Abstract: Embodiments of a system, method and apparatus incorporate two-stage identification of targets in hyperspectral image analysis. In various embodiments, unmixing is employed that integrates F-test and model averaging approaches. Further, a multi-tier target library process provides an improvement in the spectra that can be used to detect target materials and spectra that can be used for unmixing in identification. Additionally, the hierarchical identification of the present disclosure combines probabilities from model averaging to generate target identifications simultaneously at multiple levels of specificity.