Abstract: A method for flue gas denotation includes the step of, in the presence of ammonia, enabling flue gas in a denitration reactor to pass through a plurality of catalyst beds from the bottom to the top to participate in a denitration reaction. Each catalyst bed contains a catalyst support component and a granular denitration catalyst stacked on the catalyst support component, and, in every single catalyst bed, the granular denitration catalyst moves along a same direction on the catalyst support component. Between every two adjacent catalyst beds, the granular denitration catalyst falls from the tail of a previous catalyst support component to the head of a next catalyst support component, making the granular denitration catalyst travel along the catalyst support components reciprocatively.

Abstract: A method for preparing hexadecahydropyrene includes the step of carrying out the hydrogenation reaction to hydrocarbon oil containing pyrene compounds in the presence of a hydrogenation catalyst. The pyrene compounds are selected from at least one of pyrene and unsaturated hydrogenation products thereof. The hydrogenation catalyst contains a carrier and an active metal component loaded on the carrier. The active metal component is Pt and/or Pd and the carrier contains a small crystal size Y zeolite, alumina and amorphous silica-alumina. The small crystal size Y zeolite has an average grain diameter of 200-700 nm, a molar ratio of SiO2 to Al2O3 of 40-120, a relative crystallinity of ?95%, and a specific surface area of 900-1,200 m2/g. The pore volume of secondary pores in 1.7-10 nm diameter is more than 50% of the total pore volume.

Abstract: The present invention relates to the field of biotechnology, and discloses a composition capable of promoting the growth of denitrifying microorganisms and uses thereof. The composition contains a glycolipid, an alditol, and a salt of organic acid, wherein the glycolipid is at least one of trehalose glycolipid, sophorolipid and rhamnolipid. The composition provided in the present invention can promote the growth of denitrifying microorganisms, and thereby improve the denitrification activity of the denitrifying microorganisms, promote a smooth denitrification process, and shorten the processing time.

Abstract: A heavy oil hydrotreating system has a prehydrotreating reaction zone, a transition reaction zone, and a hydrotreating reaction zone that are connected in series successively, sensor units, and a control unit. In the initial reaction stage, the prehydrotreating reaction zone includes at least two prehydrotreating reactors connected in parallel, and the transition reaction zone includes or doesn't include prehydrotreating reactors; in the reaction process, the control unit controls material feeding to and material discharging from each prehydrotreating reactor in the prehydrotreating reaction zone according to pressure drop signals of the sensor units, so that when the pressure drop in any of the prehydrotreating reactors in the prehydrotreating reaction zone reaches a predetermined value, the prehydrotreating reactor in which the pressure drop reaches the predetermined value is switched from the prehydrotreating reaction zone to the transition reaction zone.

Abstract: The present invention relates to the field of isobutylene preparation. Disclosed are a catalyst and preparation method thereof, and method for preparing isobutylene by applying the same; the catalyst has a core-shell structure, the core an amorphous silica-alumina particle and/or an aggregate molding thereof, and the shell aluminum oxide comprising silicon and tin; the weight ratio of aluminum oxide comprising silicon and tin to amorphous silica-alumina is 1:60-1:3; in the aluminum oxide comprising silicon and tin, on basis of the weight of aluminum oxide comprising silicon and tin, the content of silicon is 0.5-2 wt %, and of tin is 0.2-1 wt %. The catalyst of the present invention is used to catalyze a mixture of MTBE and TBA to prepare isobutylene, enabling the MTBE cleavage and TBA dehydration reactions to be conducted simultaneously to generate isobutylene, achieving higher conversion rates of TBA and MTBE, and higher selectivity for generating isobutylene.

Abstract: The present invention relates to a method for zero-release treatment of brine waste water, comprising: (1) pretreatment; (2) reverse osmosis treatment; (3) advanced oxidation treatment; (4) biochemical treatment; (5) electrodialysis concentration; (6) circulating crystallization. Compared with the prior art, the method for zero-release treatment of brine waste water provided in the present invention realizes zero release or near zero release of waste water, improves salt recovery efficiency, can recover high-quality sodium sulfate, mirabilite and sodium chloride, and turns crystalline salts into a resource; the membrane treatment unit can operates stably in the process for a long operation period at a low cost, and the entire process has high economic efficiency.

Abstract: The present invention provides a modified composite molecular sieve, and a preparation method and an application of the modified composite molecular sieve. The modified composite molecular sieve comprises SiO2 and a composite molecular sieve that comprises molecular sieve MCM-22 and crystalline molecular sieve selected from at least one of ZSM-22, ZSM-23 and ZSM-48, wherein, the molecular sieve MCM-22 covers around the crystalline molecular sieve. The present invention further provides a catalyst and an application of the catalyst. The catalyst comprises a carrier and a noble metal loaded on the carrier, wherein, the carrier comprises a modified composite molecular sieve that is the modified composite molecular sieve provided in the present invention or the modified composite molecular sieve obtained with the method provided in the present invention.

