Patents Assigned to Fritz Industries, Inc.
  • Patent number: 9758713
    Abstract: A hydraulic cementing composition and a method of making the same is disclosed. The composition is useful to form a sheath of hardened cement in the annular space between a well pipe disposed in a well bore and the walls of the well bore. The cementing composition is a mixture of dry ingredients comprising hydraulic cement and an additive to control the loss of fluid from an aqueous slurry containing the cementing composition. The fluid loss additive and a method of making the same is disclosed. The fluid loss additive is the reaction product of three chemical compounds each having an ethylene backbone and functional groups selected from carboxylates, hydrogen, anhydrides and combinations thereof.
    Type: Grant
    Filed: March 21, 2016
    Date of Patent: September 12, 2017
    Assignee: FRITZ INDUSTRIES, INC.
    Inventors: James C. Ferrell, Jr., Kurt O. Lindstrom, Luis M. Perales, Hongfeng Ren
  • Patent number: 9714372
    Abstract: A hydraulic cementing composition and a method of making the same is disclosed. The composition is useful to form a sheath of hardened cement in the annular space between a well pipe disposed in a well bore and the walls of the well bore. The cementing composition is a mixture of dry ingredients comprising hydraulic cement and an additive to control the loss of fluid from an aqueous slurry containing the cementing composition. The fluid loss additive and a method of making the same is disclosed. The fluid loss additive is the reaction product of three chemical compounds each having an ethylene backbone and functional groups selected from carboxylates, hydrogen, anhydrides and combinations thereof.
    Type: Grant
    Filed: April 5, 2016
    Date of Patent: July 25, 2017
    Assignee: FRITZ INDUSTRIES, INC. A CORP. OF TEXAS
    Inventors: James C. Ferrell, Jr., Kurt O. Lindstrom, Luis M. Perales, Hongfeng Ren
  • Patent number: 9611419
    Abstract: A hydraulic well cementing composition is disclosed. The well cementing composition contains a hydraulic cement and a fluid loss additive. The fluid loss additive is the polymerization reaction product of a two vinylamide monomers, wherein the polymerization reaction is conducted in the presence of a molecular weight control agent. One of the vinylamide monomers includes a sulfonic acid function, the second vinylamide monomer does not include a sulfonic acid function. The fluid loss additive controls fluid loss at temperatures up to 350° F.
    Type: Grant
    Filed: April 1, 2016
    Date of Patent: April 4, 2017
    Assignee: FRITZ INDUSTRIES, INC. A CORPORATION OF TEXAS
    Inventors: James C. Ferrell, Jr., Lauren T. Gallagher, Bilal H. Bazzi
  • Patent number: 9321953
    Abstract: A hydraulic cementing composition and a method of making the same is disclosed. The composition is useful to form a sheath of hardened cement in the annular space between a well pipe disposed in a well bore and the walls of the well bore. The cementing composition is a mixture of dry ingredients comprising hydraulic cement and an additive to control the loss of fluid from an aqueous slurry containing the cementing composition. The fluid loss additive and a method of making the same is disclosed. The fluid loss additive is the reaction product of three chemical compounds each having an ethylene backbone and functional groups selected from carboxylates, hydrogen, anhydrides and combinations thereof.
    Type: Grant
    Filed: November 22, 2013
    Date of Patent: April 26, 2016
    Assignee: FRITZ INDUSTRIES, INC.
    Inventors: James C. Ferrell, Jr., Kurt O. Lindstrom, Luis M. Perales, Hongfeng Ren
  • Patent number: 9127195
    Abstract: A quantity of insoluble solid particles is coated with a hydratable gelling agent to produce a composition comprised of a mass of discrete solid particles which is dry and flowable. The composition is made by placing a binder on the insoluble solid particles and then, while the binder is sticky, placing a hydratable gelling agent on the sticky binder to thereby form the composition. The hydratable gelling agent on the composition, upon contact with an aqueous liquid, operates to increase the viscosity of the aqueous liquid.
    Type: Grant
    Filed: October 9, 2012
    Date of Patent: September 8, 2015
    Assignee: Fritz Industries, Inc.
    Inventors: James C. Ferrell, Jr., James J. Lavene, Trinidad Munoz, Jr.
  • Patent number: 8273406
    Abstract: This invention provides a process for coating particulate solids with a curable novolac resin without employing heat as a step of the process, comprising placing an epoxy resin which is curing on the particulate followed by placing a novolac resin capable of being heat cured on the epoxy resin before curing of the epoxy resin is complete.
    Type: Grant
    Filed: June 19, 2009
    Date of Patent: September 25, 2012
    Assignee: Fritz Industries, Inc.
