Patents Assigned to GreenField Ethanol Inc.
  • Publication number: 20130264264
    Abstract: Disclosed is a solid/liquid separation apparatus including an extruder press combined with a solid/fluid separation module for separating fluid from a mass of solids compressed by the extruder at elevated pressures. The extruder includes two or more extruder screws with flighting intercalated at least along a part of the extruder barrel. The separation module forms a continuation of the barrel, receives the pressurized mass and at least a portion of the twin screws, and includes a filter pack consisting of a filter plate and a backer plate. The filter plate has a throughgoing filter slot extending away from a core opening and into the filter plate for directing fluid away from the core opening. The backer plate has a core opening shaped and sized equal to the barrel and defines a passage for guiding fluid collected in the filter slot to an exterior of the filter pack.
    Type: Application
    Filed: April 5, 2013
    Publication date: October 10, 2013
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Richard Romeo LEHOUX, Christopher Bruce BRADT
  • Publication number: 20130217089
    Abstract: A method for producing hydrogen from organic material. Organic material and hydrogen-producing microorganisms are provided in a completely mixed bioreactor for breaking down the organic material into H2, CO2, fatty acids, and alcohols. H2, CO2, and a first liquid effluent are recovered from the completely mixed bioreactor. The first liquid effluent includes hydrogen-producing microorganisms, fatty acids, and alcohols. The first liquid effluent is provided into a gravity settler for separating the first liquid effluent into a concentrated biomass (including hydrogen-producing microorganisms) and a second liquid effluent (including at least a portion of the fatty acids and the alcohols). The concentrated biomass is provided into the completely mixed bioreactor. An input voltage is applied to at least one of the completely mixed bioreactor and the gravity settler for facilitating an electrohydrogenesis process therein.
    Type: Application
    Filed: February 15, 2013
    Publication date: August 22, 2013
    Applicant: GREENFIELD ETHANOL INC.
    Inventor: GREENFIELD ETHANOL INC.
  • Publication number: 20130175467
    Abstract: The use of a side stream and residue from the lignocellulose to ethanol process for use in preventing the formation of ice and in melting ice and snow on roadways. The future lignocellulose to ethanol industry will provide a significant proportion of these streams that provide an organic solution that when added to chloride salts of calcium, magnesium and sodium provides an improved environmentally friendly road deicing product with reduced corrosiveness and increased friction. A deicer composition of calcium chloride aqueous solution containing 25-38% by weight calcium chloride mixed up to 50% by volume of hemicellulose hydrolysis side stream can reduce the corrosivity of calcium chloride to 70% less that of a sodium chloride solution.
    Type: Application
    Filed: September 13, 2011
    Publication date: July 11, 2013
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Christopher Bruce Bradt, Richard Romeo Lehoux, Mark Isaac Schwartz, Demetre Spanos
  • Patent number: 8394235
    Abstract: A process for the pretreatment of lignocellulosic biomass, in particular during the production of ethanol from biomass. The process including a cooking step where the biomass is exposed to steam at elevated temperatures and pressures for a preselected period of time in a treatment vessel. During the process, volatile and liquid compounds are purged from the treatment vessel.
    Type: Grant
    Filed: January 15, 2010
    Date of Patent: March 12, 2013
    Assignee: GreenField Ethanol Inc.
    Inventors: Christopher Bruce Bradt, Richard Romeo Lehoux
  • Publication number: 20130025798
    Abstract: A process for separation of solid and liquid components in a distillation whole stillage utilizing airless spray drying is disclosed, which is more efficient and economical than conventional processes. In the process, distillation whole stillage resulting from distillation of fermented biomass is first subjected to an evaporation step for separating the whole stillage into a condensate and a concentrate including water, dissolved solids and suspended solids. The concentrate is then subjected to airless steam spray drying for converting the concentrate into dried solids, steam and vapors. All steam and vapors resulting from the airless steam spray drying step are then redirected as energy source to a processing step upstream of the airless spray drying step. At least some of the steam generated in the airless spray drying step is airless steam.
    Type: Application
    Filed: July 20, 2012
    Publication date: January 31, 2013
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Richard Romeo LEHOUX, Christopher Bruce BRADT
  • Publication number: 20130029406
    Abstract: Disclosed is a method of pretreating biomass in two pretreatment stages as part of a biofuel production process. The first stage pretreatment is carried out by heating the biomass to a first stage temperature of 140° C. to 180° C. for a first stage time of 30 minutes to 2 hours at a first stage pressure of 105 to 150 psig; and the second stage is carried out by heating the biomass to a second stage temperature of 190° C. to 210° C. for a second stage time of 2 to 10 minutes at a second stage pressure of 167 to 262 psig. The biomass may be initially conditioned prior to the first pretreatment stage by atmospheric steam heating and adjusting the moisture content of the biomass. Hemicellulose and inhibitors (inhibitory compounds) to downstream hydrolysis and fermentation are preferably removed between the first and second pretreating stages, more preferably after each pretreatment stage.
