Patents Assigned to Giulini Chemie GmbH
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Publication number: 20150064119Abstract: The invention relates to a cosmetic formulation comprising an additive agent. The additive agent having a water soluble linear alkali polyphosphate with a chain length of at least 4 to 50. The alkali polyphosphate exhibits complexing, dispersing, and antimicrobial effects. The alkali polyphosphate has a pH in the range of 6.5 to 8.5 (in aqueous solutions).Type: ApplicationFiled: March 27, 2014Publication date: March 5, 2015Applicant: BK Giulini Chemie GmbhInventors: Thauern Henrike, Gabriele Brix, Thomas Staffel
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Patent number: 6517819Abstract: An antiperspirant suspension which is finely divided, which is contained in a non-aqueous phase, and which has improved efficacy for perspiration reduction when used on human skin, includes at least one basic aluminum-zirconium-halogenohydrate complex as active ingredient in which at least 60% of the zirconium content can be directly titrated after dissolving in 0.1 n HCl with EDTA at a pH of 0.8, wherein the active ingredient optionally contains an amino acid. A process for the synthesis of the antiperspirant suspension includes mixing an aluminum salt which is effective as an antiperspirant with a zirconium salt which is effective as an antiperspirant, optionally in the presence of an amino acid, in a non-aqueous oil phase in the absence of water to provide a mixture; and grinding the mixture.Type: GrantFiled: May 26, 2000Date of Patent: February 11, 2003Assignee: BK Giulini Chemie GmbH und Co OhgInventors: Johannes Breker, Bruno Kaufmann, Wolfgang Reibel, Klaus Schanz
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Patent number: 6352587Abstract: A process for coloring an unglazed ceramic with an aqueous colorant solution containing a chromium (III) coordination compound which is at least partially neutralized and stable, including (a) dissolving a carboxylic acid selected from the group consisting of acetic acid, an organic dicarboxylic acid having a general formula (COOH)—(CH2)n—(COOH), where n ranges from 0 to 10, and an unsaturated, organic dicarboxylic acid in water at a temperature ranging from 40 to 60° C. to provide an aqueous solution of a carboxylic acid; (b) adding a chromium (III) compound to the aqueous solution of a carboxylic acid while stirring for a time and at a temperature effective for reaction to form an aqueous solution containing a chromium (III) coordination compound; (c) filtering the aqueous solution containing the chromium (III) coordination compound to provide a filtered aqueous solution; and (d) adjusting pH of the filtered aqueous solution to a pH ranging from 3 to 6.Type: GrantFiled: June 1, 1999Date of Patent: March 5, 2002Assignee: BK Giulini Chemie GmbH & Co. OHGInventors: Thomas Staffel, Jürgen Straub, Thomas Klein
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Patent number: 6302954Abstract: A solidification and curing accelerator for hydraulic binders produced by a process including providing a reaction mixture composed of constituents (a) - (e) as follows: (a) at least one of basic aluminum salts which are substantially water insoluble and aluminum hydroxide; (b) at least one of aluminum sulfate which is substantially water soluble and sulfuric acid; (c) at least one of an organic carboxylic acid or mixtures of at least two organic carboxylic acids; (d) aluminum salts of organic carboxylic acids; and (e) at least one organic and inorganic substance selected from the group consisting of sulfates, hydrogen-sulfates, carbonates, hydrogen-carbonates, alkaline earth metal oxides, and alkaline earth metal hydroxides; adding water to the reaction mixture and reacting at a temperature ranging up to 150 ° C. for a time effective to provide a reaction product which is a solution in water.Type: GrantFiled: August 20, 1999Date of Patent: October 16, 2001Assignee: BK Giulini Chemie GmbHInventors: Rudolf Lunkenheimer, Johannes Breker, Istvan Potencsik, Horst Altmann, Reinhold Sedelies
