Abstract: One aspect of the present invention relates to a mixing system for use in a chemical-process column. The mixing system includes a heavy-reactant mixing surface arranged perpendicular to a flow of reactant through the chemical-process column. The mixing system also includes an aperture formed in the heavy-reactant mixing surface. A pre-distributor is coupled to an underside of the mixing system and fluidly coupled to the aperture.

Abstract: A valve-tray assembly and method for lighter fluid heavier fluid contact towers. The active area of the tray is constructed with valves having multiple lighter fluid discharge areas facilitating improved mass transfer efficiency. The valves include first and second support legs oriented in line with the heavier fluid flow with both legs and the valve top constructed with apertures wherein the heavier fluid may flow into engagement with the lighter fluid passing from beneath the tray up, through and out of the valve.

Abstract: One aspect of the present invention relates to a mixing system for use in a chemical-process column. The mixing system includes a heavy-reactant mixing surface arranged perpendicular to a flow of reactant through the chemical-process column. The mixing system also includes an aperture formed in the heavy-reactant mixing surface. A pre-distributor is coupled to an underside of the mixing system and fluidly coupled to the aperture.

Abstract: A valve-tray assembly and method for lighter fluid heavier fluid contact towers. The active area of the tray is constructed with valves having multiple lighter fluid discharge areas facilitating improved mass transfer efficiency. The valves include first and second support legs oriented in line with the heavier fluid flow with both legs and the valve top constructed with apertures wherein the heavier fluid may flow into engagement with the lighter fluid passing from beneath the tray up, through and out of the valve.

Abstract: A liquid flow distributor for positioning above one or more packing sections in a packed exchange tower includes a plurality of troughs. At least one trough in the plurality of troughs has along a side thereto a deflecting member The deflecting member is angulated to generally follow a shape of the at least one trough. A diffuser side of the deflecting member is positioned to deposit the liquid into a discharge region. A plurality of break bars are disposed on the diffuser side of the deflecting member. A deflector side of the deflecting member is positioned for deflecting ascending vapor away from the discharge region.

Abstract: In existing structured packing, performance depends on effective contacting area. Performance decreases in cases having high surface tensions such mixtures containing a lot of water. Such mixtures are difficult to wet the packing surface. The present invention prevents liquid from intersecting the crease of the corrugation and from falling into a free space. Further, liquid flowing into the slot makes frequent liquid and vapor interfacial update resulting in positive utilization of the wetted area. The most important point of this invention is taking a large value of 3.5 or more of P/H (pitch/height of the crimp) and providing the horizontal slot on the crease, resulting in adding the flow reversal mechanism and frequent interfacial update.

Abstract: A separations tray assembly for use in a fluid-fluid exchange column. The separations tray assembly is of the type where a first fluid, in a continuous phase, is directed across successive trays in a serpentine flow path. A second fluid, in a dispersed phase ascends through apertures in the tray thus inducing interaction and mass transfer with the first fluid. In accordance with one aspect of the present invention, the separations tray further includes a diffuser skirt, having apertures disposed therein, operatively coupled to a fluid channel. The diffuser skirt is operable to direct the first fluid to cover substantially an entire volumetric cross-flow window between successive separations trays and to induce stirring and mixing of the first fluid and the second fluid to effect efficient mass transfer.

Abstract: Apparatuses and systems for removing heavy hydrocarbons from a solvent stream are disclosed herein. The apparatuses extract heavy hydrocarbons into light hydrocarbons and provide a solvent stream having the heavy hydrocarbons removed. Two water washing steps are used to remove residual solvent from the heavy hydrocarbon solution in light hydrocarbons. In some embodiments, the second water wash is used for processing subsequent batches of the solvent stream. The heavy hydrocarbons and solvent can be recovered and processed further. Methods for removing heavy hydrocarbons from a solvent stream are also disclosed herein.

Abstract: A separations tray assembly for use in a fluid-fluid exchange column. The separations tray assembly is of the type where a first fluid, in a continuous phase, is directed across successive trays in a serpentine flow path. A second fluid, in a dispersed phase ascends through apertures in the tray thus inducing interaction and mass transfer with the first fluid. In accordance with one aspect of the present invention, the separations tray further includes a diffuser skirt, having apertures disposed therein, operatively coupled to a fluid channel. The diffuser skirt is operable to direct the first fluid to cover substantially an entire volumetric cross-flow window between successive separations trays and to induce stirring and mixing of the first fluid and the second fluid to effect efficient mass transfer.

Abstract: In existing structured packing, performance depends on effective contacting area. Performance decreases in cases having high surface tensions such mixtures containing a lot of water. Such mixtures are difficult to wet the packing surface. The present invention prevents liquid from intersecting the crease of the corrugation and from falling into a free space. Further, liquid flowing into the slot makes frequent liquid and vapor interfacial update resulting in positive utilization of the wetted area. The most important point of this invention is taking a positive utilization of the wetted area. The most important point of this invention is taking a large value of 3.5 or more of P/H (pitch/height of the crimp) and providing the horizontal slot on the crease, resulting in adding the flow reversal mechanism and frequent interfacial update.

