Abstract: A method for preparing a zinc manganate anode material is disclosed. The method includes the following steps: (1) preparing a solution A containing a manganese ion and a solution B containing zinc alkali; (2) dispersing an adsorption carrier into the solution B; (3) using an alkali solution as a base solution and adding the solution A, the solution B and an oxidant solution to the base solution while stirring; (4) conducting a solid-liquid separation of the materials after reaction to obtain a solid; and (5) washing, drying and calcining the solid to obtain a zinc manganate anode material.

Abstract: A method for preparing a copper-based anode material from a waste battery includes the following steps: (1) disassembling a waste battery and taking out an anode plate; (2) using the anode plate in step (1) as an anode and taking a copper foil current collector as a cathode, and placing the anode and the cathode in an electroplating solution for electroplating; (3) after the electroplating is completed, collecting anode powder separated from the anode and soaking the copper foil current collector in an acid solution; (4) washing and drying the soaked copper foil current collector; and (5) calcinating the copper foil current collector to obtain a copper-base anode material.

Abstract: A method for preparing a refractory material from waste battery residues. The method comprises the following steps: (1) disassembling waste batteries, then sorting same to obtain positive and negative electrode powders, leaching the positive and negative electrode powders with an acid, filtering same to obtain a graphite slag, and then subjecting the filtrate to copper removal, followed by the addition of an alkali for a precipitation reaction, wherein the resulting precipitate is an iron-aluminum slag; (2) wrapping the graphite slag obtained in step (1) with wet clay to form an inner core material, then mixing wet clay with the iron-aluminum slag, wrapping the inner core material with same, and aging the wrapped inner core material to obtain a blank; (3) pre-sintering, calcining and cooling the blank prepared in step (2) to obtain a fired product; and (4) washing and drying the fired product to obtain the refractory material.

Abstract: Disclosed is a method for recovering and processing a retired battery electrode plate. The method includes disassembling a retired battery to obtain an electrode plate, energizing two ends of the electrode plate until a binder on the electrode plate is heated and melted, and then separating out an electrode material and a current collector, and when the electrode plate is a negative electrode plate, ball milling the separated electrode material, winnowing the ball-milled material to obtain graphite, subjecting the graphite to an alkali treatment, adding the graphite, which has been subjected to the alkali treatment, and an aggregate to softened asphalt, and stirring same to obtain conductive asphalt. The two ends of the electrode are energized, such that the binder is melted into liquid to flow out of the current collector, and the electrode material is stripped off the electrode plate.

Abstract: Disclosed is a method for recovering and processing a retired battery electrode plate. The method includes disassembling a retired battery to obtain an electrode plate, energizing two ends of the electrode plate until a binder on the electrode plate is heated and melted, and then separating out an electrode material and a current collector, and when the electrode plate is a negative electrode plate, ball milling the separated electrode material, winnowing the ball-milled material to obtain graphite, subjecting the graphite to an alkali treatment, adding the graphite, which has been subjected to the alkali treatment, and an aggregate to softened asphalt, and stirring same to obtain conductive asphalt. The two ends of the electrode are energized, such that the binder is melted into liquid to flow out of the current collector, and the electrode material is stripped off the electrode plate.

Abstract: The present invention relates to a method for preparing nickel sulfate using low-nickel ferronickel is disclosed. The method comprises the following steps: (1) grinding ferronickel to obtain ferronickel powder, and then sintering the ferronickel powder with an oxidant to prepare ferronickel oxide powder; (2) adding sulfuric acid to the ferronickel oxide powder prepared in step (1), mixing, heating, and washing with water to prepare a sulfate salt water washing solution; (3) adding a base to the sulfate salt water washing solution prepared in step (2) to adjust the pH value, then adding a fluoride salt to form a precipitate, filtering to remove the precipitate, and drying the filtrate to obtain nickel sulfate. The method provided in the present invention can improve the efficiency of preparing nickel sulfate, reduce the loss of nickel, and prepare nickel sulfate with high purity, the content of Ni potentially reaching 19.73%-21.34%.

Abstract: Disclosed in the present invention is a method for extracting valuable metal from low-matte nickel converter slag. The method comprises: mixing low-matte nickel converter slag and quicklime then calcinating, obtaining a calcinated material; grinding and magnetically separating the calcinated material, obtaining silicate and iron-rich slag; adding a strong alkali solution to the iron-rich slag to perform leaching processing, and performing solid-liquid separation, obtaining a filtrate and a residue; mixing the residue with an acid solution, performing oxygen pressure acid leaching, and performing solid-liquid separation, obtaining a leachate and iron oxide; introducing hydrogen sulfide gas into the leachate, adjusting the pH, and performing solid-liquid separation, obtaining a copper sulfide precipitate and a nickel-cobalt-containing filtrate.

