Abstract: The present invention relates to a process for preparing haloalkanesulfonic acids from sulfur trioxide and a haloalkane, particularly to a process for preparing trifluoromethane sulfonic acid from sulfur trioxide and trifluoromethane.
Type:
Grant
Filed:
May 23, 2019
Date of Patent:
April 25, 2023
Assignee:
Grillo-Werke AG
Inventors:
Timo Ott, Christian Diaz-Urrutia, Ingo Biertuempel
Abstract: The invention is directed to a zinc powder or zinc alloy powder for alkaline batteries, which powder has a grain size distribution wherein 60 to 100 wt.-% of the particles, relative to the zinc powder or zinc alloy powder, have a diameter of from 40 to 140 ?m. The invention is also directed to an alkaline battery.
Abstract: The invention relates to a method for inert gas welding or inert gas soldering of workpieces (A) made of steel, aluminum, magnesium, copper, or the alloys thereof with workpieces (B) made of steel, aluminum, magnesium, copper, or the alloys thereof by using an additional molten metal alloy, workpieces (A) and (B) being made of identical or different metals or metal alloys. The inventive method is characterized by the following steps: a) the workpieces that are to be connected are contacted edge to edge or in an overlapping manner; b) the additional metal alloy containing a Zn/Al alloy is fused; c) the additional molten metal alloy is applied to the contact points or partial areas of the contact points of the contacted workpieces; d) the connected workpieces are cooled. Steps b) and c) are carried out immediately after one another while at least steps b) and c) are carried out by using an inert gas. The invention further relates to a wire that is used in said method.
Type:
Grant
Filed:
March 10, 2004
Date of Patent:
February 12, 2008
Assignee:
Grillo-Werke AG
Inventors:
Jochen Spriestersbach, Jurgen Wisniewski, Frank Prenger
Abstract: The invention relates to zinc powders or zinc alloy powders with an inhomogeneous bulk density distribution depending on the particle size, wherein the difference of the bulk density measured according to ASTM B212 in the particle size range smaller than 75 ?m and that in the particle size range greater than 150 ?m is at least 0.5 g/cm3, and the mean bulk density of the powder, measured according to ASTM B212, ranges from 1.8 to 4.0 g/cm3. The invention is also directed to mixtures of said zinc powders or zinc alloy powders and to an alkaline battery including said powders.
Abstract: The process for the brightening of continuously produced sodium hydrogensulfate obtained in the reaction of sodium chloride and concentrated sulfuric acid in molten sodium hydrogensulfate in a circulation reactor, wherein evolved hydrogen chloride and heating gases generated by an immersion burner are withdrawn at various sites and seed crystals are added for a faster conversion of initially formed metastable phases, is that from 0.01 to 0.05% by weight of aluminium oxide and/or from 0.5 to 1.5% by weight of magnesium oxide and/or magnesium sulfate and, optionally, additionally calcium sulfate are added as seed crystals.
Type:
Grant
Filed:
August 30, 2004
Date of Patent:
June 27, 2006
Assignee:
Grillo-Werke AG
Inventors:
Klaus Driemel, Ingo Biertümpel, Horst Kirsch
Abstract: Zinc alloys containing from 5 to 35% by weight of aluminum and optionally further alloy components are used as constructional zinc for strips and plates.
Type:
Application
Filed:
March 22, 2004
Publication date:
September 9, 2004
Applicant:
Grillo-Werke AG
Inventors:
Michael Knepper, Jochen Spriestersbach, Andrea Jahny, Jurgen Wisniewski
Abstract: In the mixture of metal and/or alloy particles and a liquid electrolytic medium, the metal and/or alloy particles are irregularly shaped, have a non-uniform surface and a bulk density of below 33% by weight of the specific density of the compact metal and/or the compact alloy, and the volume of the medium is larger than that which corresponds to the spaces between the particles in a dry packing.
Abstract: The method for thermal spraying, especially of metals, for the coating of surfaces, wherein the material employed for coating is supplied in the form of a wire, molten and sprayed, uses a plasma arc.
Abstract: The method for thermal spraying, especially of metals, for the coating of surfaces, wherein the material employed for coating is supplied in the form of a wire, molten and sprayed, uses a plasma arc.
Abstract: The wire based on zinc and aluminum contains from 8 to 33% by weight of aluminum and up to 500 ppm of indium, in addition to zinc and the usual impurities. This wire is suitable for thermal spraying for corrosion protection, especially corrosion protection against high atmospheric humidity and high chloride ion concentrations according to DIN 50021-ss.