Abstract: The present invention relates to a valve tray for use in a chemical process column. The valve tray includes a plurality of apertures formed therein. A plurality of valves are maintained in a spaced relationship relative to individual apertures of the plurality of apertures. An area of the individual apertures is less than an area of individual valves of the plurality of valves.

Abstract: Embodiments disclose a process for converting gaseous alkanes to higher molecular weight hydrocarbons, olefins or mixtures thereofs wherein a gaseous feed containing alkanes may be reacted with a dry bromine vapor to form alkyl bromides and hydrobromic acid vapor. The mixture of alkyl bromides and hydrobromic acid then may be reacted over a synthetic crystalline alumino-silicate catalyst, such as a ZSM-5 or an X or Y type zeolite, at a temperature of from about 250° C. to about 500° C. so as to form hydrobromic acid vapor and higher molecular weight hydrocarbons, olefins or mixtures thereof. Various methods are disclosed to remove the hydrobromic acid vapor from the higher molecular weight hydrocarbons, olefins or mixtures thereof and to generate bromine from the hydrobromic acid for use in the process.

Abstract: Process and system that include the conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems. Alkyl bromides may be reacted over a catalyst in at least one conversion reactor to produce at least an effluent stream comprising higher molecular weight hydrocarbons and hydrogen bromide. A portion of the catalyst may be removed from the conversion reactor. The portion of the catalyst may be contacted with a stripping gas to displace hydrocarbons from the portion of the catalyst. The portion of the catalyst may be contacted a first inert gas. The portion of the catalyst may be contacted with oxygen to form a regenerated catalyst by removal of coke. The regenerated catalyst may be contacted with a second inert gas. At least a portion of the regenerated catalyst may be introduced into the conversion reactor.

Abstract: A chemical-process system includes a chemical-process column and a support disposed on an interior of the chemical-process column. A tray is disposed on a top surface of the support. A bolt is disposed through the tray and a clamp is disposed below the tray. The clamp has a notch formed therein for receiving a head region of the bolt. The clamp engages a bottom surface of the tray and a bottom surface of the support. The bolt is able to angularly displace with respect to at least one of the tray and the clamp.

Abstract: A chemical-process system includes a chemical-process column and a support disposed on an interior of the chemical-process column. A tray is disposed on a top surface of the support. A bolt is disposed through the tray and a clamp is disposed below the tray. The clamp has a notch formed therein for receiving a head region of the bolt. The clamp engages a bottom surface of the tray and a bottom surface of the support. The bolt is able to angularly displace with respect to at least one of the tray and the clamp.

Abstract: Processes and systems for synthesizing hydrocarbon products, such as high molecular weight hydrocarbons, olefins or mixtures thereof, from alkyl bromides wherein one or more streams of alkyl bromides may be reacted in sequential or concurrent stages at different temperatures. The catalyst used in the synthesis stages may be the same or different and at least in one instance is chosen to form hydrocarbon products having a significant C6+ paraffin content. The stages may be conducted in one or more reactors and the catalyst may be deployed in fixed beds or fluidized beds.

Abstract: A chemical-process system includes a chemical-process column and a support disposed on an interior of the chemical-process column. A tray is disposed on a top surface of the support. A bolt is disposed through the tray and a clamp is disposed below the tray. The clamp has a notch formed therein for receiving a head region of the bolt. The clamp engages a bottom surface of the tray and a bottom surface of the support. The bolt is able to angularly displace with respect to at least one of the tray and the clamp.

Abstract: An embodiment relates to a process for converting lower molecular weight, gaseous alkanes to higher hydrocarbons, such as olefins, higher molecular weight hydrocarbons, or mixtures thereof, that may use in-line hydrogen bromide oxidation for capture of hydrogen bromide produced in the process. An embodiment may provide a process for producing elemental halogen comprising: providing a first stream comprising a hydrogen halide; contacting the first stream with a metal oxide to form water, elemental halogen, and at least some metal halide, wherein the metal oxide comprises a metal capable of forming a plurality of stable oxidation states; and contacting the metal halide with an oxygen source to produce a regenerated metal oxide, wherein the oxygen source contacts the metal halide under conditions sufficient to avoid release of elemental halogen.

Abstract: Various embodiments of the present invention generally disclose systems and processes for the conversion of a feed stream comprising at least one C8 aromatic into a product stream comprising isophthalic acid and purified terephthalic acid (IPA/TA).

Abstract: A liquid flow distributor for positioning above one or more packing sections in a packed exchange tower includes a plurality of troughs. At least one trough in the plurality of troughs has along a side thereto a deflecting member. The deflecting member is angulated to generally follow a shape of the at least one trough. A diffuser side of the deflecting member is positioned to deposit the liquid into a discharge region. A deflector side of the deflecting member is positioned for deflecting ascending vapor away from the discharge region.