methods can also include heating a basic aqueous elution solution and eluting the rhenium from the activated carbon with the heated elution solution.Type: GrantFiled: August 17, 2012Date of Patent: January 29, 2013Assignee: Freeport-McMoran CorporationInventors: Brett T. Waterman, Steve Nels Dixon, Theresa Linne Morelli, George Owusu, Stefka Todorova Ormsby
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Publication number: 20130001093Abstract: The present invention relates, generally, to a method and apparatus for recovering metal values from a metal-bearing materials, and more specifically, a process for recovering copper and other metals through leaching, electrowinning using the ferrous/ferric anode reaction, and the synergistic addition of ferrous iron to the leach step.Type: ApplicationFiled: September 5, 2012Publication date: January 3, 2013Applicant: FREEPORT-MCMORAN CORPORATIONInventors: John O. Marsden, James D. Gillaspie, John C. Wilmot
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Publication number: 20120304827Abstract: Various embodiments provide new methods of rhenium recovery. The methods can include subjecting a metal-bearing solution to an activated carbon bed, and adsorbing rhenium onto the activated carbon. The methods can also include heating a basic aqueous elution solution and eluting the rhenium from the activated carbon with the heated elution solution.Type: ApplicationFiled: August 17, 2012Publication date: December 6, 2012Applicant: FREEPORT-MCMORAN CORPORATIONInventors: Brett T. Waterman, Steve Nels Dixon, Theresa Linne Morelli, George Owusu, Stefka Todorova Ormsby
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Patent number: 8308920Abstract: In various embodiments, the present invention provides an electrolytic cell contact bar having a first pole and a pair of second poles. The second poles are opposite in charge to the first pole and each of the pair of second poles are adjacent to and parallel to the first pole. In various embodiments, the contact bar may include an electrode holder capable of holding at least one electrode.Type: GrantFiled: June 28, 2011Date of Patent: November 13, 2012Assignee: Freeport-McMoran CorporationInventors: Bret Ashford, William A Ebert, Fernando D Mollo Vega, Samuel Rasmussen, Timothy G Robinson, Scot P Sandoval
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Patent number: 8273237Abstract: The present invention relates, generally, to a method and apparatus for recovering metal values from a metal-bearing materials, and more specifically, a process for recovering copper and other metals through leaching, electrowinning using the ferrous/ferric anode reaction, and the synergistic addition of ferrous iron to the leach step.Type: GrantFiled: January 16, 2009Date of Patent: September 25, 2012Assignee: Freeport-McMoran CorporationInventors: John O. Marsden, James D. Gillaspie, John C. Wilmot
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Publication number: 20120205239Abstract: The present invention relates to an anode assembly for use in an electrolytic cell for recovery of metal. The assembly includes a hanger bar, a first perimeter bar, a second perimeter bar, optionally one or more center conductor bars, a base bar, a first tab coupled to the first perimeter bar and/or the base bar, and a second tab coupled to the second perimeter bar and/or the base bar. The assembly may also include insulating separators coupled to the tabs and/or insulators coupled to an active area of the anode assembly. A system includes the anode assembly, a cathode assembly, and a tank.Type: ApplicationFiled: February 16, 2011Publication date: August 16, 2012Applicant: FREEPORT-MCMORAN CORPORATIONInventors: Luis A. Gonzalez Olguin, Rafael Garcia Navarro, Luis Ricardo Olivares, Larry R. Todd, Ron Haines, Chris Zanotti, Casey J. Clayton, Mark Peabody, Scot P. Sandoval
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Publication number: 20120205254Abstract: The present invention relates to a contact bar assembly for use in a multi-cell electrolytic system for recovery of metal, to a system including the contact bar assembly, and to a method of using the assembly and system. The contact bar assembly includes a base cap board, a primary bar having a plurality of primary bar structures formed thereon, an auxiliary bar having a plurality of auxiliary bar structures formed thereon, and a top cap board, wherein the base cap board includes slots to receive the primary bar and the auxiliary bar, and wherein the top cap board includes a plurality of openings to receive the plurality of primary bar structures and the plurality of auxiliary bar structures. A system includes the contact bar assembly, an anode assembly, a cathode assembly, and a tank.Type: ApplicationFiled: February 16, 2011Publication date: August 16, 2012Applicant: FREEPORT-MCMORAN CORPORATIONInventors: Rafael Garcia Navarro, Luis A. Gonzalez Olguin, Luis Ricardo Olivares, Larry R. Todd, Mark Peabody, Casey J. Clayton, Scot P. Sandoval
