Abstract: A melamine-containing resin modified with a cyclic urea prepolymer comprising urea, formaldehyde and ammonia or a primary amine. The prepolymer-modified melamine-containing resin provides useful binders alone, or when combined or coreacted with other resins. Products prepared with the binder include wood composites such as particleboard and medium density fiberboard.
Type:
Grant
Filed:
June 23, 1999
Date of Patent:
June 4, 2002
Assignee:
Georgia-Pacific Resins, Inc.
Inventors:
Pablo G. Dopico, Brian M. Peek, Benjamin D. Gapud, Kelly A. Shoemake, James C. Phillips
Abstract: The preparation of phenol-formaldehyde and melamine-formaldehyde resin-based binders extended with a cyclic urea-formaldehyde prepolymer and to products prepared using the binders. More particularly, the invention relates to a cyclic urea prepolymer comprising urea, formaldehyde, and ammonia or a primary amine which, when added to a phenol-formaldehyde or melamine-formaldehyde based resin, results in a useful binder for the manufacturer numerous articles.
Type:
Application
Filed:
September 7, 2001
Publication date:
May 9, 2002
Applicant:
Georgia-Pacific Resins, Inc.
Inventors:
F. C. Dupre, Millard E. Foucht, William P. Freese, Kurt D. Gabrielson, Benjamin D. Gapud, W. Hayes Ingram, Ted M. McVay, Richard A. Rediger, Kelly A. Shoemake, Kim K. Tutin, James T. Wright
Abstract: The preparation of phenol-formaldehyde and melamine-formaldehyde resin-based binders extended with a cyclic urea-formaldehyde prepolymer and to products prepared using the binders. More particularly, the invention relates to a cyclic urea prepolymer comprising urea, formaldehyde, and ammonia or a primary amine which, when added to a phenol-formaldehyde or melamine-formaldehyde based resin, results in a useful binder for the manufacturer numerous articles.
Type:
Grant
Filed:
September 7, 2001
Date of Patent:
April 30, 2002
Assignee:
Georgia-Pacific Resins, Inc.
Inventors:
F. C. Dupre, Millard E. Foucht, William P. Freese, Kurt D. Gabrielson, Benjamin D. Gapud, W. Hayes Ingram, Ted M McVay, Richard A. Rediger, Kelly A. Shoemake, Kim K. Tutin, James T. Wright
Abstract: The preparation of phenol-formaldehyde and melamine formaldehyde resin-based binders extended with a cyclic urea-formaldehyde prepolymer and to products prepared using the binders. More particularly, the invention relates to a cyclic urea prepolymer comprising urea, formaldehyde, and ammonia or a primary amine which, when added to a phenol-formaldehyde or melamine-formaldehyde based resin, results in a useful binder for the manufacturer numerous articles.
Type:
Grant
Filed:
December 14, 2000
Date of Patent:
April 9, 2002
Assignee:
Georgia-Pacific Resins, Inc.
Inventors:
Frederick C. Dupre, Millard E. Foucht, William P. Freese, Kurt D. Gabrielson, Benjamin D. Gapud, W. Hayes Ingram, Ted M McVay, Richard A. Rediger, Kelly A. Shoemake, Kim K. Tutin, James T. Wright
Abstract: A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness.
Type:
Grant
Filed:
August 28, 2000
Date of Patent:
September 18, 2001
Assignee:
Georgia-Pacific Resins, Inc.
Inventors:
Rajan Hariharan, David A. Hutchings, Kenneth A. Bourlier, Ellen V. Nagy
Abstract: The preparation of phenol-formaldehyde and melamine-formaldehyde resin-based binders extended with a cyclic urea-formaldehyde prepolymer and to products prepared using the binders. More particularly, the invention relates to a cyclic urea prepolymer comprising urea, formaldehyde, and ammonia or a primary amine which, when added to a phenol-formaldehyde or melamine-formaldehyde based resin, results in a useful binder for the manufacturer numerous articles.
Type:
Grant
Filed:
June 22, 2000
Date of Patent:
June 12, 2001
Assignee:
Georgia-Pacific Resins, Inc.
Inventors:
F. C. Dupre, Millard E. Foucht, William P. Freese, Kurt D. Gabrielson, Benjamin D. Gapud, W. Hayes Ingram, Ted M. McVay, Richard A. Rediger, Kelly A. Shoemake, Kim K. Tutin, James T. Wright
Abstract: An aqueous composition containing a hardenable binder of a melamine compound, such as an acid-hardenable melamine-formaldehyde resin, and an acidic phosphorus compound, such as a nitrogen-containing phosphorus compound made from either phosphoric acid or phosphorus acid, and expandable graphite flake, which composition is curable to an intumescent composition.
Type:
Grant
Filed:
January 2, 1998
Date of Patent:
May 8, 2001
Assignees:
Graftech Inc., Georgia-Pacific Resins Inc.
Inventors:
Brian M. Ford, David A. Hutchings, Mel E. Foucht, Shahid P. Qureshi, Chad E. Garvey, Daniel W. Krassowski
Abstract: The preparation of phenol-formaldehyde and melamine-formaldehyde resin-based binders extended with a cyclic urea-formaldehyde prepolymer and to products prepared using the binders. More particularly, the invention relates to a cyclic urea prepolymer comprising urea, formaldehyde, and ammonia or a primary amine which, when added to a phenol-formaldehyde or melamine-formaldehyde based resin, results in a useful binder for the manufacturer numerous articles.
