Patents Assigned to H. B. Fuller Licensing & Financing, Inc.
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Patent number: 5503884Abstract: A novel, pumpable, thermoplastic desiccated mastic capable of desiccating a scaled insulating glass unit. The compositions utilize adhesive materials which have a low vapor transmission rate but, nevertheless, have been found to effectively dry the air space in the unit. They do not contribute to chemical fogging and, in preferred embodiments, reduce or eliminate chemical fogging caused by other structures in the assembly. The compositions adhere well to the U-channel material and do not flow or sag under the normal range of service conditions encountered by an insulating glass assembly.Type: GrantFiled: October 21, 1994Date of Patent: April 2, 1996Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Paul J. Meyer, Anne Spinks
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Patent number: 5498646Abstract: Method for preparing adhesive compositions subjecting a mixture of block polymer and other adhesive constituents e.g., resin(s) and oil(s) to shearing and smearing in an emulsifier disperser.Type: GrantFiled: September 6, 1994Date of Patent: March 12, 1996Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Glenn C. Heuer, George F. Bateson
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Patent number: 5496907Abstract: Compounds containing a ureido group which are useful in preparing dispersions of polymers having good wet adhesion properties and low volatility. Compounds having the formula: ##STR1## where R.sup.1 is H or an alkyl group, R.sup.2 is alkylene optionally interrupted with one or more ether oxygen atoms and A is H or a residue of an active hydrogen reactive compound are useful for incorporating ureido and optionally nitrile functionality into polymers and as precursors to amino compounds prepared by reduction of the nitrile group thereof. Compounds having the formula: ##STR2## where B is defined as for A and the same or different than A are also disclosed. The disclosed compounds have use as chain extending or terminating monomers for polyurethane dispersions when one or both of A and B are H and, when one of A and has ethylenic unsaturation, as wet adhesion monomers in dispersions of free radically polymerized polymers of unsaturated monomers.Type: GrantFiled: September 2, 1994Date of Patent: March 5, 1996Assignee: H. B. Fuller Licensing & Financing, Inc.Inventor: Michael J. Dochniak
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Patent number: 5494960Abstract: Aqueous polyurethane dispersions used in adhesives for manufacturing laminate structures are provided with improved dispersion properties, which provide improved shelf-life stability of the dispersion and greater transparency and handling characteristics in application machinery for adhesives formulated therefrom, when a tertiary amine is present during an initial polyurethane prepolymer reaction between an isocyanate and a polyol component having acid functional groups. The initial reaction is carried out prior to formation of the dispersion in water.Type: GrantFiled: April 7, 1993Date of Patent: February 27, 1996Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: Thomas E. Rolando, Peter A. Voss, Christopher M. Ryan
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Patent number: 5459167Abstract: To manufacture high quality, fine pored silicone foam parts by the injection molding process, two reaction components A and B are used. They both contain a silicone polymer and fumed silica. The component A also contains a complexed organo-platinum catalyst and a small portion of water, whereas the other component B contains as a crosslinker polydimethyl hydrogen siloxane.At least one of the two components A and B of the mixture is pressurized with a gas, preferably air or nitrogen, in a pressure container so that the gas is dissolved into the component(s). The components A and B are mixed in the pressure process, injected into an injection mold, and heated so that the foaming process forms the silicone foam part.Type: GrantFiled: October 25, 1993Date of Patent: October 17, 1995Assignee: H. B. Fuller Licensing & Financing, Inc.Inventor: Franz J. Giesen
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Patent number: 5459193Abstract: An improved hot melt adhesive with low self-adhesion. The adhesive is useful for disposable articles and employs a S-EB-S block copolymer. The adhesive does not require a release liner and has superior stay-in-place properties.Type: GrantFiled: February 23, 1995Date of Patent: October 17, 1995Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Carolyn M. Anderson, Eugene R. Simmons
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Patent number: 5454898Abstract: Corrugating adhesives free of incompatibility problems with water soluble partially hydrolized polyvinyl alcohol comprise a major portion of water, starch, strong base, a boric acid compound and a partially hydrolized water soluble polyvinyl alcohol composition.Type: GrantFiled: October 6, 1989Date of Patent: October 3, 1995Assignee: H. B. Fuller Licensing & Financing Inc.Inventor: Paul L. Krankkala