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Patent number: 6268465Abstract: An aliphatic polyester amide which is hydrolysis-resistant includes a ternary polycondensation product of monomeric constituents composed of a monomeric constituent A which is at least one diol having a general formula: HO—R1—OH, where R1 is an aliphatic residue having 2-16 carbon atoms; a monomeric constituent B which is at least one dicarboxylic acid having a general formula: HOOC—R2—COOH, where R2 is an aliphatic residue having 1-14 carbon atoms; and a monomeric constituent C which is at least one diamine having a general formula: H2N—R3—NH2, where R3 is an aliphatic residue having 2-16 carbon atoms and is present in an amount of up to about 5% by weight based on total weight of the monomeric constituents, wherein polycondensation proceeds in the presence of a catalyst comprised of constituent D, which is a metal-containing catalyst, in combination with constituent E, which is at least one of an organic phosphorus compound and an inorganic phosphorus compound, and whereiType: GrantFiled: April 12, 1999Date of Patent: July 31, 2001Assignee: BK Giulini Chemie GmbH Co OHGInventors: Gudrun Chomiakow, Hasan Ulubay, Emil Wilding
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Patent number: 6255427Abstract: An amphoteric polymer dispersion obtained in the presence of at least one of starch or a starch derivative by a two-stage polymerization using anionic and cationic monomers is useful as a sizing agent for paper products, as a coating for various substrates, and as a binder in pigment-free coatings or pigment-containing coatings. The dispersion is exceptionally compatible with widely differing sizing agent systems and coating chemicals.Type: GrantFiled: January 13, 1999Date of Patent: July 3, 2001Assignee: Giulini Chemie GmbHInventors: Reiner Exner, Hasen Ulubay, Karl Hetterich
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Patent number: 6114054Abstract: A method for coloring a surface of a ceramic mass to produce a colored ceramic body includes providing a host lattice material composed of a colorless metal oxide compound which crystallizes into one of a spinel lattice or a rutile lattice and which may be water soluble; providing an aqueous coloring solution containing water; a first water soluble compound including a metal ion which is one of a two-valent metal ion or a three-valent metal ion and which colors the host lattice material; and a second water soluble compound including a metal ion which is one of a five-valent metal ion or six-valent metal ion and which provides electrostatic balance; generating a mixed-phase pigment in the surface of the ceramic mass by one of (i.) working a fine powder of the colorless metal oxide into the ceramic mass and applying the aqueous coloring solution onto at least one surface of the ceramic mass, or (i.i.Type: GrantFiled: December 15, 1998Date of Patent: September 5, 2000Assignee: BK Giulini Chemie GmbH & Co.Inventors: Thomas Klein, Thomas Staffel, Jurgen Straub, Lysander Fischer
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Patent number: 6045859Abstract: The present invention relates to a method for coloring ceramic surfaces, wherein the surfaces are treated with an aqueous solution of alkali metal or ammonium dithiosulphatoaurate(I) with a gold concentration of 0.1-10% by weight, the water is evaporated and the dithiosulphatoaurate(I) is decomposed at temperatures of 300-1400.degree. C.Type: GrantFiled: November 12, 1998Date of Patent: April 4, 2000Assignee: BK Giulini Chemie GmbH & Co. OHGInventors: Thomas Klein, Thomas Staffel, Lysander Fischer, Richard Walter, Peter Patzelt
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Patent number: 6042884Abstract: An aqueous ruthenium chloride solution for blackening ceramic surfaces includes ruthenium chloride; water present in an amount effective to provide an aqueous solution of ruthenium chloride; and a buffer which is selected from the group consisting of sodium acetate, sodium propionate, potassium acetate, potassium propionate, and mixtures thereof, and which is present in an amount effective to provide the aqueous solution with a pH of at least 1.5. A method for dyeing a ceramic surface includes applying the aqueous solution of ruthenium chloride to a ceramic surface by at least one of spraying, dipping, painting and printing to provide a treated surface; drying and firing the treated surface at a temperature ranging from about 300 to about 1400.degree. C. for a period of time ranging from one half hour to five hours; and grinding and polishing the treated surface to even out the treated surface.Type: GrantFiled: April 30, 1998Date of Patent: March 28, 2000Assignee: BK Giulini Chemie GmbHInventors: Thomas Klein, Thomas Staffel, Lysander Fischer
