Patents Assigned to Grillo-Werke AG
  • Patent number: 11634385
    Abstract: The present invention relates to a process for preparing haloalkanesulfonic acids from sulfur trioxide and a haloalkane, particularly to a process for preparing trifluoromethane sulfonic acid from sulfur trioxide and trifluoromethane.
    Type: Grant
    Filed: May 23, 2019
    Date of Patent: April 25, 2023
    Assignee: Grillo-Werke AG
    Inventors: Timo Ott, Christian Diaz-Urrutia, Ingo Biertuempel
  • Patent number: 10329251
    Abstract: A compound of the formula: CH3—SO2—O—O—SO2OH.
    Type: Grant
    Filed: November 17, 2014
    Date of Patent: June 25, 2019
    Assignee: Grillo-Werke AG
    Inventors: Timo Ott, Ingo Biertümpel
  • Patent number: 7524582
    Abstract: The invention is directed to a zinc powder or zinc alloy powder for alkaline batteries, which powder has a grain size distribution wherein 60 to 100 wt.-% of the particles, relative to the zinc powder or zinc alloy powder, have a diameter of from 40 to 140 ?m. The invention is also directed to an alkaline battery.
    Type: Grant
    Filed: June 5, 2006
    Date of Patent: April 28, 2009
    Assignee: Grillo-Werke AG
    Inventors: Armin Melzer, Petra Merkel, Jochen Spiestersbach, Rudi Kube, Norbert Schulz
  • Patent number: 7329828
    Abstract: The invention relates to a method for inert gas welding or inert gas soldering of workpieces (A) made of steel, aluminum, magnesium, copper, or the alloys thereof with workpieces (B) made of steel, aluminum, magnesium, copper, or the alloys thereof by using an additional molten metal alloy, workpieces (A) and (B) being made of identical or different metals or metal alloys. The inventive method is characterized by the following steps: a) the workpieces that are to be connected are contacted edge to edge or in an overlapping manner; b) the additional metal alloy containing a Zn/Al alloy is fused; c) the additional molten metal alloy is applied to the contact points or partial areas of the contact points of the contacted workpieces; d) the connected workpieces are cooled. Steps b) and c) are carried out immediately after one another while at least steps b) and c) are carried out by using an inert gas. The invention further relates to a wire that is used in said method.
    Type: Grant
    Filed: March 10, 2004
    Date of Patent: February 12, 2008
    Assignee: Grillo-Werke AG
    Inventors: Jochen Spriestersbach, Jurgen Wisniewski, Frank Prenger
  • Patent number: 7323031
    Abstract: The invention relates to zinc powders or zinc alloy powders with an inhomogeneous bulk density distribution depending on the particle size, wherein the difference of the bulk density measured according to ASTM B212 in the particle size range smaller than 75 ?m and that in the particle size range greater than 150 ?m is at least 0.5 g/cm3, and the mean bulk density of the powder, measured according to ASTM B212, ranges from 1.8 to 4.0 g/cm3. The invention is also directed to mixtures of said zinc powders or zinc alloy powders and to an alkaline battery including said powders.
    Type: Grant
    Filed: January 9, 2004
    Date of Patent: January 29, 2008
    Assignee: Grillo-Werke AG
    Inventors: Armin Melzer, Petra Merkel, Jochen Spriestersbach, Rudi Kube, Norbert Schulz
  • Patent number: 7067094
    Abstract: The process for the brightening of continuously produced sodium hydrogensulfate obtained in the reaction of sodium chloride and concentrated sulfuric acid in molten sodium hydrogensulfate in a circulation reactor, wherein evolved hydrogen chloride and heating gases generated by an immersion burner are withdrawn at various sites and seed crystals are added for a faster conversion of initially formed metastable phases, is that from 0.01 to 0.05% by weight of aluminium oxide and/or from 0.5 to 1.5% by weight of magnesium oxide and/or magnesium sulfate and, optionally, additionally calcium sulfate are added as seed crystals.