    Inventors: James C. Ferrell, Jr., James J. Lavene
  • Patent number: 8273426
    Abstract: A capsule having a reactive chemical enclosed in the hollow interior thereof, and at least one coating in direct contact with and surrounding the reactive chemical, wherein the coating is a heat-cured thermosetting synthetic resin. The capsule can also include a second coating which is in direct contact with and surrounds the heat-cured thermosetting synthetic resin. The reactive chemical is not reactive with, soluble in or a solvent for the coating, or coatings, which surround the reactive chemical in the hollow interior of the capsule. The coating material is not soluble in water, but is permeable to water.
    Type: Grant
    Filed: January 10, 2007
    Date of Patent: September 25, 2012
    Assignee: Fritz Industries, Inc
    Inventors: Steven B. Laramay, James J. Lavene
  • Patent number: 7947745
    Abstract: An aqueous fluid having a viscosity greater than the viscosity of water is contacted with a water soluble material for a time and at a temperature sufficient to reduce the viscosity of the aqueous fluid to a value which is less than about 10 percent of the initial viscosity of the aqueous fluid. The water soluble material is an alkali metal peroxide or a combination of an alkali metal peroxide and a transition metal-containing compound.
    Type: Grant
    Filed: October 9, 2007
    Date of Patent: May 24, 2011
    Assignees: Fritz Industries, Inc, FMC Corporation
    Inventors: Steven B. Laramay, Charles George, Henry A. Pfeffer, III
  • Patent number: 7223827
    Abstract: A composition and a method of using the composition to adjust the permeability of a subsurface formation is disclosed. The composition is a water insoluble gel made by cross linking a water soluble polymer. The water soluble polymer is made by polymerizing a precursor composition, wherein the precursor composition is a mixture of an acrylic acid compound and a reactant comprised of a divalent metal salt of the acrylic acid compound.
    Type: Grant
    Filed: February 27, 2004
    Date of Patent: May 29, 2007
    Assignee: Fritz Industries, Inc
    Inventor: Edward E. Miller
  • Patent number: 7179485
    Abstract: This invention discloses, as an article of manufacture, a capsule having a hollow interior and an enclosing wall, referred to as a membrane. The membrane is not soluble in water, but is permeable to water or an aqueous solution. The membrane is comprised of a first material and can also include a second material. When the membrane is comprised of the first material and the second material, then it is referred to as a composite material wherein the first material forms sporting matrix having the second material fixed in the matrix. The first material is a urethane/vinyl hybrid polymer and is not soluble in, reactive with or a solvent for the second material. The second material is a particulate solid, different from the first material, and is not soluble in, reactive with or a solvent for the first material.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: February 20, 2007
    Assignee: Fritz Industries, Inc A Texas Corporation
    Inventors: John H. Schneider, Steven B. Laramay
  • Patent number: 7097773
    Abstract: This invention provides a process for reducing the concentration of chloramines, chlorine, ammonia, nitrates and nitrites in saline and fresh waters by adding to the water a treating material selected from alkali metal and alkaline earth metal formaldehydesulfoxylates in a dry or solution form.
    Type: Grant
    Filed: May 26, 2004
    Date of Patent: August 29, 2006
    Assignee: Fritz Industries, Inc.
    Inventors: Tiffani Furlough, Kevin A. Senkevech
  • Patent number: 7056868
    Abstract: Water soluble associative polymers and compositions comprising them together with alkali metal salts of carboxylic acid are disclosed. Methods comprise introducing into a wellbore a fluid comprising such associative polymers and alkali metal salts of carboxylic acid, e.g., cesium formate. Disclosed water soluble associative polymers have functionality including at least sulfonate groups, carboxylate groups and hydrophobes associative with one another in a saturated aqueous solution of an alkali metal salt of a carboxylic acid.
    Type: Grant
    Filed: July 30, 2001
    Date of Patent: June 6, 2006
    Assignees: Cabot Corporation, Fritz Industries, Inc.
    Inventors: William J. Benton, Edward E. Miller, Neil Magri, John Toups
  • Publication number: 20050130846
    Abstract: Novel polymer compositions are disclosed, along with their use as well service fluids, for example as completion fluids, work-over fluids or drilling fluids, comprising water soluble copolymers having sulfonate groups and carboxylate groups, along with alkali metal salts of carboxylic acid. Exemplary copolymer has 5 to 95 wt. % structural units derived from 2-acrylamido-2-methylpropanesulfonic acid or salt thereof, and 5 to 95 wt. % structural units derived from acrylic acid or salt thereof. A salt of the polymer may be used, such as the sodium, potassium, ammonium and calcium salts. Exemplary alkali metal salts of the polymer composition include sodium, potassium and cesium salts of formic acid and/or acetic acid in amounts suitable to develop high temperature viscosity suitable for such well servicing fluids. The polymer composition is hydrateble/soluble in a brine of sodium and/or potassium and/or cesium salts of formic and/or acetic acid.
    Type: Application
    Filed: November 14, 2003
    Publication date: June 16, 2005
    Applicants: Cabot Corporation, Fritz Industries, Inc.
