Abstract: A method of reducing odors in lipid-based polyol. At least one lipid-based polyol is provided, and mixed with ricinoleic acid and/or a metal salt of ricinoleic acid. Isocyanate may be added, preferably toluene diisocyanate (TDI). The polyol, and the isocyanate when present, are reacted in the presence of the ricinoleic acid and/or a metal salt of ricinoleic acid which reduces or removes odors in the lipid-based polyol. When isocyanate is used, low, limiting levels are preferred, well below the level required to fully react with all of the polyol. Tin, zinc, sodium, and calcium ricinoleic acid metal salts are particularly preferred. Preferably the reaction takes place without added heat, at room temperature. The reaction may be performed in a chamber which is under at least a partial vacuum.
Abstract: A method of making a polyurethane foam from a mixture of isocyanate modified polyol and foam-forming ingredients, wherein the isocyanate modified polyol is made by reacting at least one polyol with at least one multifunctional isocyanate, wherein the isocyanate modified polyol is a non-foamed polyol polymer having available OH groups, wherein the foam forming ingredients comprise at least a multifunctional isocyanate and a foaming agent, preferably water, and characterised in that (i) the at least one polyol from which the isocyanate modified polyol is made comprises at least one lipid-based polyol which has undergone reaction with the isocyanate in the presence of a PU gelation catalyst, and/or (ii) the isocyanate modified polyol is mixed with a lipid-based polyol prior to, or at the same time as, foaming.
Abstract: A method of making a polyurethane foam from a mixture of isocyanate modified polyol and foam-forming ingredients, wherein the isocyanate modified polyol is made by reacting at least one polyol with at least one multifunctional isocyanate, wherein the isocyanate modified polyol is a non-foamed polyol polymer having available OH groups, wherein the foam forming ingredients comprise at least a multifunctional isocyanate and a foaming agent, preferably water, and characterized in that (i) the at least one polyol from which the isocyanate modified polyol is made comprises at least one lipid-based polyol which has undergone reaction with the isocyanate in the presence of a PU gelation catalyst, and/or (ii) the isocyanate modified polyol is mixed with a lipid-based polyol prior to, or at the same time as, foaming.