Abstract: A method may include drilling a wellbore, the wellbore intersecting a shale formation at an interval of the shale formation and casing at least a portion of the wellbore. The method may also include perforating the casing at the interval to fluidly couple the interval and the wellbore, and liberating free and absorbed gas entrapped within the interval. In addition, the method may include solubilizing in the wellbore fluid the free and absorbed gas, forming a plume comprising solubilized gas, and determining an identity and amount of solubilized gas in the plume.

Abstract: A suspended fluid sampling and monitoring system includes a BOP, the BOP attached to a wellhead. The BOP is positioned above a wellbore. The suspended fluid sampling and monitoring system further includes a TEC, the TEC connected to a sensor package. The TEC and sensor package extend through the BOP into the wellbore. The suspended fluid sampling and monitoring system also includes a fluid sample line, the fluid sample line extending through the BOP into the wellbore. The suspended fluid sampling and monitoring system also includes a fluid sample intake and filtration device, the fluid sample intake and filtration device mechanically coupled to the fluid sample line within the wellbore.

Abstract: A flow diversion valve comprising: a valve body including an upper housing releasably connected to a lower housing, the upper housing and lower housing being configured to receive a rotating rod therethrough; a shuttle positioned within the valve body, the shuttle being configured to move to cover one or more spill ports of the valve body; and a releasable locking member, wherein the releasable locking member is releasably connected to the valve body and positioned between the upper housing and the lower housing to assist in preventing relative movement therebetween.

Abstract: A suspended fluid sampling and monitoring system includes a BOP, the BOP attached to a wellhead. The BOP is positioned above a wellbore. The suspended fluid sampling and monitoring system further includes a TEC, the TEC connected to a sensor package. The TEC and sensor package extend through the BOP into the wellbore. The suspended fluid sampling and monitoring system also includes a fluid sample line, the fluid sample line extending through the BOP into the wellbore. The suspended fluid sampling and monitoring system also includes a fluid sample intake and filtration device, the fluid sample intake and filtration device mechanically coupled to the fluid sample line within the wellbore.

Abstract: Methods and apparatus suitable for quickly and accurately measuring 13C levels and supporting data in an aqueous fluid reservoir. Interpreting the resulting data to indicate key factors regarding a reservoir and completion methods, including reservoir constraint, gas producibility, and completion success. A sensor and to a sensing method that evaluates the level of hydrologic constraint in aquifers occurring in unconventional reservoirs, such as shales and coals is disclosed. Specifically, Raman spectroscopy is disclosed as a sensor and a sensing method that measures the level of naturally-occurring 13C in an aqueous reservoir and compares the level of 13C to the levels typical for highly constrained and highly unconstrained reservoirs. The disclosed sensor and sensing method also monitors the level of naturally-occurring 13C in a reservoir. Also disclosed is a method of using ?13CDic to evaluate geographic areas of coal bed reservoir water having biologic methanogenic activity.

Abstract: A coal seam producibility determination system may include a fiber optic cable, the fiber optic extending from a DAS interrogation unit into a wellbore. The DAS interrogation unit may be located at a surface. The wellbore may intersect a plurality of coal seams to be measured, the coal seams comprising fluid and solubilized gas. The wellbore contains wellbore fluid and the wellbore has a wall. The fiber optic cable extends along the plurality of coal seams. The coal seam producibility determination system may further include a spectrometer, the spectrometer located at the surface or within the wellbore. The coal seam producibility determination system may also include an optical window, the optical window in optical communication with the spectrometer, the optical window in fluid communication with the wellbore fluid.

Abstract: A flow diversion valve comprising: a valve body including an upper housing releasably connected to a lower housing, the upper housing and lower housing being configured to receive a rotating rod therethrough; a shuttle positioned within the valve body, the shuttle being configured to move to cover one or more spill ports of the valve body; and a releasable locking member, wherein the releasable locking member is releasably connected to the valve body and positioned between the upper housing and the lower housing to assist in preventing relative movement therebetween.