Abstract: The present disclosure provides a hydrocracking catalyst, a method for preparing the same and a use of the same, and a method for hydrocracking catalytic diesel oil. The catalyst comprises a support, an active metal component, and carbon, wherein, based on the total weight of the catalyst, the content of the support is 60 to 90 wt %, the content of the active metal component calculated in metal oxides is 15 to 40 wt %, and the content of carbon calculated in C element is 1 to 5 wt %; measured with an infrared acidimetric estimation method, the acid properties of the hydrocracking catalyst are: the total infrared acid amount is 0.4 to 0.8 mmol/g, wherein, the infrared acid amount of strong acid with desorption temperature greater than 350° C. is 0.08 mmol/g or lower, and the ratio of the total infrared acid amount to the infrared acid amount of strong acid with desorption temperature greater than 350° C. is 5 to 50.

Abstract: A crystallization column and a crystallization method. The crystallization column comprises an upper head (1), a tower body (2) and a lower head (3), wherein a crystallization section (11) is provided with a tray (14); and the tray (14) comprises a tray plate (15) and a plurality of lower crystallization members (17). The top end of the lower crystallization member (17) can form a movable connection with the tray plate (15), so that the two adjacent lower crystallizing members (17) are capable of oscillating collisions. The tray (14) may also comprise a plurality of upper crystallization members (21) extending upwardly from the upper surface of the tray plate (15).

Abstract: Provided is a Na—Y molecular sieve and a method for preparing the Na—Y molecular sieve, an H—Y molecular sieve and a method for preparing the H—Y molecular sieve, a hydrocracking catalyst, and a hydrocracking method. The average grain diameter of the Na—Y molecular sieve is 2-5 ?m, and the sum of pore volumes of pores in 1-10 nm diameter accounts for 70-90% of the total pore volume of the Na—Y molecular sieve. The H—Y molecular sieve obtained from the large-grain Na—Y molecular sieve can be used as an acidic component in the hydrocracking catalyst. When the hydrocracking catalyst containing the H—Y molecular sieve is applied in the hydrocracking reaction of heavy oils that contain macromolecules, it can provide better cracking activity and product selectivity in the hydrocracking reaction.

Abstract: A heavy oil hydrotreating system has a prehydrotreating reaction zone, a transition reaction zone, and a hydrotreating reaction zone that are connected in series successively, sensor units, and a control unit. In the initial reaction stage, the prehydrotreating reaction zone includes at least two prehydrotreating reactors connected in parallel, and the transition reaction zone includes or doesn't include prehydrotreating reactors; in the reaction process, the control unit controls material feeding to and material discharging from each prehydrotreating reactor in the prehydrotreating reaction zone according to pressure drop signals of the sensor units, so that when the pressure drop in any of the prehydrotreating reactors in the prehydrotreating reaction zone reaches a predetermined value, the prehydrotreating reactor in which the pressure drop reaches the predetermined value is switched from the prehydrotreating reaction zone to the transition reaction zone.

Abstract: The present invention discloses a modified Y molecular sieve, a preparation method and a use of the modified Y molecular sieve, a supported catalyst, and a hydrocracking method. The silica-alumina mole ratio in the surface layer of the modified Y molecular sieve is 20-100:1, and the silica-alumina mole ratio in the body phase of the modified Y molecular sieve is 8-30:1. When a hydrocracking catalyst prepared from the modified Y molecular sieve is used for hydrocracking, the hydrocracking catalyst has higher reactivity and higher nitrogen tolerance. The hydrocracking catalyst prepared from the modified Y molecular sieve is suitable for use for increasing the yield of diesel oil, increasing the yield of chemical materials, and catalyzed hydrogenation conversion of diesel oil, etc.

Abstract: Disclosed are a beta molecular sieve, a preparation method therefor, and a hydrogenation catalyst containing same. The properties of the beta molecular sieve are as follows: the molar ratio of SiO2/Al2O3 is 30-150, the non-framework aluminum accounts for not more than 2% of the total aluminum, and the silicon atoms coordinated in a Si(OAl) structure account for not less than 95% of the silicon atoms in the framework structure. The preparation method comprises: contacting the raw material powder of the beta molecular sieve with normal pressure and dynamic water vapor, and then with ammonium fluosilicate. The beta molecular sieve of the present invention has the features of a uniform skeleton structure of silicon and aluminum, an appropriate acidity, and a reasonable pore structure, and is suitable as an acidic component of a hydro-upgrading catalyst and a hydro-cracking catalyst for diesel oil.