    Inventors: William Benton, Edward Miller
  • Patent number: 6656989
    Abstract: Novel polymer compositions are disclosed, along with their use as well service fluids, for example as completion fluids, work-over fluids or drilling fluids, comprising water soluble copolymers having sulfonate groups and carboxylate groups, along with alkali metal salts of carboxylic acid. Exemplary copolymer has 5 to 95 wt. % structural units derived from 2-acrylamido-2-methylpropanesulfonic acid or salt thereof, and 5 to 95 wt. % structural units derived from acrylic acid or salt thereof. A salt of the polymer may be used, such as the sodium, potassium, ammonium and calcium salts. Exemplary alkali metal salts of the polymer composition include sodium, potassium and cesium salts of formic acid and/or acetic acid in amounts suitable to develop high temperature viscosity suitable for such well servicing fluids. The polymer composition is hydrateble/soluble in a brine of sodium and/or potassium and/or cesium salts of formic and/or acetic acid.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: December 2, 2003
    Assignees: Cabot Corporation, Fritz Industries, Inc.
    Inventors: William J. Benton, Edward E. Miller
  • Patent number: 6136935
    Abstract: This invention discloses a composition and a method of using the composition to cement a borehole penetrating a subsurface earth formation. The composition, the random polymerization product of two or three different vinyl-containing monomers including a vinylamide morpholine derivative, operates to reduce fluid loss from the cement slurry used to cement the borehole to the subsurface formation.
    Type: Grant
    Filed: August 12, 1999
    Date of Patent: October 24, 2000
    Assignee: Fritz Industries, Inc.
    Inventors: Rebecca G. Udarbe, Kim Hancock-Grossi
  • Patent number: 6107256
    Abstract: This invention provides a composition for and a method of using the composition to reduce the loss of liquid from aqueous compositions employed while rotary drilling. The composition of this invention comprises a polymeric material selected from homopolymers, random copolymers and random terpolymers, each of which includes a vinylamide morpholine derivative in the recipe for making the polymeric material.
    Type: Grant
    Filed: August 27, 1998
    Date of Patent: August 22, 2000
    Assignee: Fritz Industries, Inc.
    Inventors: Rebecca G. Udarbe, Kim Hancock-Grossi, Charles R. George
  • Patent number: 6089318
    Abstract: This invention discloses a polymer composition, a cement slurry containing said polymer composition and a method of using the cement slurry to cement a borehole penetrating a subsurface earth formation wherein the polymer composition is made by polymerizing a vinylamide morpholine derivative with a styrene sulfonic acid salt in the presence of a humate. The polymer composition operates to reduce fluid loss from the cement slurry to the subsurface formation.
    Type: Grant
    Filed: August 11, 1999
    Date of Patent: July 18, 2000
    Assignee: Fritz Industries, Inc.
    Inventors: Steven B. Laramay, Rebecca G. Udarbe, Charles R. George
  • Patent number: 6085840
    Abstract: This invention discloses a polymer composition, a cement slurry containing said polymer composition and a method of using the cement slurry to cement a borehole penetrating a subsurface earth formation wherein the polymer composition is made by polymerizing a vinylamide morpholine derivative and at least one branched N-vinylamide derivative in the presence of a humate. The polymer composition operates to reduce fluid loss from the cement slurry to the subsurface formation.
    Type: Grant
    Filed: June 5, 1998
    Date of Patent: July 11, 2000
    Assignee: Fritz Industries, Inc.
    Inventors: Steven B. Laramay, Rebecca G. Udarbe
  • Patent number: 6066262
    Abstract: Water having alkalies selected from sodium, potassium and mixtures thereof dissolved therein is treated with a composition to reduce the concentration of the alkalies whereby the water is rendered usable according to ASTM standards to render the water usable as concrete mix water. The composition and the method of its use is disclosed herein, wherein the composition is selected from compounds in the group consisting of lithium carbonate, acid zirconium phosphate, carbon dioxide and mixtures thereof.
    Type: Grant
    Filed: December 11, 1998
    Date of Patent: May 23, 2000
    Assignee: Fritz Industries, Inc.
    Inventors: Daniel P. Montgomery, Freda M. Bauer
  • Patent number: 5997633
    Abstract: A composition for and a method of promoting the flow of a concrete slurry through a pump and a conduit is provided. The composition is a dry particulate mixture comprised of a water soluble, inorganic material and a solvatable, organic polymer. The composition, when mixed with a suitable quantity of water, is useful in a method of priming a pump used to pump a concrete slurry. The composition, when mixed with a concrete slurry, is useful to improve the flow of the slurry through a conduit.
    Type: Grant
    Filed: September 5, 1997
    Date of Patent: December 7, 1999
    Assignee: Fritz Industries, Inc
    Inventor: Daniel P. Montgomery