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Patent number: 5443674Abstract: A method of binding book blocks to form books is disclosed. The method involves applying an aqueous composition to the spine area of a book block and removing the volatile components of the composition. The composition comprises (1) an aqueous vehicle, a film-forming polymeric resin, and a polyurethane resin or (2) an aqueous polyurethane dispersion or emulsion. The composition may also include an alkaline component. In another embodiment, the composition comprises a mixture of an aqueous, film-forming polymeric latex, an alkaline component to adjust the pH the latex to that of an aqueous polyurethane dispersion, and the aqueous polyurethane dispersion.Type: GrantFiled: August 31, 1992Date of Patent: August 22, 1995Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: Flavia M. Fresonke, Ramesh Mehta
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Patent number: 5444108Abstract: A mechanically peelable masking coating composition particularly useful for metals, and the method of preparing same for use is provided. The composition is heat curable in one or two heatings to produce a firmly adhering yet peelable coating. In its preferred form the composition comprises a mixture of a dispersion grade vinyl, a plasticizer, an adhesion promoter such as an epoxy, and optionally a thixotrope where greater resistance to sag and flow are desired. No fugitive solvents are required.Type: GrantFiled: April 8, 1994Date of Patent: August 22, 1995Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: James A. E. Hagquist, Lawrence L. Micek
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Patent number: 5403874Abstract: Method for preparing adhesive compositions by dissolution of the block polymer component(s) thereof in a hot melt of the other adhesive constituents e.g., resin(s) and oil(s).Type: GrantFiled: December 23, 1992Date of Patent: April 4, 1995Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: Glenn C. Heuer, George F. Bateson
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Patent number: 5399706Abstract: Imidazolidinone compounds of the formula: ##STR1## where R is a C.sub.3 -C.sub.5 alkylene group, R.sup.1 and R.sup.2 are independently H or C(.dbd.O)R.sup.4, R.sup.3 is an aliphatic hydrocarbon group optionally substituted with one or more alkoxy groups or interrupted by one or more ether oxygen atoms, and R.sup.4 is a hydrocarbon group substituted with an active hydrogen functional group are useful as chain extending monomers providing pendant imidazolidinone functionality to polyurethane/urea and epoxy polymers. The subject imidazolidinone compounds may also be incorporated into polyester/polyamide polyols or reacted to prepare radically polymerizable ethylenically unsaturated monomer and prepolymer compounds used in the synthesis of emulsion polymers.Type: GrantFiled: March 2, 1993Date of Patent: March 21, 1995Assignee: H. B. Fuller Licensing & Financing, Inc.Inventor: Michael J. Dochniak
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Patent number: 5391436Abstract: Metal casing structures for windows, doors frames and the like which employ a cured polyurethane thermal break produced from a liquid curable formulation catalyzed by certain tertiary amines, especially a diazabicyclic compound, between respective interior and exterior facing segments of the casing have much greater resistance to debonding of the break on thermal cycling than do casings manufactured using prior art formulations catalyzed with metal compounds.Type: GrantFiled: June 7, 1993Date of Patent: February 21, 1995Assignee: H. B. Fuller Licensing & Financing, Inc.Inventor: Kevin J. Reid
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Patent number: 5356940Abstract: A process for producing a high quality silicone foam by free foaming, in which a two-component addition crosslinking system is used, comprised of a component A which contains a silicone polymer having at least two double bonds per molecule, preferably vinyl groups, a complexed organo-platinum for example with butanol, fumed silica, and water, as well as further additives, if appropriate, and a component B which contains a silicone polymer having at least two double bonds per molecule, preferably vinyl groups, fumed silica, and polydimethyl hydrogen siloxane as SiH crosslinking agent. The two components A and B are mixed, and the reaction mixture is subsequently pressurized, preferably using compressed air or nitrogen, in a storage vessel over several hours so that the gas is present in the mixture in a dissolved form.Type: GrantFiled: October 22, 1993Date of Patent: October 18, 1994Assignee: H. B. Fuller Licensing & Financing, Inc.Inventor: Franz J. Giesen
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Patent number: 5354807Abstract: Improved anionic water dispersible polyurethanes are disclosed. Polyurethane-urea polymers in aqueous dispersion are obtained by chain extending an NCO-containing prepolymer in aqueous medium. The NCO-containing prepolymer is prepared by reacting a polyisocyanate with an active hydrogen-containing compound such as a polyol and dimethylolpropionic acid (DMPA) to form a pre-prepolymer and to this is added a diamine monomer containing a pendant aliphatic, to form the prepolymer which is then dispersed in water and chain extended. The improved anionic water dispersible polyurethane polymers of the invention form excellent coatings and adhesives.Type: GrantFiled: August 3, 1993Date of Patent: October 11, 1994Assignee: H. B. Fuller Licensing & Financing, Inc.Inventor: Michael J. Dochniak