Abstract: Provided are a supported catalyst, a preparation method therefor and use thereof, and a method for the preparation of isobutylene from halomethane. The catalyst is characterized in that it comprises a carrier and a metallic active component supported on the carrier, wherein the metallic active component comprises zinc oxide and zinc halide. On the basis of the total amount of the catalyst, by weight content, the content of zinc oxide is 0.5%-20%, the content of zinc halide is 10%-50%, and the content of the support is 40%-88%. Compared with the prior art, the catalyst of the present invention can convert halomethane into isobutylene with a high selectivity. With the reaction for preparing of isobutylene by converting bromomethane according to the method of the present invention, the conversion of bromomethane is not less than 90% and the selectivity of isobutylene is not less than 80%.

Abstract: A dividing wall column (10), comprising: a partition plate (11) arranged along an axial direction of the dividing wall column (10); a first shaft (22) arranged along a radial direction of the dividing wall column (10), and a first splitter plate (23) with an end connected to the first shaft (22), which are both placed beneath the partition plate (11), wherein the first splitter plate (23) is configured to be pivotable around the first shaft (22), so as to control distribution of a stream from below the first splitter plate (23) into spaces formed at two sides of the partition plate (11); and a second shaft (13) arranged along the radial direction of the dividing wall column (10), and a second splitter plate (20) with an end connected to the second shaft (13), which are both placed above the partition plate (11), wherein the second splitter plate (20) is configured to be pivotable around the second shaft (13), so as to control the stream from above the second liquid splitter plate (20) into the spaces formed a

Abstract: The present disclosure provides a method for processing an acid gas, comprising: using a processor 1 for receiving and processing the acid gas to obtain a gas phase stream 1 and a liquid phase stream 2, wherein the stream 2 is partially or completely recycled to the processor 1; using a processor 2 for processing the stream 1 from the processor 1 to obtain a gas phase stream 3 and a liquid phase stream 4; using a processor 3 for processing the stream 3 from the processor 2 to obtain a gas phase stream 5 and a liquid phase stream 6; and using a processor 4 for receiving the stream 43 from the processor 2 and using the stream 43 as a processing solution for processing the stream 5 from the processor 3 to obtain a gas phase stream 7 and a liquid phase stream 8, which can be divided into two sub-streams including a stream 81 and a stream 82. The present disclosure further provides an apparatus for processing an acid gas.

Abstract: Disclosed are an associated copolymer, a method for preparation of a polymer and a polymer prepared with the method, a use of the associated copolymer and/or the polymer in drilling fluids, and a drilling fluid containing the associated copolymer and/or the polymer. The associated copolymer comprises acrylamide structural units, zwitter-ionic structural units, and cationic polyamine structural units at a specific proportion, and the cationic polyamine structural units have specific kinematic viscosity and cationic degree; thus, when the associated copolymer is used as a viscosity improver for drilling fluids, the obtained drilling fluid not only has favorable apparent viscosity after it is aged at a high temperature, but also has high dynamic shear force, and is resistant to high temperature up to 200° C. or above, resistant to NaCl up to saturated concentration, and resistant to CaCl2 up to 20 wt % concentration.

Abstract: The present invention relates to a hydrogenation catalyst composition, process for preparing the same and use thereof. The composition comprises a hydrogenation catalyst, an organonitrogen compound in an amount of 0.01%-20% by weight of the catalyst, a sulfiding agent in an amount of 30%-150% by weight of the sulfur-requiring amount calculated theoretically of the hydrogenation catalyst, and an organic solvent in an amount of 0.1%-50% by weight of the catalyst. The preparation process comprises introducing the required substances onto the hydrogenation catalyst in oxidation state. By introduction of the organonitrogen compound, sulfur and organic solvent, the hydrogenation catalyst composition of the present invention may further increase the sulfur-maintaining ratio of the catalyst during the activation, slow down the concentrative exothermic phenomenon, decrease the rate of temperature rise of the catalyst bed layer, and improve the activity of the catalyst.

Abstract: The present invention relates to a process for carrying our gas-liquid countercurrent processing comprising passing the liquid material and the gas reactant in countercurrent flow through the fixed bed of catalyst in a reactor, characterized in that the fixed bed of catalyst includes two or more catalyst layers, with the difference of voidage between the adjacent catalyst layers being at least 0.05. The voidages of the catalyst layers can be increased or decreased in the direction of the flow of the liquid phase. The process of the invention can be effected with an increased range of gas-liquid ratio and an improved stability and flexibility.

Abstract: The present invention relates to a mesoporous molecular sieve MPL-1 and its preparation process. The anhydrous composition of this molecular sieve contains at least three elements, i.e. aluminum, phosphorus and oxygen. The molecular sieve has larger pore diameters, generally 1.3 nm-10.0 nm, a larger specific surface area and adsorption capacity. It is synthesized under the hydrothermal process with an organic compound as template. Where necessary, silicon and/or titanium may be added to synthesize the aluminosilicophosphate, aluminotitanophosphate, or aluminosilicotitanophosphate molecular sieves having a mesoporous structure, and/or metal compounds may be added to synthesize derivatives of mesoporous aluminophosphate molecular sieves containing the corresponding hetero-atoms.