Abstract: A method for enriching lithium from a lithium clay includes the following steps (1) the raw ore were crushed to produce fine particles, (2) performing rougher on the fine particles by adding ferric sulfate or ferric nitrate, sodium oleate, and cocoamine to obtain rough concentrate and rough tailing, (3) finely separating the rough concentrate to obtain the first part of concentrate, (4) re-grinding the rough tailing by ball mill, (5) performing rougher on the reground tailing to obtain reground rough concentrate and re-ground rough tailing, (6) performing cleaner on the reground rough concentrate to obtain the second part of concentrate, and (7) performing scavenger on the reground rough tailing to obtain the cleaned tailing.

Abstract: Disclosed is a preparation method of porous sodium iron phosphate used as a sodium ion battery cathode material, which includes: mixing ferrous nitrate, silver nitrate and a reducing agent to prepare a mixed solution, adding the mixed solution dropwise to a carbonate solution for reaction to obtain a precipitate, mixing the precipitate with sodium dihydrogen phosphate and sodium iodide and then grinding, sintering the ground material under the condition of air isolation, and soaking the sintered material in an organic solvent to obtain porous sodium iron phosphate used as a sodium ion battery cathode material.

Abstract: A method for recycling and preparing a positive electrode material from waste lithium iron phosphate batteries. The method comprises the following steps: discharging, crushing, and stripping waste lithium iron phosphate batteries to obtain black powder; then mixing the black powder with benzenesulfonate, and reacting in a fluidized bed; and then adding an acid and an alkali to remove impurities, finally adding a lithium supplement, an iron supplement, or a phosphate, and a reducing agent, and sintering. According to the method, by controlling and optimizing the crushing, stripping, carbon and fluorine removal, and impurity removal processes, a positive electrode material with high purity can be recycled while controlling the recycling cost, and batteries prepared by means of the recycled positive electrode material have good performance.

Abstract: Disclosed are a nickel-iron wet treatment method and an application thereof. The treatment method comprises: in a high-pressure oxygen environment, mixing a crushed nickel-iron material, sulphuric acid and a corrosion aid, performing an acid leaching reaction, then performing solid-liquid separation on slurry subjected to acid leaching, adding an oxidant into the obtained filtrate, performing heating, removing the corrosion aid, adding a precipitating agent into the filtrate, controlling the pH value of the filtrate, and performing solid-liquid separation to obtain a ferric hydroxide precipitate and a nickel-containing filtrate; and performing extraction and back extraction on the nickel-containing filtrate to prepare battery-grade nickel sulphate.

Abstract: Disclosed in the present invention is a method for extracting nickel from a high matte nickel leaching residue. The method comprises: firstly, adding a crushed material of a high matte nickel leaching residue to an organic solvent in which sulfur is dissolved, heating same for reaction, and carrying out solid-liquid separation to obtain a first filtrate and a first filter residue; adding the first filter residue to a copper sulfate solution, heating same for reaction, and carrying out solid-liquid separation to obtain a second filtrate and a second filter residue; and evaporating, condensing and concentrating the second filtrate, and filtering same to obtain copper sulfate crystals and a nickel-containing filtrate. Throughout the whole reaction, only a small amount of sulfur and copper sulfate are consumed, and the organic solvent can be recycled.

Abstract: A fixing assembly includes a connecting sleeve, a spike member, and an elastic member; the spike member is rotatably connected to the connecting sleeve; one end of the elastic member is connected to the connecting sleeve, and the other end of the elastic member is connected to the spike member; the elastic member at least helically surrounds and abuts against the outer peripheral wall of the spike member, and the elastic member is configured to generate elastic deformation when the spike member rotates relative to the connecting sleeve along a direction opposite to the helical surrounding direction of the elastic member; there is an included angle between the direction of elastic deformation and the axial extension direction of the spike member to form a helical convex elastic structure.

