Patents Assigned to Gipelec
  • Patent number: 4478920
    Abstract: The electrolyte is constituted by a conductive vitreous compound having the formula aP.sub.2 S.sub.5, bLi.sub.2 S, cLiX, where X represents chlorine, bromine, or iodine, and where a, b, and c are numbers chosen so that the ratio b/(a+b) lies between 0.61 and 0.70, and so that the ratio c/(a+b+c) is less than or equal to a limit corresponding to the solubility in vitreous phase of LiX in the compound aP.sub.2 S.sub.5, bLi.sub.2 S, with the positive active material comprising 20% to 80% by volume solid electrolyte together with an electron conductor, the improvement wherein a substance chosen from the halogens and the chalcogens is included in the electrolyte in order to produce an in situ chemical reaction at the lithium electrolyte interface thereby creating an ionically conductive bonding layer comprising a lithium halogenide or chalcogenide.
    Type: Grant
    Filed: April 13, 1983
    Date of Patent: October 23, 1984
    Assignee: GIPELEC
    Inventors: Jean-Paul Gabano, Jean-Pierre Duchange
  • Patent number: 4448864
    Abstract: A lithium - manganese dioxide cell in which a certain quantity of copper oxyphosphate is added to the manganese dioxide to obtain a second discharge voltage plateau for use in detecting the end of cell life before it is too late.
    Type: Grant
    Filed: July 22, 1983
    Date of Patent: May 15, 1984
    Assignee: Societe Anonyme dite: GIPELEC
    Inventor: Michel Broussely
  • Patent number: 4444857
    Abstract: An electrochemical cell having a lithium based negative active material, an electrolyte in the form of a vitreous cation conductive compound having a formula: aP.sub.2 S.sub.5, bLi.sub.2 S, cLiX, where X stands for chlorine, bromine or iodine, and a, b, and c are numbers chosen in such a manner that b/(a+b) lies in the range 0.61 to 0.70 and c/(a+b+c) is less than or equal to the maximum solubility in the vitreous phase of LiX in the compound aP.sub.2 S.sub.5, bLi.sub.2 S, and a positive active material in the form of a compressed powder with particles of the electrolyte dispersed throughout said positive active material. The positive active material is chosen from the group constituted by: (CH.sub.x ; Cu.sub.d O(PO.sub.4).sub.2 ; V.sub.6 O.sub.13 ; V.sub.2 S.sub.5 ; MoS.sub.3 ; CuS; S; CuO; Cu.sub.3 B.sub.2 O.sub.6 ; FeS.sub.2 ; Pb.sub.3 O.sub.4 ; Bi.sub.2 O.sub.3 ; PbO; BiO(CrO.sub.4).sub.2 ; AgBi(CrO.sub.4).sub.2 ; I.sub.2 ; MoO.sub.3 ; WO.sub.3 ; TiS.sub.2 ; NiPS.sub.
    Type: Grant
    Filed: June 8, 1982
    Date of Patent: April 24, 1984
    Assignee: Societe Anonyme dite: GIPELEC
    Inventors: Jean-Pierre Duchange, Jean-Paul Gabano
  • Patent number: 4438184
    Abstract: The sealing between the terminal (1) and the metal wall (2) is provided by a glass seal (3). At least that portion of the terminal which comes into contact with the glass seal is covered with a layer of at least one electrically insulating oxide (4).
    Type: Grant
    Filed: July 12, 1982
    Date of Patent: March 20, 1984
    Assignee: Gipelec
    Inventor: Bernard Chenaux
  • Patent number: 4375502
    Abstract: An electrolyte for an electric cell whose negative active material (4) is constituted by lithium and whose positive active material is constituted by thionyl chloride. The electrolyte contains at least one solvent and at least one solute, said solvent being thionyl chloride and said solute being chosen from the group which includes lithium tetrachloroaluminate and lithium hexachloroantimonate. According to the invention said electrolyte further includes a complex chosen from the group which includes AlCl.sub.3,So.sub.2 and SbCl.sub.5,SO.sub.2.The voltage rise of electric cells which include such an electrolyte takes negligible time. Figure to be published: FIG. 1.
    Type: Grant
    Filed: April 30, 1981
    Date of Patent: March 1, 1983
    Assignee: Societe Anonyme dite: GIPELEC
    Inventor: Jean-Paul Gabano
  • Patent number: 4371592
    Abstract: A primary cell of high specific energy in which the anode active material (16) is an alkali metal and the cathode active material is sulphur oxychloride which simultaneously acts as an electrolyte solvent, said electrolyte further containing a dissolved salt and a co-solvent. The co-solvent is chosen from among phosphoryl chloride and benzoyl chloride; the dissolved salt is lithium tetrachloroaluminate.
    Type: Grant
    Filed: March 16, 1981
    Date of Patent: February 1, 1983
    Assignee: Gipelec
    Inventor: Jean-Paul Gabano
  • Patent number: 4331750
    Abstract: A cation conductive vitreous alkaline composition and a method of preparing such a composition.The composition corresponds to a formula of aP.sub.2 S.sub.5, bLi.sub.2 S, cLiX, where:X represents chlorine, bromine or iodine;c is greater than or equal to 0;the ratio b/(a+b) lies between 0.61 and 0.70; andthe ratio c/(a+b+c) is less than or equal to a limitwhich corresponds to solubility in the vitreous phase of LiX in the composition aP.sub.2 S.sub.5, bLi.sub.2 S.
    Type: Grant
    Filed: January 19, 1981
    Date of Patent: May 25, 1982
    Assignee: Societe Anonyme dite: GIPELEC
    Inventors: Jean-Pierre Malugani, Guy Robert
  • Patent number: 4303743
    Abstract: The cell includes a positive electrode (3), a negative electrode (4) and an expansion space (15), the gelled electrolyte (5) being disposed between the two electrodes firstly in contact with their electrochemical exchange surfaces and secondly between the negative electrode (4) and the expansion space (15).The surface (14) of the electrolyte (5) in the expansion space is covered partially with a plate (18) which exerts a pressure on the electrolyte (5), which pressure presses the electrolyte closely against the surfaces of the electrodes (3, 4).
    Type: Grant
    Filed: December 16, 1980
    Date of Patent: December 1, 1981
    Assignee: Societe Anonyme dite: GIPELEC
    Inventor: Jean-Marie Reau
  • Patent number: 4268588
    Abstract: The invention relates to a solid positive active material for electric cells whose negative active material is an alkali metal. In accordance with the invention, said positive material is a compound formed by two oxides, namely, bismuth oxide Bi.sub.2 O.sub.3 and cupric oxide CuO. Application to lithium cells.
    Type: Grant
    Filed: November 20, 1979
    Date of Patent: May 19, 1981
    Assignee: Gipelec
    Inventors: Andre Lecerf, Michel Broussely
  • Patent number: D283646
    Type: Grant
    Filed: October 25, 1983
    Date of Patent: April 29, 1986
    Assignee: Gipelec, S.A.
    Inventors: Alain Battarel, Jean-Marc Picard