Abstract: The invention relates to a method for producing lithium-transition metal mixtures of general formula Lix(M1yM21-y)nOnz, wherein M1 represents nickel, cobalt or manganese, M2 represents chromium, cobalt, iron, manganese, molybdenum or aluminium, and is different from M1, n is 2 if M1 represents manganese and is 1 otherwise, x is comprised between 0.9 and 1.2, y is comprised between 0.5 and 1.0 and z is comprised between 1.9 and 2.1. According to the inventive method, an intimate mixture composed of transition metal compounds containing oxygen and of a lithium compound containing oxygen is calcinated, said mixture being obtained by processing a solid powder transition metal compound with a solution of said lithium compound, and then drying. At least the M1 compound is used in powder form having a specific surface of at least 20 m2/g (BET) and calcination is carried out in a fluidised bed.
Type:
Grant
Filed:
August 13, 1998
Date of Patent:
April 5, 2005
Assignee:
H. C. Starck GmbH & