Abstract: The disclosure is directed to a method of forming high-aspect-ratio metallic glass articles that are substantially free of defects and cosmetic flaws by means of rapid capacitive discharge forming. Metallic glass alloys that are stable against crystallization for at least 100 ms at temperatures where the viscosity is in the range of 100 to 104 Pa-s are considered as suitable for forming such high-aspect-ratio articles.

Abstract: The disclosure is directed to Ni—P—B alloys bearing Mn and optionally Cr and Mo that are capable of forming a metallic glass, and more particularly metallic glass rods with diameters at least 1 mm and as large as 5 mm or larger. The disclosure is further directed to Ni—Mn—Cr—Mo—P—B alloys capable of demonstrating a good combination of glass forming ability, strength, toughness, bending ductility, and corrosion resistance.

Abstract: Golf clubs formed from bulk-solidifying amorphous metals (i.e., metallic glasses) having high elastic modulus and fracture toughness, and to methods of forming the same are provided. Among other components, the golf club materials disclosed enable fabrication of flexural membranes or shells used in golf club heads (drivers, fairways, hybrids, irons, wedges and putters) exhibiting enhanced flexural or bending compliance together with the ability to deform plastically and avoid brittle fracture or catastrophic failure when overloaded under bending loads. Further, the high strength of the material and its density, comparable to that of steel, enables the redistribution of mass in the golf club while maintaining a desired overall target mass.

Abstract: A method of forming a bulk metallic glass is provided. The method includes overheating the alloy melt to a temperature above a threshold temperature, Ttough, associated with the metallic glass demonstrating substantial improvement in toughness compared to the toughness demonstrated in the absence of overheating the melt above Tliquidus, and another threshold temperature, TGFA, associated with the metallic glass demonstrating substantial improvement in glass-forming ability compared to the glass-forming ability demonstrated in the absence of overheating the melt above Tliquidus. After overheating the alloy melt to above Ttough and TGFA, the melt may be cooled and equilibrated to an intermediate temperature below both Ttough and TGFA but above Tliquidus, and subsequently quenched at a high enough rate to form a bulk metallic glass.

Abstract: Ni—Fe—Si—B and Ni—Fe—Si—B—P metallic glass forming alloys and metallic glasses are provided. Metallic glass rods with diameters of at least one, up to three millimeters, or more can be formed from the disclosed alloys. The disclosed metallic glasses demonstrate high yield strength combined with high corrosion resistance, while for a relatively high Fe contents the metallic glasses are ferromagnetic.

Abstract: An automated rapid capacitive discharge apparatus is provided for sequentially or simultaneously rapidly heating and shaping a plurality of metallic glass feedstock samples. The apparatus includes a sample feeder defining a body for holding a plurality of samples and being capable of sequentially positioning at least one feedstock sample into a discharge position within the processing compartment. In the processing compartment the sample is heated by a discharge of a quantum of electrical energy supplied via electrodes, then shaped into a desired shape by means of a shaping tool, and subsequently moved out of the discharge position as a second feedstock moves into a discharge position.

Abstract: An alloy comprising Fe, Ni, P, B and Ge is disclosed, having a composition according to the formula [Fe1-yNiy](100-a-b-c)PaBbGec, where a, b, c subscripts denote atomic percent; y subscript denotes atomic fraction, a is between 9 and 12, b is between 5.5 and 7.5, c is between 2 and 6, and y is between 0.45 and 0.55. Metallic glass rods with diameter of at least 1 mm can be formed from the alloy by rapid quenching from the molten state.

Abstract: A bulk-glass forming Ni—Cr—Nb—P—B alloy is provided. The alloy includes Ni(100?a?b?c?d)CraTabPcBd, where the atomic percent a is between 3 and 11, the atomic percent b is between 1.75 and 4, the atomic percent c is between 14 and 17.5, and the atomic percent d is between 2.5 and 5. The alloy is capable of forming a metallic glass having a lateral dimension of at least 3 mm.

Abstract: A Ni-based bulk metallic glass forming alloy is provided. The alloy includes Ni(100-a-b-c-d)CraNbbPcBd, where an atomic percent of chromium (Cr) a ranges from 3 to 13, an atomic percent of niobium (Nb) b is determined by x?y*a, where x ranges from 3.8 to 4.2 and y ranges from 0.11 to 0.14, an atomic percent of phosphorus (P) c ranges from 16.25 to 17, an atomic percent of boron (B) d ranges from 2.75 to 3.5, and the balance is nickel (Ni), and where the alloy is capable of forming a metallic glass object having a lateral dimension of at least 6 mm, where the metallic glass has a stress intensity factor at crack initiation when measured on a 3 mm diameter rod containing a notch with length between 1 and 2 mm and root radius between 0.1 and 0.15 mm, the stress intensity factor being at least 70 MPa m1/2.

Abstract: The disclosure provides Ni—Mo—P—B, Ni—Mo—Nb—P—B, and Ni—Mo—Nb—Mn—P—B alloys capable of forming metallic glass objects. The metallic glass objects can have lateral dimensions in excess of 1 mm and as large as 3 mm or larger. The disclosure also provides methods for forming the metallic glasses.

Abstract: Nickel based alloys capable of forming bulk metallic glass are provided. The alloys include Ni—Cr—Si—B compositions, with additions of P and Mo, and are capable of forming a metallic glass rod having a diameter of at least 1 mm. In one example of the present disclosure, the Ni—Cr—Mo—Si—B—P composition includes about 4.5 to 5 atomic percent of Cr, about 0.5 to 1 atomic percent of Mo, about 5.75 atomic percent of Si, about 11.75 atomic percent of B, about 5 atomic percent of P, and the balance is Ni, and wherein the critical metallic glass rod diameter is between 2.5 and 3 mm and the notch toughness between 55 and 65 MPa m1/2.