Type:
Application
Filed:
December 14, 2000
Publication date:
April 12, 2001
Applicant:
Georgia-Pacific Resins, Inc.
Inventors:
F. C. Dupre, Millard E. Foucht, William P. Freese, Kurt D. Gabrielson, Benjamin D. Gapud, W. Hayes Ingram, Ted M. McVay, Richard A. Rediger, Kelly A. Shoemake, Kim K. Tutin, James T. Wright
Abstract: A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness.
Type:
Grant
Filed:
June 22, 1999
Date of Patent:
December 26, 2000
Assignee:
Georgia-Pacific Resins, Inc.
Inventors:
Rajan Hariharan, David A. Hutchings, Kenneth A. Bourlier, Ellen V. Nagy
Abstract: A single package, ready-to-use (RTU) resin/wax emulsion adhesive and a method of preparing the same by heating a thermosetting resin and adjusting the pH of the wax emulsion prior to combining the resin and wax emulsion. The use of the adhesive in making bonded composites such as wood products, including oriented strand board (OSB), parallel strand lumber, wafer board and particle board composites.
Type:
Grant
Filed:
March 3, 1997
Date of Patent:
October 17, 2000
Assignee:
Georgia-Pacific Resins, Inc.
Inventors:
Brian M. Peek, Barry W. Sewell, Roger Scott Johnson, Daniel DiCarlo
Abstract: The preparation of phenol-formaldehyde and melamine-formaldehyde resin-based binders extended with a cyclic urea-formaldehyde prepolymer and to products prepared using the binders. More particularly, the invention relates to a cyclic urea prepolymer comprising urea, formaldehyde, and ammonia or a primary amine which, when added to a phenol-formaldehyde or melamine-formaldehyde based resin, results in a useful binder for the manufacturer numerous articles.
Type:
Grant
Filed:
December 17, 1998
Date of Patent:
September 5, 2000
Assignee:
Georgia-Pacific Resins, Inc.
Inventors:
F. C. Dupre, Millard E. Foucht, William P. Freese, Kurt D. Gabrielson, Benjamin D. Gapud, W. Hayes Ingram, Ted M. McVay, Richard A. Rediger, Kelly A. Shoemake, Kim K. Tutin, James T. Wright
Abstract: An intumescent composition comprising the dried product of a composition containing as essential components (1) the reaction product of aluminum oxide or aluminum hydroxide hydrate and an organic amine phosphate or a salt thereof, and (2) expandable graphite flake.
Type:
Grant
Filed:
March 6, 1998
Date of Patent:
August 15, 2000
Assignee:
Georgia-Pacific Resins, Inc.
Inventors:
David A. Hutchings, Shahid P. Qureshi, Millard E. Foucht, Richard D. Sampson, Ted M. McVay
Abstract: A process for disproportionating rosins using iodide catalysts. In one embodiment, a tall oil rosin is heated in the presence of a lithium iodide catalyst. In another embodiment, a catalyst system is formed from a mixture of lithium iodide and ferrous iodide. The mixed catalyst system completes disproportionation of tall oil rosin in about three hours. Phosphoric acid may be added to remove iron colored impurities when using the mixed catalyst system. Another aspect of the invention involves preparing a soap from the disproportionated rosin by adding a defoamer and a base, such as potassium hydroxide.
Abstract: An aqueous binder composition containing a urea-formaldehyde resin modified with a water-soluble styrene-maleic anhydride copolymer is used in the preparation of fiber mats.
Type:
Grant
Filed:
January 4, 1999
Date of Patent:
July 4, 2000
Assignee:
Georgia-Pacific Resins, Inc.
Inventors:
Shau-Gan Chang, Larry R. Graves, Charles R. Hunter, Stacey L. Wertz
Abstract: A phenolic resin modified with an alkali salt of sulfite or bisulfite in order to provide compatibility with a wax emulsion sizing agent, an adhesive prepared from the phenolic resin and wax emulsion, and the use of the adhesive in making bonded composites such as wood products, including, parallel strand lumber, oriented strand board (OSB), laminated veneer lumber (LVL), medium density fiberboard, wafer board and particle board, and textile products.
Abstract: Modified melamine-formaldehyde resins prepared by reacting melamine with formaldehyde at a F:M molar ratio in the range of about 1.55:1-2.5:1 under alkaline conditions, wherein the resin is prepared in the presence of about 1-10 wt % dicyandiamide and about 1-10 wt % sorbitol based on the total weight of resin solids. The resins are used to impregnate substrates in the preparation of decorative laminates. The laminates can be used to produce, for example, furniture, countertops or flooring.
Type:
Grant
Filed:
January 14, 1998
Date of Patent:
December 14, 1999
Assignee:
Georgia-Pacific Resins, Inc.
Inventors:
Benjamin D. Gapud, Mary K.A. Shoemake, Eric A. Searcy
Abstract: An aqueous composition containing an acid-hardenable melamine-formaldehyde resin and a nitrogen-containing acidic phosphorus curing agent made from either phosphoric acid or phosphorous acid which is curable to an intumescent composition.
Abstract: The invention is directed to a stable phenolic dispersion of hydrophilic phenolic resin polymer using polyvinyl alcohol as protective colloid. Incorporation of a small proportion of an etherified bisphenol-A resin into an aqueous solution of a phenolic resin and a protective colloid (e.g., polyvinyl alcohol) forms a stable dispersion with low volatile organics content.