Abstract: The present invention relates to a hydrogen storage alloy, an electrode for a Ni-MH battery, a secondary battery, and a method for preparing the hydrogen storage alloy. The chemical composition of the hydrogen storage alloy is expressed by the general formula La(3.0˜3.2)xCexZrySm(1-(4.11˜4.2)x-y)NizCouMnvAlw, where x, y, z, u, v, w are molar ratios, and 0.14?x?0.17, 0.02?y?0.03, 4.60?z+u+v+w?5.33, 0.10?u?0.20, 0.25?v?0.30, and 0.30?w?0.40. The atomic ratio of the metal lanthanum (La) to the metal cerium (Ce) is fixed at 3.0 to 3.2, which satisfies the requirements of the overcharge performance of the electrode material. A side elements are largely substituted by samarium (Sm) element, that is, the atomic ratio of Sm on the A side is 25.6% to 42%, so as to solve the problem of shortened cycle life caused by the small amount of cobalt (Co) atoms.
Type:
Grant
Filed:
May 28, 2019
Date of Patent:
March 12, 2024
Assignees:
South China University of Technology, Sihui Dabowen Industrial Co., Ltd., Guangdong Research Institute of Rare-Metal
Inventors:
Liuzhang Ouyang, Cheng Tan, Min Zhu, De Min, Hui Wang, Tongzhao Luo, Fangming Xiao, Renheng Tang