Patents Assigned to H. B. Fuller
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Patent number: 6120887Abstract: This invention relates to a non-contact coating method for producing a continuous coating and articles constructed therefrom. This invention further relates to a method for producing a textile material with a moisture-impermeable barrier layer and to a method for producing a moisture-absorbing article of hygiene which has such a barrier layer. This invention particularly relates to a textile material and hygienic disposable articles comprising a body fluid impermeable barrier layer which can be produced from a non-contact coating method. Preferably, the thermoplastic composition used for producing the barrier layer exhibits certain rheological characteristics and comprises at least one homogeneous linear or substantially linear interpolymer of ethylene with at least one C.sub.3 -C.sub.20 alpha-olefin, further characterized by each said interpolymer having a polydispersity less than about 2.5.Type: GrantFiled: August 29, 1996Date of Patent: September 19, 2000Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Harald Werenicz, Thomas Wittkopf, Gerhard Voss, Peter Remmers, Mark G. Katsaros, Robert G. Polance, II, Mark S. Kroll, Wendy Hoenig, Selim Yalvac, Kalyan Sehanobish, Teresa Karjala, Deepak Parikh, David C. Kelley
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Patent number: 6112477Abstract: A pumpable, thermoplastic desiccated mastic capable of desiccating a sealed insulating glass unit. The disclosed compositions comprise a defined resin component and a desiccant/adsorbent component comprising at least 20% by weight of the composition of a desiccant or moisture and volatile organic chemical adsorbing material. The said desiccant/adsorbent component being present in an amount less than the level which will cause the composition when tested as set forth in ASTM D-1238, Procedure B using a 1100 gram load and an 8 gram sample at 190.degree. C. to provide a melt flow time for a piston travel of 2.54 cm(1 inch) of more than 60 seconds.Type: GrantFiled: April 2, 1997Date of Patent: September 5, 2000Assignee: H. B. Fuller Licensing & Financing Inc.Inventor: Anne Spinks
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Patent number: 6106950Abstract: The present invention relates to oxygen barrier film structures and a method of using thereof. More particularly, the invention relates to oxygen barrier film structures comprising at least one substrate, a primer layer on at least one surface of the substrate, said primer comprising a mixture of at least one aqueous dispersion of polyurethane (A) and at least one water dispersible crosslinking agent (B); an oxygen and moisture resistant barrier coating onto said primer treated surface of the polymeric substrate; said coating comprising a mixture of at least one aqueous polyvinyl alcohol or its copolymers (C) and at least one crosslinking agent (D). Improved adhesion properties of the barrier coating on substrates such as polyolefin, polyester and polyamide are obtained.Type: GrantFiled: June 4, 1998Date of Patent: August 22, 2000Assignee: H. B. Fuller Licesing & Financing Inc.Inventors: Brenda C. Searle, Leonard C. Jannusch, Thomas E. Rolando, Peter A. Voss, Craig P. Copping
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Patent number: 6087550Abstract: This invention relates to water responsive thermoplastic compositions and articles constructed thereof. This invention particularly relates to thermoplastic copolyester compositions useful for the manufacture of disposable articles such as disposable diapers and feminine napkins. More particularly, this invention relates to thermoplastic copolyester compositions that are useful as a raw material in the manufacture of nonwovens, barrier films or coatings and as well as for various improved hot melt adhesives compositions useful for incorporating hydrophilic features into disposable articles.Type: GrantFiled: November 22, 1995Date of Patent: July 11, 2000Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Carolyn Anderson-Fischer, Mai Nguyen, Mark S. Hull, Mark G. Katsaros, Mark S. Kroll, Greg J. VanLith
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Patent number: 6067776Abstract: The present invention is directed to a method of packaging thermoplastic compositions. Preferably, the steps of the method may be employed in a continuous process. The method is especially suited for thermoplastic compositions such as pressure sensitive hot melt adhesives. The pressure sensitive thermoplastic composition may be packaged in an inclusion meltable film material wherein the film can be melted and blended with the hot melt adhesive during use, or alternatively, the composition may be contained in a drum. Alternatively the thermoplastic composition may be coated with a pelletizing aid.Type: GrantFiled: April 29, 1998Date of Patent: May 30, 2000Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Glenn C. Heuer, Norris R. Brand, Randall D. Nelson, Wolfgang Weber
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Patent number: 6031045Abstract: A method for the preparation of sulfonated polymer compositions wherein water dispersible isocyanate-terminated polyurethane prepolymers are reacted in the presence of aqueous polyvinyl dispersions which may contain active hydrogen atoms. The invention is further directed to a water-based sulfonated polyurethane polyvinyl hybrid latex wherein a sulfonated polyurethane is used as a seed for the polymerization of ethylenically unsaturated monomers and a method for preparing the same. The inventive compositions develop interpenetrating polymer networks or may form core-shell type structures, and are characterized as having enhanced mechanical and adhesion properties.Type: GrantFiled: August 12, 1997Date of Patent: February 29, 2000Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Yi Wei, Youlu Duan, Yuduo Zhu