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Patent number: 8187450Abstract: The present invention relates, generally, to a method and apparatus for electrowinning metals, and more particularly to a method and apparatus for copper electrowinning using the ferrous/ferric anode reaction. In general, the use of a flow-through anode—coupled with an effective electrolyte circulation system—enables the efficient and cost-effective operation of a copper electrowinning system employing the ferrous/ferric anode reaction at a total cell voltage of less than about 1.5 V and at current densities of greater than about 26 Amps per square foot (about 280 A/m2), and reduces acid mist generation. Furthermore, the use of such a system permits the use of low ferrous iron concentrations and optimized electrolyte flow rates as compared to prior art systems while producing high quality, commercially saleable product (i.e., LME Grade A copper cathode or equivalent), which is advantageous.Type: GrantFiled: April 1, 2010Date of Patent: May 29, 2012Assignee: Freeport-McMoran CorporationInventors: Scot Philip Sandoval, Timothy George Robinson, Paul Richard Cook
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Publication number: 20120125160Abstract: The present invention relates generally to a process for removing dissolved or colloidal silica from a pregnant leach solution (“PLS”). More particularly, an exemplary embodiment of the present invention relates to a, process which mixes PLS with an acid source, preferably lean electrolyte, to induce formation of colloidal silica that can then be collected and removed. Additionally, in an exemplary embodiment of the present invention, at least one silica seeding agent is added to induce formation of colloidal silica, at least one flocculant is added to induce aggregation of the colloidal silica, and a solid-liquid separation process is utilized to remove advantageous amounts or substantially all of the colloidal silica, thereby providing relief from supersaturation of dissolved silica in the metal recovery processes.Type: ApplicationFiled: January 30, 2012Publication date: May 24, 2012Applicant: FREEPORT-MCMORAN CORPORATIONInventors: James D Gillaspie, David R. Baughman, Dennis D. Gertenbach, Wayne W. Hazen, George Owusu, John C Wilmot
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Publication number: 20120118110Abstract: A system and method for recovering a metal value from a metal-bearing ore material are provided. A metal-bearing ore can be mixed with certain substances and to form an agglomerated ore. In an intermediate state, between agglomeration and heap formation, bacteria can be added to the metal-bearing ore material to produce an augmented ore. The augmented ore can then be formed into a heap.Type: ApplicationFiled: January 24, 2012Publication date: May 17, 2012Applicant: FREEPORT-MCMORAN CORPORATIONInventors: John Lawrence Urie, Gabe Bowman, Cristian Alejandro Caro Matus, Percy Mayta, Scott Hoenecke, Manuel Chavez
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Publication number: 20120085706Abstract: The present invention relates to a method and article for manipulating an amount of organic material entrained in an aqueous phase of a solvent extraction process. The method includes estimating an interfacial shear stress between an aqueous phase and an organic phase of a solvent extraction apparatus, estimating an amount of organic material entrained in the aqueous phase based on the estimated interfacial shear stress, and manipulating one or more solvent extraction process parameters to manipulate the amount of organic material entrained in the aqueous phase. The method and apparatus can be used to improve performance of and reduce operating costs associated with the solvent extraction apparatus.Type: ApplicationFiled: October 7, 2010Publication date: April 12, 2012Applicant: FREEPORT-MCMORAN CORPORATIONInventors: Charles L. Bryce, Jason M. Morgan, William R. Sircy, Rosemary D. Blosser
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Publication number: 20120060651Abstract: The present invention relates generally to a process for controlled leaching and sequential recovery of two or more metals from metal-bearing materials. In one exemplary embodiment, recovery of metals from a leached metal-bearing material is controlled and improved by providing a high grade pregnant leach solution (“HGPLS”) and a low grade pregnant leach solution (“LGPLS”) to a single solution extraction plant comprising at least two solution extractor units, at least two stripping units, and, optionally, at least one wash stage.Type: ApplicationFiled: November 22, 2011Publication date: March 15, 2012Applicant: FREEPORT-MCMORAN CORPORATIONInventors: Barbara J. Savage, David G. Meadows, Wayne W. Hazen