    Type: Grant
    Filed: August 30, 2004
    Date of Patent: June 27, 2006
    Assignee: Grillo-Werke AG
    Inventors: Klaus Driemel, Ingo Biertümpel, Horst Kirsch
  • Publication number: 20040173294
    Abstract: Zinc alloys containing from 5 to 35% by weight of aluminum and optionally further alloy components are used as constructional zinc for strips and plates.
    Type: Application
    Filed: March 22, 2004
    Publication date: September 9, 2004
    Applicant: Grillo-Werke AG
    Inventors: Michael Knepper, Jochen Spriestersbach, Andrea Jahny, Jurgen Wisniewski
  • Patent number: 6706220
    Abstract: In the mixture of metal and/or alloy particles and a liquid electrolytic medium, the metal and/or alloy particles are irregularly shaped, have a non-uniform surface and a bulk density of below 33% by weight of the specific density of the compact metal and/or the compact alloy, and the volume of the medium is larger than that which corresponds to the spaces between the particles in a dry packing.
    Type: Grant
    Filed: March 11, 2002
    Date of Patent: March 16, 2004
    Assignee: Grillo-Werke AG
    Inventor: Wolfgang Glaeser
  • Patent number: 6680085
    Abstract: The method for thermal spraying, especially of metals, for the coating of surfaces, wherein the material employed for coating is supplied in the form of a wire, molten and sprayed, uses a plasma arc.
    Type: Grant
    Filed: January 9, 2003
    Date of Patent: January 20, 2004
    Assignee: Grillo-Werke AG
    Inventor: Dieter Kley
  • Publication number: 20030099779
    Abstract: The method for thermal spraying, especially of metals, for the coating of surfaces, wherein the material employed for coating is supplied in the form of a wire, molten and sprayed, uses a plasma arc.
    Type: Application
    Filed: January 9, 2003
    Publication date: May 29, 2003
    Applicant: Grillo-Werke AG,
    Inventor: Dieter Kley
  • Publication number: 20030049157
    Abstract: The wire based on zinc and aluminum contains from 8 to 33% by weight of aluminum and up to 500 ppm of indium, in addition to zinc and the usual impurities. This wire is suitable for thermal spraying for corrosion protection, especially corrosion protection against high atmospheric humidity and high chloride ion concentrations according to DIN 50021-ss.
    Type: Application
    Filed: September 3, 2002
    Publication date: March 13, 2003
    Applicant: Grillo-Werke AG
    Inventors: Jochen Spriestersbach, Peter Staubwasser
  • Patent number: 6376102
    Abstract: The method for applying a zinc-based anticorrosion layer for reinforced concrete is characterized in that a layer consists of at least two layers, of which the first layer, directly sprayed on the concrete, is made of pure zinc and the second layer sprayed thereon is made of a zinc/alumimum alloy.
    Type: Grant
    Filed: December 27, 2000
    Date of Patent: April 23, 2002
    Assignee: Grillo-Werke AG
    Inventors: Jochen Spriestersbach, Michael Knepper, Jürgen Wisniewski
  • Patent number: 6224943
    Abstract: The method for improving the corrosion resistance of reinforced concrete coated with a thermal spray coat of metals, especially of zinc or zinc alloys, is effected by electrically connecting said spray coat with the armour and additionally coating it with a polyurethane resin which is applied as a low-viscosity solution in organic solvents.
    Type: Grant
    Filed: April 24, 2000
    Date of Patent: May 1, 2001
    Assignee: Grillo-Werke AG
    Inventors: Michael Knepper, Jochen Spriestersbach, Juergen Wisniewski
  • Patent number: 6071359
    Abstract: Tin and zinc based shot for use as ammunition having a diameter of from 1.5 to 5.5 mm, containing, by weight, in addition to tin and the usual unavoidable contaminants, from 12 to 60% of zinc and from 0 to 5% of aluminum, but less than 0.1% of copper, less than 0.1% of iron, and less than 1% of lead.