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Patent number: 6020429Abstract: This invention relates to a catalyzed reactive hot melt adhesive comprising a) a reactive polyurethane adhesive and b) from about 0.005% to about 0.04% by weight of a catalyst selected from the group consisting of 2,2-dimorpholinoethyl ether and di(2,6-dimethyl morpholinoethyl) ether.Type: GrantFiled: June 18, 1997Date of Patent: February 1, 2000Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Kang Yang, Michelle B. Acquaye
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Patent number: 5905104Abstract: The invention provides a protective coating composition for use on substrates including steel, aluminum, iron and the like. This composition further provides abrasion resistance, electrical resistance, ultra-violet protection, corrosion resistance and heat resistance. It can be particularly useful for coating high temperature stacks, mufflers, manifolds, boilers, ovens, furnaces, steam lines, heat exchangers, barbecue equipment, cooking utensils and other parts that require such powder coating composition. This composition further provides good initial adhesion.This invention also provides a powder coating composition containing a hydroxyl-functional silicone resin, a glycidyl-functional acrylic resin and an optional flow control agent.Type: GrantFiled: October 29, 1997Date of Patent: May 18, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Wayne G. Eklund, Paula Torrejon Ramos, Charles J. Torborg
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Patent number: 5883217Abstract: The present invention relates to polyurethane hot melt adhesive that are hardened by the action of moisture and which contain at least one reaction product from a component that contains NCO groups and an essentially linear hydroxypolyester, hydroxypolyether, and/or hydroxypolyetherester component. In addition, the present invention relates to a procedure for manufacturing a material that is permeable to water only in vapor form, this being in the form of a fiber material, in particular in the form of a web, which is joined to a polyurethane film, in which the fiber material is coated with a polyurethane material and subsequently the polyurethane material is hardened to form a water-vapor permeable film. The present invention also relates to a material that is permeable to water only in vapor form and which is in the form of a fiber material, in particular in the form of a web, that is bonded to a polyurethane film.Type: GrantFiled: June 24, 1997Date of Patent: March 16, 1999Assignee: H. B. Fuller CompanyInventors: Harald Werenicz, Franz Maitz, Walter Nussbaumer, Ludwig Stingl, Franz Peter-Schmitz
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Patent number: 5872182Abstract: A water-based sulfonated polyurethane composition and footwear manufactured using the composition as as an adhesive, coating and primer. The sulfonated polyurethane is a reaction product ofa) at least one polyisocyanate;b) at least one alkylene diol;c) at least one sulfonated polyester polyol wherein the sulfo groups thereof are present as alkali metal salts; andd) at least one dihydroxy carboxylic acid, or salt thereof. The composition may also be modified to include a dispersed polymer or copolymer of an ethylenically unsaturated monomer. Such mofified compositions may be obtained by preparing the sulfonated polyurethane in the presence of an ethylenically unsaturated monomer and subsequently subjecting the mixture to free-radical polymerization conditions.Type: GrantFiled: November 21, 1995Date of Patent: February 16, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Youlu Duan, Sonja Stammler, Jillian H. Ierien, Brian L. Marty
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Patent number: 5869596Abstract: This invention relates to a nonwoven web and fibers comprising a water soluble polyamide and articles constructed therefrom. The water soluble polyamide may be used alone or in combination with conventional thermoplastic web and fiber forming materials such as water insoluble polyethylene, polypropylene, polyester and polyamide. The water soluble polyamide may also be combined with biodegradable or selectively dispersible material to form nonwoven webs and fibers having various combinations of properties. Such water soluble webs and fibers have utility in the manufacture of disposable absorbent articles such as disposable diapers, feminine napkins, incontinent products and cellulosic articles such as tissues and towels, as well as for water soluble heat fusible webs for the textile industry.Type: GrantFiled: May 14, 1998Date of Patent: February 9, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Sharf U. Ahmed, Greg J. Van Lith
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Patent number: 5869555Abstract: A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid.Type: GrantFiled: November 18, 1996Date of Patent: February 9, 1999Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: Eugene R. Simmons, Kevin J. Sweeney, Jeffrey S. Lindquist, Christopher E. Olson, Freddie C. Carter, James R. Farmer
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Patent number: 5869593Abstract: This invention relates to a hot melt moisture cure polyurethane composition which is the reaction product of a) a polyether polyol formed from a compound selected from the group consisting of ethylene oxide, propylene oxide, 1,2-butylene oxide, 1,4-butylene oxide and mixtures thereof; b) a crystalline polyester polyol having a melting point from about 40.degree. C. to about 120.degree. C.; and c) and at least one polyfunctional isocyanate component.Type: GrantFiled: April 27, 1998Date of Patent: February 9, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Marietta B. Helmeke, John M. Zimmel, Franz Maitz
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Patent number: 5869562Abstract: This invention relates to an envelope coated with a hot melt pressure sensitive adhesive composition preferably comprising a) from about 10% to about 40% by weight in the adhesive of at least one block copolymer selected from the group consisting of styrene-isoprene-styrene block copolymers, styrene-butadiene-styrene block copolymers and mixtures thereof wherein the block copolymers comprise from about 15% to about 35% styrene by weight in the copolymer and diblock contents from about 0% to about 90% by weight in the copolymer; and b) from about 60% to about 90% by weight in the adhesive of a modifier selected from the group consisting of solid tackifying resins, liquid tackifying resins, liquid elastomers and mixtures thereof. The invention further relates to an improved oil-free pressure sensitive adhesive that is low in viscosity and provides a destructive bond and resists deformation of high density spun polyolefin materials.Type: GrantFiled: March 28, 1997Date of Patent: February 9, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Jeffrey S. Lindquist, Janelle C. Cameron, Eugene R. Simmons
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Patent number: 5866675Abstract: This invention relates to a nonwoven web comprising a water soluble polyamide and articles constructed therefrom. The water soluble polyamide may be used alone or in combination with conventional thermoplastic web forming materials such as water insoluble polyethylene, polypropylene, polyester and polyamide. The water soluble polyamide may also be combined with biodegradable or selectively dispersible material to form nonwoven webs having various combinations of properties. Such water soluble webs have utility in the manufacture of disposable absorbent articles such as disposable diapers, feminine napkins, incontinent products and cellulosic articles such as tissues and towels, as well as for water soluble heat fusible webs for the textile industry.Type: GrantFiled: August 29, 1997Date of Patent: February 2, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Sharf U. Ahmed, Greg J. Van Lith
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Patent number: 5863977Abstract: This invention relates to hot melt adhesives comprising a high molecular weight polystyrene-ethylene/butylene-polystyrene block copolymer and articles constructed therefrom. This polymer is useful in a variety of hot melt adhesive applications such as food packaging adhesives, rodent traps, skin attachment adhesives, positioning adhesives, diaper tapes, low tack diaper fastening systems, foam in place gaskets, etc.Type: GrantFiled: February 12, 1997Date of Patent: January 26, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Carolyn A. Fischer, Eugene R. Simmons, Mark S. Kroll, Jeffrey S. Lindquist
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Patent number: 5863979Abstract: A method of making paper in which dry chemical additives are incorporated into the pulp mixture by addition of an entire bag containing the additive directly to the mixture, the improvement being that the bag is sealed with an adhesive closure, the adhesive being a hot melt consisting essentially of a water dispersable polyamide prepared from a diacid component comprising in major portion an aliphatic diacid of 6 or fewer carbon atoms and a diamine component consisting of one or more compounds of the formula :H.sub.2 N--C.sub.y H.sub.2y --(OC.sub.2 H.sub.4).sub.x --O--C.sub.y H.sub.2y --NH.sub.2where y is 2 or 3 and x is 1-50 and a wax. Such bags will not leak in shipping and handling, and yet can be added directly to paper batches at ambient temperature in the manner of the unsealable bags employed in the prior art.Type: GrantFiled: October 11, 1996Date of Patent: January 26, 1999Assignee: H. B. Fuller Licensing and Finance, Inc.Inventor: Sharf U. Ahmed
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Patent number: 5861470Abstract: The invention discloses two-component water-based laminating adhesives, comprising aqueous polyurethane dispersions and water dispersible polyisocyanates based on the isocyanurates of hexamethylene diisocyanate, having enhanced machining characteristics. The invention further discloses a method for the preparation of dry-bond laminates having enhanced properties including dry-bond clarity and water resistance.Type: GrantFiled: March 7, 1997Date of Patent: January 19, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Peter A. Voss, Thomas E. Rolando
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Patent number: 5853864Abstract: The articles of this invention have increased resistance to moisture induced delamination at a bond line comprising a substrate, a second layer an dan adhesive. The increased resistance to moisture and increase in bond strength between the adhesive, the substrate and the second layer is produced through a novel adhesive. The adhesive after spraying cools to below the softening point of the components but retains sufficient liquidity to fully wet or to penetrate the second layer causing the layers to be bonded to the film substrate through intimate adhesive bonds or by bonding through a physical entrapment. The physical entrapment of the nonwoven layer substantially prevents moisture-induced debonding or delamination.Type: GrantFiled: June 21, 1995Date of Patent: December 29, 1998Assignee: H. B. Fuller Licensing & Financing Inc.Inventor: William L. Bunnelle
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Patent number: RE36177Abstract: The invention relates to a method of packaging an adhesive composition, especially a thermoplastic or thermosetting hot melt adhesive. The method comprises the steps of providing one substantially uniform separate portion of the adhesive composition; sufficiently solidifying said portion for packaging; substantially completely surrounding said sufficiently solidified portion with a plastics packaging material. The packaging material being meltable together with the adhesive composition and blendable into said molten adhesive composition, the kind and amount of said packaging material being chosen so as not to disadvantageously affect the properties of the adhesive composition when blended into same. Preferably, the packaging material is a net, a wrap, a sack or a bag. Packagings made of plastic film are advantageously voided of air, to prevent problems in melting. The packaged adhesive can be melted as it is.Type: GrantFiled: March 24, 1995Date of Patent: April 6, 1999Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Alain Rouyer, Emmanuelle Pariente, Peter Yeboa-Kodie, Harald Werenicz