Abstract: A method may include measuring a formation sample using a Raman spectrometer to determine a formation sample characteristic, wherein the formation sample characteristic is mineral ID and distribution, carbon ID and distribution, thermal maturity, rock texture, fossil characterization, or combinations thereof.

Abstract: A multi-zone monitoring system allowing simultaneous measurement of separate zones of multi-zone wellbore formations comprising a multi-component umbilical containing both electrical lines and a hydraulic fluid lines, an inflatable isolation packer that can traverse through the wellbore and be inflated with hydraulic fluid to seal off a portion of the wellbore wherein the inflatable isolation packer is connected to a hydraulic line of the multi-component umbilical, wherein the inflatable isolation packer further comprises: one or more cable bypass feed throughs for the umbilical's electric and hydraulic fluid lines, wherein the hydraulic line is attached to the inflatable isolation packer with compression fittings.

Abstract: Methods and apparatus suitable for quickly and accurately measuring 13C levels and supporting data in an aqueous fluid reservoir. Interpreting the resulting data to indicate key factors regarding a reservoir and completion methods, including reservoir constraint, gas producibility, and completion success. A sensor and to a sensing method that evaluates the level of hydrologic constraint in aquifers occurring in unconventional reservoirs, such as shales and coals is disclosed. Specifically, Raman spectroscopy is disclosed as a sensor and a sensing method that measures the level of naturally-occurring 13C in an aqueous reservoir and compares the level of 13C to the levels typical for highly constrained and highly unconstrained reservoirs. The disclosed sensor and sensing method also monitors the level of naturally-occurring 13C in a reservoir. Also disclosed is a method of using ?13CDic to evaluate geographic areas of coal bed reservoir water having biologic methanogenic activity.

Abstract: A multi-zone monitoring system allowing simultaneous measurement of separate zones of multi-zone wellbore formations comprising a multi-component umbilical containing both electrical lines and a hydraulic fluid lines, an inflatable isolation packer that can traverse through the wellbore and be inflated with hydraulic fluid to seal off a portion of the wellbore wherein the inflatable isolation packer is connected to a hydraulic line of the multi-component umbilical, wherein the inflatable isolation packer further comprises: one or more cable bypass feed throughs for the umbilical's electric and hydraulic fluid lines, wherein the hydraulic line is attached to the inflatable isolation packer with compression fittings.

Abstract: An analytical method that establishes a thermodynamic equilibrium or known dynamic relationship between the concentrations of gases, natural gas liquids and oils or pressures of gasses in an isolated zone of a shale, or group of distinct shale gas intervals, with the concentrations of fluids or pressures of gasses in a wellbore penetrating the shale interval or intervals. An analytical method for identifying the chemical composition of gas, natural gas liquids and oils and determining their origin in an isolated zone of a shale, or group of distinct shale gas intervals with the identification of chemical composition of gas, natural gas liquids and oils in a wellbore penetrating the shale interval or intervals. A surface measurement apparatus capable of performing the measurement ex-situ. A downhole measurement apparatus capable of reliably performing the measurement in-situ and a downhole straddle-packer assembly capable of isolating part of, or an entire shale interval.

Abstract: A multi-zone monitoring system allowing simultaneous measurement of separate zones of multi-zone wellbore formations comprising a multi-component umbilical containing both electrical lines and a hydraulic fluid lines, an inflatable isolation packer that can traverse through the wellbore and be inflated with hydraulic fluid to seal off a portion of the wellbore wherein the inflatable isolation packer is connected to a hydraulic line of the multi-component umbilical, wherein the inflatable isolation packer further comprises: one or more cable bypass feed throughs for the umbilical's electric and hydraulic fluid lines, wherein the hydraulic line is attached to the inflatable isolation packer with compression fittings.

