Abstract: There is disclosed a multi-component system lithium phosphate compound particles having an olivine structure and represented by a general formula of LiYM11-ZM2ZPO4 in which M1 is one metal element selected from the group consisting of Fe, Mn and Co, Y is a number satisfying a formula of 0.9?Y?1.2, M2 is at least one metal element selected from the group consisting of Mn, Co, Mg, Ti and Al, and Z is an number satisfying a formula of 0<Z?0.1, wherein a concentration of the metal element M2 existing on a surface of the particle is higher than the concentration of that existing in core portion of the particle and that the concentration of the metal element M2 is continuously lowered from the surface of particle to a core portion of the particle.

Abstract: There is disclosed a lead storage battery comprising a group of plates housed in a battery jar, and an electrolyte injected therein to impregnate the group of plates with the electrolyte, thus performing formation treatment, the lead storage battery being adapted to be used in a partial state of charge where the state of charge is confined within the range of more than 70% to less than 100%, wherein the group of plates are formed of a stack constituted by a large number of negative substrates comprising grid substrates filled with a negative active material, by a large number of positive substrates comprising grid substrates filled with a positive active material, and by a porous separator interposed between the negative electrodes and positive electrodes, and the electrolyte contains at least one kind of ion selected from the group consisting of aluminum ions, selenium ions and titanium ions.

Abstract: The present invention generally relates to electrodes for use in lead-acid battery systems, batteries and electrical storage devices thereof, and methods for producing the electrodes, batteries and electrical storage devices. In particular, the electrodes comprise active battery material for a lead-acid storage battery, wherein the surface of the electrode is provided with a coating layer comprising a carbon mixture containing composite carbon particles, wherein each of the composite carbon particles comprises a particle of a first capacitor carbon material combined with particles of a second electrically conductive carbon material. The electrical storage devices and batteries comprising the electrodes are, for example, particularly suitable for use in hybrid electric vehicles requiring a repeated rapid charge/discharge operation in the PSOC, idling-stop system vehicles, and in industrial applications such as wind power generation, and photovoltaic power generation.

Abstract: The object of the present invention is to provide a lithium transition metal silicate-type cathode active material that shows superior cycle characteristics, and shows little deterioration of discharge capacity even after repeated charge-and-discharge. In the present invention, a cathode active material that is expressed by the general formula Li2-yFe1-xMxSi1-yXyO4 (M=at least one transition metal selected from the group consisting of Mn, Ti, Cr, V, Ni, Co, Cu, Zn, Al, Ge, Zr, Mo, W; X=at least one element selected from the group consisting of Ti, Cr, V, Zr, Mo, W, P, B; 0?x<1, 0?y<0.25), and contains a lithium transition metal silicate, which comprises a mixed phase of an orthorhombic-type structure with a space group Pmn21 symmetry, and a monoclinic-type structure with a space group P21/n symmetry, is provided.

Abstract: A nanosized particle has a first phase that is a simple substance or a solid solution of element A, which is Si, Sn, Al, Pb, Sb, Bi, Ge, In or Zn, and a second phase that is a compound of element D, which is Fe, Co, Ni, Ca, Sc, Ti, V, Cr, Mn, Sr, Y, Zr, Nb, Mo, Ru, Rh, Ba, lanthanoid elements (not including Ce and Pm), Hf, Ta, W or Ir, and element A, or a compound of element A and element M, which is Cu, Ag, or Au. The first phase and second phase are bound via an interface, and are exposed to the outer surface. The surface of the first phase other than the interface is approximately spherical. Furthermore, a lithium ion secondary battery includes the nanosized particle as an anode active material.

Abstract: An object of the present invention is to provide a cathode active material which contains small-particle sized and low-crystalline lithium transition metal silicate and which undergoes charge-discharge reaction at room temperature. The cathode active material for a non-aqueous electrolyte secondary battery is characterized by containing a lithium transition metal silicate and exhibits diffraction peaks having half widths of 0.175 to 0.6°, the peaks observed through powder X-ray diffractometry within a 2? range of 5 to 50°.

Abstract: There is disclosed a multi-component system lithium phosphate compound particles having an olivine structure and represented by a general formula of LiYM11-ZM2ZPO4 in which M1 is one metal element selected from the group consisting of Fe, Mn and Co, Y is a number satisfying a formula of 0.9?Y?1.2, M2 is at least one metal element selected from the group consisting of Mn, Co, Mg, Ti and Al, and Z is an number satisfying a formula of 0<Z?0.1, wherein a concentration of the metal element M2 existing on a surface of the particle is higher than the concentration of that existing in core portion of the particle and that the concentration of the metal element M2 is continuously lowered from the surface of particle to a core portion of the particle.

Abstract: Provided is a lead-based alloy for a lead-acid battery, comprising not less than 0.02% and less than 0.05% by weight of calcium, not less than 0.4% and not more than 2.5% by weight of tin, not less than 0.005% and not more than 0.04% by weight of aluminum, not less than 0.002% and not more than 0.014% by weight of barium, and the balance of lead and unavoidable impurities.

Abstract: The present invention relates to a method for producing a lead-base alloy grid for lead-acid battery having excellent mechanical strength, corrosion resistance, and growth resistance the method including heat treatment of a Pb—Ca—Sn alloy grid being subjected to natural aging for 2 to 750 hours before heat treatment.