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Patent number: 5925722Abstract: A process for producing an amphoteric aqueous polymer dispersion by two-step radical copolymerization includes (a) decomposing a starch by treatment with an enzyme or acid hydrolysis to provide a starch solution composed of decomposed starch and/or derivatives thereof having an average molecular weight ranging from 500 to 2000 g/mole and with the starch solution having an internal viscosity<0.Type: GrantFiled: November 25, 1996Date of Patent: July 20, 1999Assignee: Giulini Chemie GmbHInventors: Reiner Exner, Hasan Ulubay, Karl Hetterich
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Patent number: 5660625Abstract: Improved set accelerating mixtures and their use are disclosed to shorten the period after mixing hydraulically setting building materials, for example cement, up to the transition into the solid phase. The improved set accelerating mixtures comprise basic aluminum sulphates of the formula: Al(OH).sub.a (SO.sub.4).sub.b, in which the subscripts satisfy the conditions:a=3-2b and b=0.05 to 0.4.These basic aluminum sulphates are produced by parallel precipitation from solutions containing aluminum at temperatures usually less than 60.degree. C. by mixing dilute acid solutions and alkaline solutions containing sulphates in the pH range from 5.0 to 8.0 to produce an amorphous, basic aluminum sulphate.Type: GrantFiled: January 24, 1996Date of Patent: August 26, 1997Assignee: Giulini Chemie GmbHInventors: Otto Helmboldt, Istvan Potencsik, Johannes Breker, Reinhold Sedelies, Detlev Roggenkamp
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Patent number: 5204414Abstract: Salts of lower alkyl vinyl ether/maleic anhydride are described as active components in dental adhesives. A process for the preparation of these salts is described.The salts are partially neutralized mixed salts of lower alkyl vinyl ether/maleic anhydride copolymers. The neutralization of the copolymer is effected with aluminum, and calcium and/or sodium.Type: GrantFiled: July 5, 1990Date of Patent: April 20, 1993Assignee: Giulini Chemie GmbHInventors: Zvi Pelah, Ernst Urmann, Werner Kopp
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Patent number: 5187308Abstract: The present invention relates to a novel process for the production of low viscosity copolymers of maleic acid monoalkyl ester and vinyl alkyl ethers characterized in that the copolymerization of alkyl vinyl ether is performed with a mixture composed of maleic acid anhydride and maleic acid monoalkyl ester. The specific viscosity is controlled by the setting of a certain maleic acid anhydride to maleic acid monoalkyl ester ratio.Type: GrantFiled: November 14, 1990Date of Patent: February 16, 1993Assignee: Giulini Chemie GmbHInventors: Zvi Pelah, Istvan Potencsik, Werner Kopp, Ernst Urmann
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Patent number: 5169967Abstract: A novel aluminum magnesium hydroxy fatty acid compound is disclosed having a general formula, Al.sub.x Mg.sub.y (OH).sub.3x+2y-z R.sub.z.nH.sub.2 O, wherein R is at least one aliphatic monocarboxylic acid group having the formula RCOO.sup.- and comprising from 12 to 22 carbon atoms, and wherein x=2, 2.ltoreq.y.ltoreq.10, z=2, and n is an integer greater than zero. The compound is prepared by a process including placing water and a salt which is one of an alkali metal salt or an ammonium salt of at least one aliphatic monocarboxylic acid having from 12 to 22 carbon atoms in a reactor fitted with heating and stirring means. The salt is dissolved by intensive stirring and by heating to a temperature ranging from 20.degree. to 90.degree. C. to provide a salt solution. The pH of the salt solution in the reactor is maintained at a pH of at least 8 to provide an alkaline solution.Type: GrantFiled: September 26, 1990Date of Patent: December 8, 1992Assignee: Giulini Chemie GmbHInventors: Uwe Assmus, Klaus Schanz, Bruno Kaumann