Abstract: The invention subject of this disclosure teaches a method of determining a production factor for a carbonaceous material reservoir, the method comprising: providing a well in a carbonaceous material reservoir; providing unsampled fluid at a depth in the well; placing a sensor adjacent to the unsampled fluid and performing a measurement on the unsampled fluid; using data from the measurement to determine a partial pressure of a solution gas in the carbonaceous material reservoir; and determining a production factor for the carbonaceous material reservoir from the partial pressure of the solution gas.

Abstract: An analytical method that establishes a thermodynamic equilibrium or known dynamic relationship between the concentrations of gases, natural gas liquids and oils or pressures of gasses in an isolated zone of a shale, or group of distinct shale gas intervals, with the concentrations of fluids or pressures of gasses in a wellbore penetrating the shale interval or intervals. An analytical method for identifying the chemical composition of gas, natural gas liquids and oils and determining their origin in an isolated zone of a shale, or group of distinct shale gas intervals with the identification of chemical composition of gas, natural gas liquids and oils in a wellbore penetrating the shale interval or intervals. A surface measurement apparatus capable of performing the measurement ex-situ. A downhole measurement apparatus capable of reliably performing the measurement in-situ and a downhole straddle-packer assembly capable of isolating part of, or an entire shale interval.

Abstract: The invention subject of this disclosure teaches a method of determining a production factor for a carbonaceous material reservoir, the method comprising: providing a well in a carbonaceous material reservoir; providing unsampled fluid at a depth in the well; placing a sensor adjacent to the unsampled fluid and performing a measurement on the unsampled fluid; using data from the measurement to determine a partial pressure of a solution gas in the carbonaceous material reservoir; and determining a production factor for the carbonaceous material reservoir from the partial pressure of the solution gas.

Abstract: The invention subject of this disclosure teaches a method of determining a production factor for a carbonaceous material reservoir, the method comprising: providing a well in a carbonaceous material reservoir; providing unsampled fluid at a depth in the well; placing a sensor adjacent to the unsampled fluid and performing a measurement on the unsampled fluid; using data from the measurement to determine a partial pressure of a solution gas in the carbonaceous material reservoir; and determining a production factor for the carbonaceous material reservoir from the partial pressure of the solution gas.

Abstract: The invention subject of this disclosure teaches a method of determining a production factor for a carbonaceous material reservoir, the method comprising: providing a well in a carbonaceous material reservoir; providing unsampled fluid at a depth in the well; placing a sensor adjacent to the unsampled fluid and performing a measurement on the unsampled fluid; using data from the measurement to determine a partial pressure of a solution gas in the carbonaceous material reservoir; and determining a production factor for the carbonaceous material reservoir from the partial pressure of the solution gas.

Abstract: Disclosed is a system for measuring a chemical in a subsurface formation comprising housing component traversable within the well, a guide extending down the well from a fixed location being operatively connected to the housing, a radiation source, and an optical pathway between a sample and detector wherein the detector is located at the ground surface. Also disclosed is a method for reducing long distance transmission of radiation comprising placing a radiation source in a housing, placing a housing down in a well bore, lowering a spectrometer down the well bore, and controlling movement of a spectrometer by a guide wire controller at the ground surface. Further disclosed is a method of radiating a sample comprising, transmitting the radiation through at least one optical pathway, interacting a sample with the radiation, producing characteristic radiation from the sample, and transmitting by an optical pathway to a detector located in a spectrometer.

Abstract: A measuring system for in-situ measurements down a well (1) by a spectrometer (4) is provided. The spectrometer (4) includes a radiation source (5) and a detector (6). A probe (15) optically connected to the spectrometer (4) and includes an optical pathway (7) for transmission of a radiation from the radiation source (5) and at least a second optical pathway for transmission of a characteristic radiation from a sample probe (15) near a side surface (11) of the borehole (3) and to optically couple the optical pathways (7) to the side surface (11), wherein the probe (15) is traversable up and down the well (1) by way of a guide operatively connected to the probe (15) and to a fixed location at the well head. By use of the apparatus and method a concentration of methane or other substance of interest is obtained and thereby a potential production of a coal bed methane formation is obtained.