Abstract: Methods are provided for the removal of sulfur and other ARD/AMD-generating materials through the smoldering combustion of an organic material. The methods comprise admixing an ARD/AMD-generating porous matrix material with an organic material to produce a mixture, exposing the mixture to an oxidant, and initiating a self-sustaining smoldering combustion of the mixture. Additional embodiments aggregate the organic material or ARD/AMD-generating porous matrix material or mixture thereof in an impoundment such as a reaction vessel, depression or matrix pile. Further embodiments utilize at least one heater to initiate combustion and at least one air supply port to supply oxidant to initiate and maintain combustion.

Abstract: A method for remediating contaminated soil and groundwater includes selecting a treatment material and creating a smolderable mixture of a contaminant, the treatment material, and soil.

Abstract: A method for remediating a contaminated porous matrix including selecting the type and quantity of organic fuel to create a smolderable mixture of the organic fuel and contaminated porous matrix, and controlling the rate of oxidant addition to manipulate the relative proportions of oxidative breakdown products, non-oxidative breakdown products, and non-destructive remediation processes. The method further involves collecting the volatilized contaminant, and any gaseous breakdown products of the contaminant.

Abstract: A method for remediating contaminated soil and groundwater includes selecting a treatment material and creating a smolderable mixture of a contaminant, the treatment material, and soil.

Abstract: In some embodiments, the invention provides a method for converting of a flue gas desulfurization (FGD) waste product to a gypsum-enriched product by fostering growth of sulfur oxidizing bacteria (SOB) in the FGD waste product. Also provided are isolated sulfur oxidizing bacteria cultures as well as kits comprising an isolated sulfur oxidizing bacteria culture and written instructions for fostering the growth of the isolated sulfur oxidizing bacteria culture in FGD waste product to product a gypsum-enriched product.

Abstract: Methods are provided for generating or recovering gaseous materials such as hydrogen and solids such as metals through the smoldering combustion of an organic material. The methods include admixing a porous matrix material with an organic material, and, in some embodiments a catalyst, to produce a porous mixture. The mixture is exposed to an oxidant, initiating a self-sustaining smoldering combustion of the mixture, and collecting the vapors and combustion products or processing the porous matrix following combustion to physically separate the porous matrix material from ash containing inorganic materials of value. Additional embodiments aggregate the organic material or catalyst or porous matrix material or mixture thereof in an impoundment such as a reaction vessel, lagoon or matrix pile. Further embodiments utilize at least one heater to initiate combustion and at least one air supply port to supply oxidant to initiate and maintain combustion.

Abstract: A method destroys organic liquid contaminants contained in a plurality of below-ground volumes by smoldering combustion. The method applies heat to at least a portion of a first one of the volumes of organic liquid and forces oxidant into the first volume of organic liquid so as to initiate self-sustaining smoldering combustion of the first volume of organic liquid. The method may terminate the heat applied to the first volume of organic liquid. Next, the method modulates the flow of the oxidant into the first volume of organic liquid so as to cause at least a portion of the first volume of organic liquid to migrate and come into contact with another one of the volumes of organic liquid, so as to propagate the smoldering combustion. In an alternative embodiment, the flow of the oxidant may be modulated to establish a substantially stationary combustion front.

Abstract: A device and method to quantitatively measure concentrations of volatile organic compound vapors below the ground surface using a preferably “fully” passive device that is placed in a drilled or bored hole for a specified period of time, wherein the sampler constrains the uptake rate to match values that minimize or eliminate the starvation effect and provide acceptable sensitivity for most soil types as calculated via mathematical models.

Abstract: The invention provides a device and method to quantitatively measure concentrations of volatile organic compound vapors below the ground surface using a preferably “fully” passive device that is placed in a drilled or bored hole for a specified period of time, wherein the sampler constrains the uptake rate to match values that minimize or eliminate the starvation effect and provide acceptable sensitivity for most soil types as calculated via mathematical models.

Abstract: A method for remediating contaminated soil includes adding a heat-activated oxidizing agent into the soil; exposing the soil to direct current through a first set of electrodes so as to cause migration of the oxidizing agent through the soil and pore water contained in the soil; and exposing the soil to alternating current through a second set of electrodes so as to heat the soil and thus to activate the oxidizing agent. The first and second sets of electrodes are optionally the same set.

Abstract: There is provided a method for achieving oxidation of organic contaminants held in low permeability soil and its contained pore water. The method comprises the supply and electromigration of an oxidant throughout the soil and pore water by means of an applied direct current via electrodes arrayed within the soil, followed by the heating of the soil by an applied alternating current using the identical electrodes.

Abstract: In a water storage system with water conduits, water pumps, drain valves, discharge valves, for storing a first volume of water, a method of maximizing water availability monitors a second volume of water within the system. Data regarding forecasted precipitation predicted to occur at some point in the future, including a predicted duration, intensity and volume are received and an expected time-dependent volume of water to be added to the system during the forecasted precipitation is estimated. If at least one of: a first sum of the predicted volume and the second volume and a second sum of the expected time-dependent volume and the second volume is greater than the first volume then the water pumps, drain valves, and discharge valves are controlled to discharge water until each of the first and second sums is not greater than the first volume.

Abstract: Methods are provided for the volumetric reduction of organic liquids. The methods comprise admixing a porous matrix material with an organic liquid to produce a mixture, forcing oxidant through the mixture, and initiating a self-sustaining smoldering combustion of the mixture. Additional embodiments aggregate the organic liquid or porous matrix material or mixture thereof in an impoundment such as a reaction vessel, lagoon or matrix pile. Further embodiments utilize at least one heater to initiate combustion and at least one air supply port to supply oxidant to initiate and maintain combustion. Yet further embodiments comprise the batch addition of a fuel additive to the aggregate prior to smoldering to ensure that the ensuing smoldering combustion is self-sustaining or of the required temperature to reduce or remove other contaminants in the matrix or organic liquid such as heavy metals or asbestos.

Abstract: Subterranean gases are removed from a building site by drawing air from ambience and passing the air through an air permeable bed of materials (10) located at the site as a diffused air stream. The subterranean gases become entrained in the diffused air stream which is then exhausted from the bed and removed from the site. A system for practicing the method has slotted air injection conduits (12) interspersed between slotted air extraction conduits (15) embedded in an air permeable bed of materials beneath the building. The system has a blower (18) for drawing air from the extraction conduits and removing it from the site.

Abstract: Subterranean gases are removed from a building site by drawing air from ambience and passing the air through an air permeable bed of materials (10) located at the site as a diffused air stream. The subterranean gases become entrained in the diffused air stream which is then exhausted from the bed and removed from the site. A system for practicing the method has slotted air injection conduits (12) interspersed between slotted air extraction conduits (15) embedded in an air permeable bed of materials beneath the building. The system has means (18) for drawing air from the extraction conduits and removing it from the site.