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Patent number: 5348680Abstract: A cleaning compound for removing reactive polyurethane (PUR) hot melt adhesives from production and processing devices, machines and equipment which includes at least one reactive monofunctional hydroxyl compound which can react with the reactive isocyanate groups of the hot melt adhesive. The monohydroxy functional compound of the invention's cleaning compound completely saturates the remaining NCO groups of the hot melt adhesive to be removed, converting the adhesive into non-reactive, meltable compounds which are soluble in the cleaning compound.Type: GrantFiled: November 23, 1992Date of Patent: September 20, 1994Assignee: H. B. Fuller Licensing & Financing, Inc.Inventor: Franz Maitz
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Patent number: 5330601Abstract: Pretreatment of elastomer substrate surfaces with aqueous solutions of monopersulfate compound (MPS) and the improved adhesive bonds obtained between such pretreated substrate surfaces and other substrates.Type: GrantFiled: May 20, 1993Date of Patent: July 19, 1994Assignee: H.B. Fuller Licensing & Financing, Inc.Inventor: Peter Gottschalk
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Patent number: 5328539Abstract: The present invention includes a thermoplastic receptor for radio signals having a frequency of about 1 to 100 MHz, the receptor having a dissipation factor of about 0.1 or greater. Also disclosed are heat meltable adhesives, film compositions, and composites comprising a thermoplastic and a thermoplastic receptor. The present invention also includes a method of applying a thermoplastic composition by applying radio signals having a frequency of about 1 to 100 MHz to a composition comprising a thermoplastic composition and a receptor.Type: GrantFiled: December 31, 1992Date of Patent: July 12, 1994Assignee: H. B. Fuller Licensing & Financing Inc.Inventor: Norman J. Sato
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Patent number: 5318198Abstract: The invention relates to containers for hot melt adhesives containing isocyanate compounds and to such containers used with heated platen dispensing equipment for the hot melt. More particularly, the invention relates to containers and dispensers for isocyanate containing adhesives that can dispense the adhesive to a use locus without generating toxic concentrations of isocyanate compounds in the environment around the dispenser. The isocyanate compounds are sealed within the containers during dispensing, preventing the generation of a toxic concentration of isocyanate in the environment or the atmosphere during dispensing operations.Type: GrantFiled: August 28, 1992Date of Patent: June 7, 1994Assignee: H.B. Fuller Licensing & Financing Inc.Inventors: Lawrence L. Micek, Michael J. Maksymkiw
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Patent number: 5310588Abstract: A sealant for use at temperatures greater than about 700.degree. F. may be formed from:(a) about 40 to 90 wt-% of a silicone having a molecular weight of about 10,000 to 10,000,000 and repeating units comprising:(i) about 1 to 20 mole-% of units having the formula: ##STR1## wherein R comprises --H, a C.sub.1-5 alkyl group, a C.sub.1-5 fluoroalkyl group, a vinyl group or a phenyl group and(ii) about 99 to 80 mole-% of units having the formula: ##STR2## wherein each R independently comprises --H, a C.sub.1-5 alkyl group, a C.sub.1-5 fluoroalkyl group, a vinyl group, or a phenyl group; and(b) about 1 to 10 wt-% of a thermal stabilizer;(c) about 0.1 to 2 wt-% of a curing agent; and(d) about 0 to 50 wt-% of an inorganic filler;wherein the composition remains an effective sealant at temperatures above about 700.degree. F. The sealant may be used to bond and seal a barrier film or vacuum bag to a forming tool in autoclave curing and processing of thermosetting and thermoplastic composites.Type: GrantFiled: August 13, 1991Date of Patent: May 10, 1994Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: Brian W. Carlson, Brian S. Glasbrenner
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Patent number: 5196470Abstract: An alcohol based, water soluble binder composition for nonwoven material made from water swellable, water soluble or water sensitive fibers and related substances is provided comprising a substantially anhydrous solution of an acrylic polymeric resin, and an alcohol diluent. The water soluble binder composition effectively binds water swellable, water soluble or water sensitive fibers into a nonwoven material such as a fabric; the nonwoven material comprising a nonwoven web of a water swellable, soluble or sensitive fiber component.Type: GrantFiled: March 1, 1991Date of Patent: March 23, 1993Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: Stewart C. Anderson, Richard Malmsten