Patents Assigned to General Chemical Corporation
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Patent number: 7067100Abstract: A process for the production of liquid ferric sulfate from finely-divided ferric oxide, sulfuric acid and water in a closed reaction vessel at temperatures ranging from about 130.degree. C. to about 150.degree. C. and pressures from about 30 psi to about 70 psi. The reaction time ranges from Four to eight hours and produces liquid ferric sulfate having at least 10% trivalent iron. Yield and efficiency are provided by controlling the specific gravity prior to the reaction and by counter current cycling the waste stream from the reaction through the dilution water and use of a polymeric settling agent to remove unreacted iron content from the digester output.Type: GrantFiled: March 12, 2003Date of Patent: June 27, 2006Assignee: General Chemical CorporationInventors: Steven Faigen, Joseph Hurd, Larry Knuth
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Patent number: 6869894Abstract: A liquid form adhesive system is provided for spin-coating on wafers and mounting to rigid carrier substrates to support thinning and backside processing. The liquid adhesive comprises about 30-35% of a rosin, between 5-10% of a thermoplastic urethane, a nonionic surfactant present between 1-3%, and a trace of an ultraviolet fluorescing dye. The entire system is dissolved in 50-65%, by weight, of a dual solvent mixture composed of dimethylacetamide and propylene glycol monomethyl ether. When the mixture is made to a specific viscosity, filtered, applied by a spin-coating method to the wafer frontside surface, and cured, the result is a uniform and smooth surface of defined thickness. When the coated wafer is mounted to a rigid substrate, it may be mechanically thinned to thicknesses down to and beyond 25 um, depending upon the wafer composition, diameter, and process.Type: GrantFiled: December 20, 2002Date of Patent: March 22, 2005Assignee: General Chemical CorporationInventor: John C. Moore
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Patent number: 6805802Abstract: Process muds are de-watered by the addition of high clay alumina. The clay is mixed with plant sludges or muds so as to cause flocculation of the solid particles, and separating the water from the solid materials, as by filtration. Various polymers and/or alum process residues can be added as well. In addition to de-watering plant sludges, this method also reduces color, and reduces the total organic carbon as well as heavy metals, from the filtered water. This permits disposal of the water to public waterways with no additional treatment.Type: GrantFiled: July 25, 2002Date of Patent: October 19, 2004Assignee: General Chemical CorporationInventors: Christopher Bruce Lind, Raymond T. Pettyjohn
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Patent number: 6667021Abstract: n the manufacture of sodium carbonate having increased CO2 uptakes the carbonation reaction to form sodium bicarbonate is enhanced by the addition of particular amounts of a cationic quaternary amine, selected from the family of dialkylethoxylated quaternary salts, benzylalkyl quaternary salts, or a combination of quaternary salts from these families, to treat the 25-30% by weight sodium carbonate liquor prior to filtration. The manufactured product yields a modified sodium carbonate liquor product that, when crystallized and converted to any anhydrous product, is more readily carbonated with CO2 in the production of sodium bicarbonate. The cationic additive reacts with organic materials in the sodium carbonate liquor to form solid polymeric by-products. Thus the treatment with a cationic compound is made prior to filtering the liquor. After filtering to remove the polymeric by-products and other solid materials, the liquor is evaporated or crystallized to produce a purified and modified sodium carbonate.Type: GrantFiled: September 12, 2001Date of Patent: December 23, 2003Assignee: General Chemical CorporationInventors: Victor Eugene Braman, Marco Antonio Cortes, Stephen Tremayne Gaddis, Kenneth Douglas Boyle
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Patent number: 6551973Abstract: A stripping composition is provided for removing polymeric organic substances from an inorganic substrate. The stripping composition comprises about 3 to about 15 weight percent aromatic quaternary ammonium hydroxide, preferably benzyltrimethylammonium hydroxide (BTMAH), about 50 to about 87.5 weight percent alkylsulfoxide, a co-solvent preferably a glycol, and, desirably, a suitable corrosion inhibitor and a non-ionic surfactant. Also provided is a method for stripping polymeric organic substances (i.e., negative-tone novolak and acrylic photoresists and post-etch residue) from inorganic substrates by contacting the polymeric organic substance with the organic stripping the BTMAH composition for a period of time sufficient to remove said polymeric substances.Type: GrantFiled: October 9, 2001Date of Patent: April 22, 2003Assignee: General Chemical CorporationInventor: John Cleaon Moore
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Patent number: 6537464Abstract: A method of making poly aluminum chloride water treatment products comprising reacting an aluminum compound with a base at a temperature in the range of about 70 to 250° F., measuring the aluminum oxide content and adding water to the reaction product as needed to prepare a product having an aluminum oxide content of about 10 percent by weight of the solution.Type: GrantFiled: October 31, 2001Date of Patent: March 25, 2003Assignee: General Chemical CorporationInventors: Benjamin Shultes, III, Karen Elizabeth Ruehl, Teresa Antoinette Kristoff, Nicole Marie Gasiorowski