    Type: Grant
    Filed: October 24, 1997
    Date of Patent: June 6, 2000
    Assignee: Grillo-Werke AG
    Inventors: Jurgen Wisniewski, Jochen Spriestersbach
  • Patent number: 5240793
    Abstract: The zinc powder for alkaline batteries having a residual lead content of less than 30 ppm, an indium content of from 10 to 10,000 ppm, and preferably from 100 to 1,000 ppm, a gallium content of from 0 to 1,000 ppm and a content of alkali and/or alkaline earth metals of up to 1,000 ppm additionally contains from 10 to 10,000 ppm, and preferably from 100 to 1,000 ppm, of bismuth.
    Type: Grant
    Filed: September 24, 1991
    Date of Patent: August 31, 1993
    Assignee: Grillo-Werke AG
    Inventor: Wolfgang Glaeser
  • Patent number: 5191155
    Abstract: Polychlorinated waste materials such as polychlorinated dibenzodioxines (PCDD), polychlorinated dibenzofuranes (PCDF) and polychlorinated biphenyls (PCB) are subjected to nonpolluting destruction by combusting said materials together with waste sulfuric acids, acid tars and similar sulfur- and carbon-containing waste products of various compositions and consistencies in a multi-stage combustion furnace.
    Type: Grant
    Filed: October 7, 1991
    Date of Patent: March 2, 1993
    Assignee: Grillo-Werke AG
    Inventors: Klaus Driemel, Joachim Wolf, Wolfgang Schwarz
  • Patent number: 4968496
    Abstract: Disclosed are deodorants containing the hydrolyzed ene-adducts and Diels-Alder adducts of ricinene fatty acids and maleic anhydride, which preferably additionally contain(a) zinc ricinoleate with zinc compounds of multiply hydroxylated higher fatty acids, oxamines and resin acids and(b) solvents taken from the group of alcohols, optionally with the addition of water, triethanolamine and organic acids.
    Type: Grant
    Filed: July 14, 1988
    Date of Patent: November 6, 1990
    Assignee: Grillo-Werke AG
    Inventors: Dieter Rohe, Peter Bubel, Klaus Driemel
  • Patent number: 4963629
    Abstract: Copolymers of unsaturated carboxylic acids with alkaline solutions of monosaccharides or disaccharides capable of forming enolates provide polycarboxylates which are excellently suitable as sequestrants, complexing agents and co-builders in washing and cleaning agents.
    Type: Grant
    Filed: August 10, 1989
    Date of Patent: October 16, 1990
    Assignee: Grillo-Werke AG
    Inventors: Klaus Driemel, Klaus Bunthoff, Helmut Nies, Dieter Rohe
  • Patent number: 4548642
    Abstract: A zinc powder having a low gas evolution in an alkaline electrolyte for use in an alkaline battery are obtained by alloying the zinc with at least one metal selected from the group consisting of lead, cadmium, thallium and indium and at least one further metal selected from the group consisting of lead, cadmium, thallium, indium gold, silver, tin and gallium. Thereby it is possible to avoid the use of mercury as an alloying element but nevertheless to obtain a zinc powder which meet all of the requirements for use in alkaline batteries.
    Type: Grant
    Filed: March 27, 1984
    Date of Patent: October 22, 1985
    Assignee: Grillo-Werke AG
    Inventor: Wolfgang Glaeser
  • Patent number: 4460543
    Abstract: Zinc powder containing mercury for alkaline batteries are prepared by reacting zinc powder with metallic mercury in the presence of amalgamation aids with agitation in a closed system, at a partial oxygen pressure of less than 100 mbar, while the volatile parts are continually exhausted, then raising the partial value of atmosphere air. Additional alloying elements can be added to reduce the gas development, by mixing zinc powder with metallic mercury in which is dissolved a part or the entire quantity of the required alloying elements.
    Type: Grant
    Filed: April 6, 1983
    Date of Patent: July 17, 1984
    Assignee: Grillo-Werke AG
    Inventor: Wolfgang Glaeser