Type:
Application
Filed:
September 3, 2002
Publication date:
March 13, 2003
Applicant:
Grillo-Werke AG
Inventors:
Jochen Spriestersbach, Peter Staubwasser
Abstract: The method for applying a zinc-based anticorrosion layer for reinforced concrete is characterized in that a layer consists of at least two layers, of which the first layer, directly sprayed on the concrete, is made of pure zinc and the second layer sprayed thereon is made of a zinc/alumimum alloy.
Type:
Grant
Filed:
December 27, 2000
Date of Patent:
April 23, 2002
Assignee:
Grillo-Werke AG
Inventors:
Jochen Spriestersbach, Michael Knepper, Jürgen Wisniewski
Abstract: The method for improving the corrosion resistance of reinforced concrete coated with a thermal spray coat of metals, especially of zinc or zinc alloys, is effected by electrically connecting said spray coat with the armour and additionally coating it with a polyurethane resin which is applied as a low-viscosity solution in organic solvents.
Type:
Grant
Filed:
April 24, 2000
Date of Patent:
May 1, 2001
Assignee:
Grillo-Werke AG
Inventors:
Michael Knepper, Jochen Spriestersbach, Juergen Wisniewski
Abstract: Tin and zinc based shot for use as ammunition having a diameter of from 1.5 to 5.5 mm, containing, by weight, in addition to tin and the usual unavoidable contaminants, from 12 to 60% of zinc and from 0 to 5% of aluminum, but less than 0.1% of copper, less than 0.1% of iron, and less than 1% of lead.
Abstract: The zinc powder for alkaline batteries having a residual lead content of less than 30 ppm, an indium content of from 10 to 10,000 ppm, and preferably from 100 to 1,000 ppm, a gallium content of from 0 to 1,000 ppm and a content of alkali and/or alkaline earth metals of up to 1,000 ppm additionally contains from 10 to 10,000 ppm, and preferably from 100 to 1,000 ppm, of bismuth.
Abstract: Polychlorinated waste materials such as polychlorinated dibenzodioxines (PCDD), polychlorinated dibenzofuranes (PCDF) and polychlorinated biphenyls (PCB) are subjected to nonpolluting destruction by combusting said materials together with waste sulfuric acids, acid tars and similar sulfur- and carbon-containing waste products of various compositions and consistencies in a multi-stage combustion furnace.
Type:
Grant
Filed:
October 7, 1991
Date of Patent:
March 2, 1993
Assignee:
Grillo-Werke AG
Inventors:
Klaus Driemel, Joachim Wolf, Wolfgang Schwarz
Abstract: Disclosed are deodorants containing the hydrolyzed ene-adducts and Diels-Alder adducts of ricinene fatty acids and maleic anhydride, which preferably additionally contain(a) zinc ricinoleate with zinc compounds of multiply hydroxylated higher fatty acids, oxamines and resin acids and(b) solvents taken from the group of alcohols, optionally with the addition of water, triethanolamine and organic acids.
Type:
Grant
Filed:
July 14, 1988
Date of Patent:
November 6, 1990
Assignee:
Grillo-Werke AG
Inventors:
Dieter Rohe, Peter Bubel, Klaus Driemel
Abstract: Copolymers of unsaturated carboxylic acids with alkaline solutions of monosaccharides or disaccharides capable of forming enolates provide polycarboxylates which are excellently suitable as sequestrants, complexing agents and co-builders in washing and cleaning agents.
Type:
Grant
Filed:
August 10, 1989
Date of Patent:
October 16, 1990
Assignee:
Grillo-Werke AG
Inventors:
Klaus Driemel, Klaus Bunthoff, Helmut Nies, Dieter Rohe
Abstract: A zinc powder having a low gas evolution in an alkaline electrolyte for use in an alkaline battery are obtained by alloying the zinc with at least one metal selected from the group consisting of lead, cadmium, thallium and indium and at least one further metal selected from the group consisting of lead, cadmium, thallium, indium gold, silver, tin and gallium. Thereby it is possible to avoid the use of mercury as an alloying element but nevertheless to obtain a zinc powder which meet all of the requirements for use in alkaline batteries.
Abstract: Zinc powder containing mercury for alkaline batteries are prepared by reacting zinc powder with metallic mercury in the presence of amalgamation aids with agitation in a closed system, at a partial oxygen pressure of less than 100 mbar, while the volatile parts are continually exhausted, then raising the partial value of atmosphere air. Additional alloying elements can be added to reduce the gas development, by mixing zinc powder with metallic mercury in which is dissolved a part or the entire quantity of the required alloying elements.