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Patent number: 6530343Abstract: A method of controlling ammonia levels and soluble phosphorus generated from the animal waste in milking parlors comprising applying to the parlor floor an acidic aluminum salt liquid. The treatment effective amount is effective to reduce phosphorus solubility in the manure; reduce phosphorus runoff and/or phosphorus leaching from fields fertilized with manure; inhibit ammonia volatilization from the manure; flocculate solids in the manure; reduce pathogens in the manure; increase the nitrogen content in the manure; and/or reduce acid rain associated with the manure.Type: GrantFiled: June 13, 2002Date of Patent: March 11, 2003Assignee: General Chemical CorporationInventor: Christopher B. Lind
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Patent number: 6468518Abstract: Animal enclosures such as poultry houses generate high amounts of ammonia that adversely affect weight gain and mortality or the animals, particularly among young chicks. The addition of a deliquescent salt, such as calcium chloride, to alum to treat animal waste products rapidly activates the alum to remove ammonia from the atmosphere. The ammonia sulfate by-product is useful as a nitrogen fertilizer.Type: GrantFiled: February 8, 2001Date of Patent: October 22, 2002Assignee: General Chemical CorporationInventors: Christopher Bruce Lind, Joseph Lewis Hurd, Russell Hayden Barnes
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Patent number: 6270740Abstract: An improved method of purifying sodium carbonate from a natural source whereby a dissolved sodium carbonate product is treated with a cationic compound, such as a quaternary amine, to react with carbon-containing contaminants and filtering the product. The filtered modified sodium carbonate solution is then crystallized and dried. The modified sodium carbonate has a greater reactivity or uptake of carbon dioxide for the manufacture of sodium bicarbonate than conventional sodium carbonates.Type: GrantFiled: September 9, 1999Date of Patent: August 7, 2001Assignee: General Chemical CorporationInventors: James Milo Shepard, Victor Eugene Braman, Kenneth Douglas Boyle, Carter Jay Moore
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Patent number: 6165369Abstract: Stable suspensions can be made from acidic metal salt solutions and finely divided acid-insoluble solid particles that have a particle size of less than twenty-five microns, preferably less than ten microns, and most preferably, about one micron. These suspensions can be used to treat surface waters to remove organic materials therefrom. The suspension forms a floc that includes the solid particles and organic materials, which floc rapidly settles out of solution, leaving purified water as the supernatant liquid.Type: GrantFiled: June 16, 1999Date of Patent: December 26, 2000Assignee: General Chemical CorporationInventors: James Nelson Tanis, Jawahar Chunilal Parekh
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Patent number: 6075212Abstract: An apparatus and method for accurately weighing a rail car coupled to other rail cars without uncoupling the rail car to be weighed includes a hydraulically operated positioning device assembly with opposed pushers that can be elevated to hold the axle of a rail car uptrack of the car to be weighed, a scale mounted downtrack of the rail car positioning device, and a car stop mounted downtrack of the scale that can be elevated to block the wheels of a car downtrack of the car being weighed.The rail car positioning device engages the car uptrack of the car to be weighed, moves the car to be weighed over the scale, and, by reversibly moving the car, centers the car over the scale. The car stop then engages the downtrack car to maintain it and other cars coupled to it downtrack in a fixed position during weighing and filling of the car on the scale. The carriage assembly then releases the car on the scale and moves uptrack where it acquires a hold on the next empty car.Type: GrantFiled: September 11, 1998Date of Patent: June 13, 2000Assignee: General Chemical CorporationInventors: Mark Alan Lee, Stephen Tremayne Gaddis
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Patent number: 5938970Abstract: Polynucleate metal hydroxide anionic compounds and method for their production. The compounds have the formula:M.sub.a N.sub.b (OH).sub.c X.sub.d Y.sub.e Z.sub.f.(H.sub.2 O).sub.gwhereinM is a tri- or more valent metal ion;N is a divalent metal ion that forms a soluble salt with anions X, Y or Z;OH represents the level of basicity;X is a monovalent anion;Y is a divalent anion;Z is a trivalent anion;a is 1;b is from 0.15 to 2.0;c is from 0.3 to 5;d is from 0 to 3;e is from 0.1 to 2.25;f is from 0 to 1; andg is greater than 4 where the compound is in the form of an aqueous solution, or from 0 to 20 where the compound is not in the form of an aqueous solution. The compounds are useful for water treatment for removal of suspended solids and for various applications in the paper industry.Type: GrantFiled: June 11, 1997Date of Patent: August 17, 1999Assignee: General Chemical CorporationInventors: Phillip B. Reilly, Jr., P. Brennan Reilly, III
