Abstract: The present invention is directed to a method for pre-lithiation of negative electrodes during lithium loaded electrode manufacturing for use in lithium-ion capacitors. There is provided a system and method of manufacture of LIC electrodes using thin lithium film having holes therein, and in particular, to the process of manufacturing lithium loaded negative electrodes for lithium-ion capacitors by pre-lithiating electrodes with thin lithium metal films, wherein the thin lithium metal films include holes therein, and the lithium loaded negative electrodes are manufactured using a roll-to-roll lamination manufacturing process.

Abstract: A lithium-ion capacitor (LIC) is provided which includes positive electrodes, negative electrodes pre-loaded on surface with lithium sources including lithium strips and ultra-thin lithium films having holes, separators and organic solvent electrolyte with lithium salt for high performance including high energy density, high power density, long cycle life, long DC life and wide temperature ranges. A method for making an LIC is also provided, where cell components important to optimize the electrochemical performance of LIC's are configured, said components include PE active material and binders, NE active material and binders, thickness/mass ratio of positive electrode (PE) to negative electrode (NE) active layers, PE and NE's size designs and layer numbers, types of material for Separators and NE pre-lithiation methods, NE pre-lithiation includes loading various lithium (Li) sources including lithium strips and ultra-thin lithium films having holes onto the surface of NE.

Abstract: The present invention provides for two types of wide operating temperature range electrolyte formulations that contain methyl butyrate (MB) and additives have been investigated and compared in Lithium-ion capacitors (LICs), which were consisted of hard carbon (HC)/stabilized lithium metal powder (SLMP) anodes and activated carbon (AC) cathodes. The electrolyte L1 that was 1M LiPF6 in ethylene carbonate (EC)+ethyl methyl carbonate (EMC)+MB (20:20:60 v/v %)+0.1M lithium bis(oxalato)borate (LiBOB) and electrolyte L2 that was 1M LiPF6 in EC+EMC+MB (20:20:60 v/v %)+0.1M lithium difluoro(oxalato)borate (LiDFOB) enabled the LICs to discharge at the temperature as low as ?40° C., which the conventional electrolyte LP30 that was 1 M LiPF6 in EC+dimethyl carbonate (DMC) (50:50 w/w %) could not achieve. At the low temperature of ?40° C., L2 held more than 64% of the discharge capacity at 30° C., while the L1 only had the discharge capacity retention of 30%.

Abstract: The present invention provides for high performance lithium-ion capacitor laminate cells that include positive electrodes, negative electrodes and organic solvent electrolyte with lithium salt, and a method for making said high performance lithium-ion capacitor laminate cells. These high performance lithium-ion capacitor laminate cells of the present invention, include a negative electrode which is pre-doped with sufficient lithium ions by employing lithium sources including lithium powder known as SLMP or thin lithium films on the surface of negative electrodes, and this pre-doping with placing lithium sources on negative electrode surface results in LIC laminate cells with considerably higher performance in specific energy, specific power and cycle life.

Abstract: The present invention is directed to a method for pre-lithiation of negative electrodes during lithium loaded electrode manufacturing for use in lithium-ion capacitors. There is provided a system and method of manufacture of LIC electrodes using thin lithium film having holes therein, and in particular, to the process of manufacturing lithium loaded negative electrodes for lithium-ion capacitors by pre-lithiating electrodes with thin lithium metal films, wherein the thin lithium metal films include holes therein, and the lithium loaded negative electrodes are manufactured using a roll-to-roll lamination manufacturing process.

Abstract: The present invention is directed to a Process for Lithium Loaded Electrode Manufacturing for Lithium-Ion Capacitors, wherein there is provided a system of manufacture of electrodes using a lithium foil, and in particular, to the process of manufacturing lithium loaded negative electrodes for lithium-ion capacitors and the like using lithium foil, lithium strips and/or lithium films, employing a roll-to-roll manufacturing process wherein there is no drying time and no heat required to be applied to the laminator rolls, and wherein a lithium loaded negative electrode is manufactured using lithium foil strips in a roll-to-roll process, may include a top lithium strip and a bottom lithium strip on the negative electrode generated by the roll-to-roll process.

Abstract: The present invention provides for two types of wide operating temperature range electrolyte formulations that contain methyl butyrate (MB) and additives have been investigated and compared in Lithium-ion capacitors (LICs), which were consisted of hard carbon (HC)/stabilized lithium metal powder (SLMP) anodes and activated carbon (AC) cathodes. The electrolyte L1 that was 1M LiPF6 in ethylene carbonate (EC)+ethyl methyl carbonate (EMC)+MB (20:20:60 v/v %)+0.1M lithium bis(oxalato)borate (LiBOB) and electrolyte L2 that was 1M LiPF6 in EC+EMC+MB (20:20:60 v/v %)+0.1M lithium difluoro(oxalato)borate (LiDFOB) enabled the LICs to discharge at the temperature as low as ?40° C., which the conventional electrolyte LP30 that was 1 M LiPF6 in EC+dimethyl carbonate (DMC) (50:50 w/w %) could not achieve. At the low temperature of ?40° C., L2 held more than 64% of the discharge capacity at 30° C., while the L1 only had the discharge capacity retention of 30%.

Abstract: The present invention provides for high performance lithium-ion capacitor laminate cells that include positive electrodes, negative electrodes and organic solvent electrolyte with lithium salt, and a method for making said high performance lithium-ion capacitor laminate cells. These high performance lithium-ion capacitor laminate cells of the present invention, include a negative electrode which is pre-doped with sufficient lithium ions by employing lithium sources including lithium powder known as SLMP or thin lithium films on the surface of negative electrodes, and this pre-doping with placing lithium sources on negative electrode surface results in LIC laminate cells with considerably higher performance in specific energy, specific power and cycle life.