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Patent number: 5169886Abstract: A cationic dispersant composed of a copolymer made of the monomers N,N-dimethylamino acrylate and/or methacrylate, the acrylic acid ester and or methacrylic acid ester of a C.sub.10 to C.sub.22 fatty alcohol, methyl acrylate and/or methyl methacrylate, acrylic and/or methacrylic acid and optionally n-butyl acrylate and/or methacrylate and isobutyl acrylate and/or methacrylate. It is equally suitable for the production of stable sizing agent dispersions intended for internal or surface sizing.Type: GrantFiled: December 4, 1991Date of Patent: December 8, 1992Assignee: Giulini Chemie GmbHInventors: Josef Bung, Hasan Ulubay, Bernd Schutzius
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Patent number: 5143665Abstract: Method of producing a mold from a ceramic composition which can be washed-out with water after use thereof in a molding process, the method including forming a ceramic composition by mixing from about 30 to about 80 weight percent of at least one hemihydrate including alpha-calcium sulfate hemihydrate or beta-calcium sulfate hemihydrate, from about 5 to about 45 weight percent of fire clay, and from about 5 to about 25 weight percent of at least one silicate-based filler. About 100 parts by weight of the ceramic composition are mixed under stirring into from about 46 to about 54 parts by weight of water to form a slurry. The slurry is poured into a formation mold suitable for forming the desired mold and the slurry contained in the formation mold is allowed to set and form a set body. The set body is then removed from the formation mold and dried to provide the mold.Type: GrantFiled: March 28, 1991Date of Patent: September 1, 1992Assignee: Giulini Chemie GmbHInventors: Neville H. Clubbs, Hans-Joachim Forster, Ulrich Kiefer, Jurgen Bleh
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Patent number: 5142077Abstract: Aluminum magnesium hydroxy compounds of the formulaAl.sub.x Mg.sub.y (OH).sub.35-z R.sub.z.nH.sub.2 Oin which R represents an anion of at least one monocarboxylic acid having from 2 to 22 carbon atoms, and n, x, y and z are defined by: ##EQU1## are described.Type: GrantFiled: September 23, 1988Date of Patent: August 25, 1992Assignee: Giulini Chemie GmbHInventors: Roland Martin, Klaus Schanz, Bruno Kaufmann
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Patent number: 5073573Abstract: A gel composition useful as a thickening agent, for example in cosmetic compositions, containing an aluminum-magnesium-hydroxy compound of the general formulaAl.sub.x Mg.sub.y (OH).sub.35-z R.sub.z.nH.sub.2 Owhere R represents the anion of a monocarboxylic acid having 2 to 22 carbon atoms and n, x, y and z are defined by0.ltoreq.n.ltoreq.103.ltoreq.x.ltoreq.94.ltoreq.y.ltoreq.133.ltoreq.z.ltoreq.5and3x+2y=35;and also containing an organic, lipophilic compound which is liquid at 20.degree. C.Type: GrantFiled: September 23, 1988Date of Patent: December 17, 1991Assignee: Giulini Chemie GmbHInventors: Roland Martin, Klaus Schanz, Bruno Kaufmann
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Patent number: 5047490Abstract: A process of manufacturing powdered copolymers of maleic anhydride with methyl vinyl ether in a mole ratio of 1:1 and a specific viscosity in a range from 2 to 5 by copolymerization of maleic anhydride with methyl vinyl ether in the presence of radical initiators to initiate polymerization. The process includes mixing maleic anhydride with an excess of about 3 to about 20 mol methyl vinyl ether per mol maleic anhydride and initiating a polymerization reaction with a radical initiator added in a quantity of from about 0.001 to about 1 weight % with respect to the maleic anhydride. The polymerization reaction takes place in the absence of other solvents.Type: GrantFiled: July 14, 1989Date of Patent: September 10, 1991Assignee: Giulini Chemie GmbHInventors: Zvi Pehlah, Istvan Potencsik, Werner Kopp, Ernst Urmann
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Patent number: 5028270Abstract: An aqueous silicic acid sol which is freeze-stabilized and which is useful for the production of phosphate-based embedding compositions used in dental technology, the aqueous silicic acid sol including from 25 to 50 weight percent of silicon dioxide; and from 2 to 10 weight % of a compound which is one of urea or a urea derivative and which has the general formula: ##STR1## wherein X and Y are groups selected from the group consisting of an --NH.sub.2 group and an --NHR group, in which R is an alkyl radical having from 1 to 4 carbon atoms.Type: GrantFiled: March 23, 1989Date of Patent: July 2, 1991Assignee: Giulini Chemie GmbHInventors: Hans-Joachim Forster, Josef Gotzig, Jorg Brenn, Wolfgang Tucholke