Abstract: The present invention discloses a preparation method for and the use of a lithium silicate-based adsorbent. The method comprises: mixing and stirring butyl methacrylate, an acid and an organic solvent to obtain a first solution; adding lithium silicate, an initiator and N,N?-methylenebisacrylamide into the first solution, and heating and stirring same for a reaction to obtain a second solution; subjecting the second solution to low-temperature dehydration, cooling and drying to obtain a lithium silicate-based polymer; mixing the lithium silicate-based polymer with a third solution; and subjecting same to low-temperature carbonization under anoxic conditions, so as to obtain the lithium silicate-based adsorbent, wherein the third solution is obtained by mixing cotton fibers, tartaric acid, carboxymethylcellulose and water.

Abstract: The present invention discloses a preparation method for and the use of a lithium silicate-based adsorbent. The method comprises: mixing and stirring butyl methacrylate, an acid and an organic solvent to obtain a first solution; adding lithium silicate, an initiator and N,N?-methylenebisacrylamide into the first solution, and heating and stirring same for a reaction to obtain a second solution; subjecting the second solution to low-temperature dehydration, cooling and drying to obtain a lithium silicate-based polymer; mixing the lithium silicate-based polymer with a third solution; and subjecting same to low-temperature carbonization under anoxic conditions, so as to obtain the lithium silicate-based adsorbent, wherein the third solution is obtained by mixing cotton fibers, tartaric acid, carboxymethylcellulose and water.

Abstract: The present disclosure discloses a preparation method of a tin-based lithium cobaltate precursor and use thereof. The method involves adding a cobalt salt solution, a precipitant and a complexing agent for reaction to obtain a precipitate, wherein the precipitant is a mixed solution of carbonate and stannate; calcining the precipitate; and mixing the calcined material with dioxane, ball-milling the mixture, and subjecting the ball-milled product to a heating and pressurization treatment to obtain the tin-based lithium cobaltate precursor. In the present disclosure, after carbonate and stannate are blended, the blend react with cobalt salt to form the co-precipitate of cobalt carbonate and cobalt stannate, and after calcination, a mixture of cobalt(II,III) oxide and tin dioxide is formed. By utilizing dioxane for solvent hot pressing, particles are bonded to each other, forming grain boundary channels. In addition, by doping with tin, the conductivity of the material is improved.

Abstract: Disclosed is a method for efficiently removing fluorine from a spent lithium battery. The method comprises: mixing aluminum and a sodium hydroxide solution for reaction to obtain a sodium metaaluminate solution; introducing sulfuric acid into the sodium metaaluminate solution, and stirring to react at a certain temperature to obtain a fluorine removal agent; adding a sodium fluoroaluminate seed crystal and the fluorine removal agent into an impurity-removed battery powder leaching solution, introducing a sodium carbonate solution at the same time, performing reaction at a certain temperature, controlling the pH value of a reaction endpoint, and performing solid-liquid separation after the reaction is finished to obtain a fluorine-removed liquid and filter residues; and adding the sodium hydroxide solution into the filter residues for reaction, and performing solid-liquid separation to obtain a filtrate containing fluorine and aluminum, and insoluble residues.

Abstract: Disclosed is a method for repairing a waste silicon-carbon material which relates to the technical field of secondary batteries. The method for repairing a waste silicon-carbon material includes the following steps: (1) pretreating the waste silicon-carbon material to obtain a powdery mixture; (2) mixing the powdery mixture obtained in step (1) with an metal-organic framework compound, and washing and drying the mixture to obtain a black powder; and (3) mixing the black powder obtained in step (2) with graphite, calcining the mixture in an acetylene atmosphere, and subjecting the calcined product to vapor deposition, cooling, washing and drying to obtain a silicon-carbon material.

Abstract: Disclosed are a rod-shaped sodium ion positive electrode material, a preparation method therefor and an application thereof. The material comprises a rod-shaped base material and nanofibers inserted into the base material. C—Na is loaded on the nanofibers. The chemical general formula of the rod-shaped sodium ion positive electrode material is Na(FeaTb)PO4/CNF-c(C—Na), and 0.001?c?0.1, wherein T is at least one of Ni, Co, Zn, Mn, Fe, V, Ti or Mo, 0.9?a<1, 0<b?0.2, and 0.001?c?0.1. In the present invention, on one hand, some transition metal elements are doped to improve the electrochemical performance thereof, and on the other hand, a modulator is added to synthesize the rod-shaped sodium ion positive electrode material, and the C—Na loaded nanofibers are added to adjust the proportion of large and small rod-shaped materials, so that the composition of a single Na(FeaTb)PO4 rod-shaped nanostructure is optimized.

Abstract: Disclosed is a method for purifying a nickel-cobalt-manganese leaching solution.