Abstract: The present invention relates to a method for producing a lead-base alloy grid for lead-acid battery having excellent mechanical strength, corrosion resistance and growth resistance, including two-step heat treatment of a Pb—Ca—Sn alley grid containing 0.06% by mass or less of calcium, the first heat treatment being conducted at a temperature of 40° C. to 110° C., the second heat treatment being conducted at a temperature of 90° C. to 140° C., and the first heat treatment being conducted at a lower temperature than the second heat treatment.

Abstract: A method of manufacturing a lead or a lead alloy plate lattice for a lead-acid battery, featured in that a melt of lead or a lead alloy is continuously extruded under temperatures lower by 10 to 100° C. than the melting point of the lead or the lead alloy, followed by subjecting the extrudate to cold rolling under temperatures lower by 50 to 230° C. than the melting point of the lead or the lead alloy with the total draft rate set at 10 to 90% and subsequently cooling and processing the cold rolled extrudate so as to manufacture a plate lattice.

Abstract: A process for producing a lead-acid battery, in which a lead bushing cast in a lid b of an assembled lead-acid battery A and a pole inserted through an insertion hole in the lead bushing are welded together by applying a laser beam thereto. At the time of the laser welding, as desired, a jig is so placed around the lead bushing as to surround it and the laser welding is carried out.

Abstract: Provided is a lead-based alloy for a lead-acid battery, comprising not less than 0.02% and less than 0.05% by weight of calcium, not less than 0.4% and not more than 4.0% by weight of tin, not less than 0.005% and not less than 0.002% and not more than 0.014% by weight of barium, and the balance of lead and unavoidable impurities.

Abstract: Disclosed are a method of manufacturing a lead (or lead alloy) plate lattice for a lead-acid battery, featured in that a melt of lead or a lead alloy is continuously extruded under temperatures lower by 10 to 100° C. than the melting point of lead or the lead alloy, followed by subjecting the extrudate to cold rolling under temperatures lower by 50 to 230° C. than the melting point of lead or the lead alloy with the total draft rate set at 10 to 90% and subsequently cooling and processing the cold rolled extrudate so as to manufacture a plate lattice, and a lead-acid battery comprising the particular lead (or a lead alloy) plate lattice.

Abstract: In order to monitor a state of a battery, a threshold value of an internal impedance of the battery is first determined. It is prepared an approximate expression indicating a correlation between a residual capacity of the battery and an internal impedance of the battery which is greater than the threshold value. The internal impedance of the battery is then measured. When the measured internal impedance is the threshold value or less, the residual capacity is determined as an initial value. When the measured internal impedance is greater than the threshold value, the residual capacity is monitored with the approximate expression.

Abstract: This invention provides an apparatus for separating and supplying plates from a stacked plate assembly capable of highly efficiently separating and conveying one plate by one from a stacked plate assembly of a storage cell without interruption and conveying and supplementing, one by one, the separated plate to a next step with improved reliability. In this apparatus, separation suction disks (6) for sucking, separating and holding the uppermost plate P are arranged on a support table (2) at an upper end portion of an elevation rod (1a) of an elevation mechanism (1) above a stacked plate assembly (A1) for separation having a large number of plates stacked in such a fashion as to be capable of moving up and down also included are rotary bodies (13) each having rotary suction disks (12) arranged along a circumference with predetermined gaps.

Abstract: Provided is a lead-based alloy for a lead-acid battery, comprising not less than 0.02% and less than 0.05% by weight of calcium, not less than 0.4% and not more than 2.5% by weight of tin, not less than 0.005% and not more than 0.04% by weight of aluminum, not less than 0.002% and not more than 0.014% by weight of barium, and the balance of lead and unavoidable impurities.

Abstract: A process for producing a lead-acid battery, in which a lead bushing 1 cast in a lid b of an assembled lead-acid battery A and a pole 2 inserted through an insertion hole 3 in the lead bushing 1 are welded together by applying a laser beam 4b thereto. At the time of the laser welding, as desired, a jig 7 is so placed around the lead bushing 1 as to surround it and the laser welding is carried out.

Abstract: A terminal structure for a storage battery in which a plate terminal 1 includes one end plate portion 1a connected to the electrode pole H of the storage battery, and a led-out plate portion 1b led out from the electrode pole H to a notch D of a cover C. The led-out plate portion 1b is formed into a horizontal plate portion 1b1 having a bolt insertion hole 3, and a vertical plate portion 1b2 vertically bent downwards into an L-shape and having a bolt insertion hole 4; and the plate terminal 1 is mounted on a cover face d1 by the vertical plate portion 1b2; characterized in that a lower-plate portion 6 of the vertical plate portion 1b2 is provided with engagement portions 7, 7 and is pressed into a snug fit hole 8 provided in the cover C, so as to fix the respective engagement portions 7, 7 in engagement with opposing inner wall faces 8a, 8b.

Abstract: In order to monitor a state of a battery, a threshold value of an internal impedance of the battery is first determined. It is prepared an approximate expression indicating a correlation between a residual capacity of the battery and an internal impedance of the battery which is greater than the threshold value. The internal impedance of the battery is then measured. When the measured internal impedance is the threshold value or less, the residual capacity is determined as an initial value. When the measured internal impedance is greater than the threshold value, the residual capacity is monitored with the approximate expression.