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Patent number: 5935487Abstract: The addition of an effective amount of a liquid modified diethanolamide to a calcium chloride composition, which can be a brine solution or a solid, reduces the amount of corrosion of metals by the resulting composition. The calcium chloride/diethanolamide composition can be used as a deicer composition.Type: GrantFiled: August 4, 1998Date of Patent: August 10, 1999Assignee: General Chemical CorporationInventors: John Scott Beazley, William Edward Sadar, Douglas Robert Maynes, Mark G. Jantzen
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Patent number: 5919377Abstract: A railroad tank car can be filled with a slurry of a solid and a solvent therefor. The tank car is fitted with a feed distribution header that is provided with a plurality of predetermined spaced openings. The header is mounted in the car so that after the solids have settled, the solids are located below the distribution header and the supernatant liquid is above the distribution header. The supernatant liquid can then be withdrawn from the tank car through the distribution header and flows back to a storage tank from where it came. All of this can be accomplished with a single pump. Removing or unloading of solids from the car is effected by rendering the solids flowable with a liquor and pumping the solids from the car or dissolving them.Type: GrantFiled: October 31, 1996Date of Patent: July 6, 1999Assignee: General Chemical CorporationInventors: Andrew Chisholm, Samuel Louis Bean, Mark David Dulik, Peter Anthony Monopoli
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Patent number: 5840207Abstract: The addition of an effective amount of a liquid modified diethanolamide which is suitably a reaction product of cocoamide and phthalic anhydride to a calcium chloride composition, which can be a brine solution or a solid, reduces the amount of corrosion of metals by the resulting composition. The calcium chloride/diethanolamide composition can be used as a deicer composition.Type: GrantFiled: August 22, 1996Date of Patent: November 24, 1998Assignee: General Chemical CorporationInventors: John Scott Beazley, William Edward Sadar, Douglas Robert Maynes, Mark G. Jantzen
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Patent number: 5830522Abstract: Shrimp and other seafood can be preserved to extend their freshness shelf life by immersing them in an aqueous solution prepared by dissolving a dry mixture containing sodium metabisulfite with from 30 to 50% by weight of sodium sulfite. These solutions have excellent preservative action yet have very little or no odor of sulfur dioxide. The solutions are useful in a concentration of up to about 3% by weight.Type: GrantFiled: October 10, 1996Date of Patent: November 3, 1998Assignee: General Chemical CorporationInventor: Samuel Louis Bean
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Patent number: 5766485Abstract: Alum process residues (APR) are used to remove colored contaminants from waste waters. In addition, in accordance with the invention, up to 0.1% by weight of alum and up to 5 ppm of a polyelectrolyte polymer is added to improve color removal, turbidity removal and the settling rate. The resultant APR-alum-polymer mixture together with contaminants in the waste water settles rapidly, reducing the costs of the color removal process.Type: GrantFiled: June 6, 1995Date of Patent: June 16, 1998Assignee: General Chemical CorporationInventors: Christopher Bruce Lind, David Kisling Kennedy
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Patent number: 5755858Abstract: A topsoil composition comprising an alumina clay, an organic compost and sand effective to nurture and sustain plants. The proportions of the ingredients are chosen to provide good nutrients to plants, good water retention and good water drainage properties, and generally comprise at least 20 percent by volume of each ingredient, and typically comprises about 25 percent by volume of alumina clay, up to 30 percent by volume of compost and about 45 percent by volume of sand.Type: GrantFiled: December 9, 1996Date of Patent: May 26, 1998Assignee: General Chemical CorporationInventor: Jack Williams Barnett
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Patent number: 5636449Abstract: A tube dryer system is used to remove moisture from solid commercial products. The present apparatus includes a condensate vessel that separates condensed steam from excess steam. The excess steam is passed through a thermocompressor and combined with incoming fresh steam to produce a combined steam feed stream having a higher flow rate at only slightly reduced pressure and reduced superheat content, resulting in increased dryer capacity and reduced steam losses with no increase in energy costs.Type: GrantFiled: October 26, 1995Date of Patent: June 10, 1997Assignee: General Chemical CorporationInventors: Stephen T. Gaddis, Thomas B. Barker
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Patent number: 5573674Abstract: A stable activated silica sol is made by reacting sodium aluminum sulfate and a solution of silica. This solution removes suspended particles from aqueous streams rapidly and effectively. The silica sol is stable for many days and thus can be prepared off-site and transported to the point of use. Further, the activated silica or colloidal silica sol solution of the invention can be continuously added to water and waste water streams, or paper making pulps, stocks and furnishes, without danger of solidifying in the transport systems.Type: GrantFiled: October 27, 1995Date of Patent: November 12, 1996Assignee: General Chemical CorporationInventors: Christopher B. Lind, Michael A. Ware