    Type: Application
    Filed: July 20, 2012
    Publication date: January 31, 2013
    Applicant: GreenField Ethanol Inc.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Regis-Olivier BENECH
  • Publication number: 20130014749
    Abstract: Disclosed is an improvement in a conventional process for C5 and C6 sugar recovery from lignocellulosic biomass for fermentation to ethanol, which process including the conventional steps of pretreatment of the biomass with steam at elevated temperature and pressure, collection of C5 sugars from hemicellulose breakdown, cellulose hydrolysis and collection of C6 sugars from cellulose breakdown. The improvement includes conditioning of the biomass prior to the pretreatment step by heating the biomass with steam for a time period between 5 minutes to 60 minutes to achieve a steam treated biomass having a temperature of about 80 to 100°C.; and adjusting a moisture content of the steam treated biomass to about 45% to 80%. An increased recovery of C5 and C6 sugars is achieved compared to the conventional process.
    Type: Application
    Filed: July 12, 2012
    Publication date: January 17, 2013
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Regis-Olivier BENECH
  • Publication number: 20130017589
    Abstract: A process is defined for the continuous steam pretreatment and fractionation of corn cobs and low lignin lignocellulosic biomass to produce a concentrated cellulose solid stream that is sensitive to enzymatic hydrolysis. Valuable chemicals are recovered by fractionating the liquid and vapor stream composed of hydrolysis and degradation products of the hemicellulose. Cellulosic derived glucose is produced for fermentation to biofuels. A hemicellulose concentrate is recovered that can be converted to value added products including ethanol.
    Type: Application
    Filed: July 17, 2012
    Publication date: January 17, 2013
    Applicant: GreenField Ethanol Inc.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Regis-Olivier BENECH
  • Publication number: 20120329116
    Abstract: A process for the pretreatment of lignocellulosic biomass is disclosed, which includes the steps of pretreating the lignocellulosic biomass to hydrolyze and solubilize hemicelluloses in the biomass; explosively decomposing the biomass into fibers; and extracting from the resulting solids fraction a liquefied portion of the lignocellulosic biomass before or after explosive decomposition. This removes compounds from the lignocellulosic biomass which are inhibitory to enzymatic cellulose hydrolysis and sugar fermentation to ethanol. For improved economy, the inhibitory compounds are not completely removed. The extraction step is controlled on the basis of the xylose equivalent content in the reaction mixture and the extracting step is discontinued once a xylose equivalent content of 4-8% w/w of xylose in the dry matter of the solids fraction is achieved.
    Type: Application
    Filed: July 23, 2012
    Publication date: December 27, 2012
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Regis-Olivier BENECH
  • Patent number: 8287651
    Abstract: A process for the production of ethanol from biomass is disclosed. The process relates to the pretreatment of corncob biomass and includes the steps of exposing corncob to steam in a reaction vessel at an elevated temperature and reaction pressure for a preselected exposure time. Volatile compounds are continuously vented during pretreatment. The reaction pressure is released for explosive decomposition of the corncob biomass into fibrous solids and condensate. The exposure is preferably carried out at a temperature of 190-210° C. and a pressure of 190 psig to 275 psig and an exposure time of 3 to 10 minutes.
    Type: Grant
    Filed: September 16, 2009
    Date of Patent: October 16, 2012
    Assignee: GreenField Ethanol Inc.
    Inventors: Robert Benson, Chris Bradt, Regis-Olivier Benech, Richard Romeo Lehoux
  • Publication number: 20120118517
    Abstract: A solid/fluid separation module and pretreatment apparatus and method enables pretreatment of biomass at high temperature and pressure with the ability to vary residence and processing times.
    Type: Application
    Filed: November 9, 2011
    Publication date: May 17, 2012
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Richard Romeo LEHOUX, Christopher Bruce BRADT
  • Publication number: 20120111514
    Abstract: A process is defined for the continuous steam pretreatment and fractionation of bagasse to produce a concentrated cellulose solid stream that is sensitive to enzymatic hydrolysis. Valuable chemicals are recovered by fractionating the liquid and vapor stream composed of hydrolysis and degradation products of the hemicellulose. Cellulosic derived glucose is produced for fermentation to biofuels. A hemicellulose concentrate is recovered that can be converted to value added products including ethanol.
    Type: Application
    Filed: November 4, 2011
    Publication date: May 10, 2012
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Régis-Olivier BENECH
  • Publication number: 20120115200
    Abstract: A continuous process for the recovery of ethanol from hemicellulose and cellulose from lignocellulosic biomass. Yield of fermentable sugars can be maximized by continuous operation of the pre-treatment system and careful selection of pretreatment conditions including the addition of only small amounts of dilute mineral acid and low pressure. With this approach, the xylose component that is mainly present in its unfermentable oligomeric form in known pre-hydrolysis Kraft processes can be recovered more efficiently and as a monomer that can be fermented by xylose fermenting yeasts and bacteria. Due to the use of only dilute acids, there is a very low loss of glucose and xylose hence very low production of toxic chemicals (e.g. HMF, furfural) in the pretreatment step. The resulting overall fermentation efficiency of both hexose and pentose sugars is 90% of the theoretical maximum.
    Type: Application
    Filed: November 8, 2011
    Publication date: May 10, 2012
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Régis-Olivier BENECH
  • Publication number: 20110229949
    Abstract: A polyploid transformed yeast cell comprising a deleted or disrupted GDH1 gene encoding an NADPH-dependent glutamate dehydrogenase. The polyploid yeast cell shows increased production of ethanol and reduced production of glycerol when compared with a control polyploid yeast cell.
    Type: Application
    Filed: March 23, 2011
    Publication date: September 22, 2011
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Hubert PIATKOWSKI, Mark Isaac SCHWARTZ
  • Patent number: 7935514
    Abstract: A polyploid transformed yeast cell comprising a deleted or disrupted GDH1 gene encoding an NADPH-dependent glutamate dehydrogenase. The polyploid yeast cell shows increased production of ethanol and reduced production of glycerol when compared with a control polyploid yeast cell.
    Type: Grant
    Filed: November 14, 2008
    Date of Patent: May 3, 2011
    Assignee: GreenField Ethanol Inc.
    Inventors: Hubert Piatkowski, Mark Isaac Schwartz
  • Publication number: 20100313882
    Abstract: A process is defined for the continuous steam pretreatment and fractionation of corn cobs and low lignin lignocellulosic biomass to produce a concentrated cellulose solid stream that is sensitive to enzymatic hydrolysis. Valuable chemicals are recovered by fractionating the liquid and vapor stream composed of hydrolysis and degradation products of the hemicellulose. Cellulosic derived glucose is produced for fermentation to biofuels. A hemicellulose concentrate is recovered that can be converted to value added products including ethanol.
    Type: Application
    Filed: April 23, 2010
    Publication date: December 16, 2010
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Frank A. Dottori, Robert Ashley Cooper Benson, Regis-Olivier Benech
  • Publication number: 20100269990
    Abstract: A process for separating the components of lignocellulosic biomass for the purpose of producing a pure reactive cellulose is disclosed. The process has two stages. In the first stage, the lignocellulosic biomass is pretreated with steam, with or without an acid catalyst, and then pressed, with or without the presence of an eluent, to remove hemicellulose and other impurities. In the second stage, the pretreated biomass is extracted with a solvent such as ethanol with or without acid catalysts in order to remove lignin and release a purified cellulose stream. The extracted cellulose is then rapidly decompressed to rupture the fibrous structure. The process provides a purified cellulose stream that is relatively easy to hydrolyze with enzymes and ferment to biofuels and other chemicals such as ethanol.
    Type: Application
    Filed: April 23, 2010
    Publication date: October 28, 2010
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Régis-Olivier BENECH
  • Publication number: 20100263814
    Abstract: A process for the pretreatment of lignocellulosic biomass is disclosed. The process is intended for use in connection with biomass to ethanol processes and is directed in particular to an economical removal of inhibitory compounds generated in biomass pretreatment, which are inhibitory to downstream hydrolysis and fermentation steps. The process includes the steps of heating the lignocellulosic biomass with steam to a preselected temperature, at a preselected pressure and for a preselected time to hydrolyze and solubilize hemicelluloses in the biomass; explosively decomposing the biomass into fibers; and extracting from the resulting reaction mixture a liquefied portion of the lignocellulosic biomass before or after explosive decomposition. The liquefied portion is extracted to remove compounds from the lignocellulosic biomass which are inhibitory to enzymatic cellulose hydrolysis and sugar fermentation to ethanol. For improved efficiency and economy, the inhibitory compounds are not completely removed.
    Type: Application
    Filed: April 7, 2010
    Publication date: October 21, 2010
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Frank A. DOTTORI, Robert Ashley Cooper BENSON, Régis-Olivier BENECH
  • Publication number: 20100255554
    Abstract: A method for optimization of a fed batch hydrolysis process wherein the hydrolysis time is minimized by controlling the feed addition volume and/or batch addition frequency of the prehydrolysate and optionally also the enzyme feed. The increase over time in hydrolysate consistency and volume and/or concentration of sugars released in the reactor, so that the enzymatic hydrolysis is controlled, significantly reduces the impact of cellulase feedback inhibition, especially for enzyme contents lower than 0.5%. The overall time to reach conversion of the total prehydrolysate feed is reduced significantly where the batch addition frequency is equal to one batch each time 70% to 90%, preferably 80%, conversion of the previous batch is reached in the reaction mixture. At an enzyme load of 0.3% in the reaction mixture, the optimum frequency each time 80% conversion was reached was found to be one batch every 105 minutes.
    Type: Application
    Filed: March 31, 2010
    Publication date: October 7, 2010
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Robert Ashley Cooper BENSON, Regis-Olivie BENECH
  • Publication number: 20100181034
    Abstract: A process for the pretreatment of lignocellulosic biomass, in particular during the production of ethanol from biomass. The process including a cooking step where the biomass is exposed to steam at elevated temperatures and pressures for a preselected period of time in a treatment vessel. During the process, volatile and liquid compounds are purged from the treatment vessel.
    Type: Application
    Filed: January 15, 2010
    Publication date: July 22, 2010
    Applicant: GREENFIELD ETHANOL INC.
    Inventors: Chris BRADT, Richard Romeo LEHOUX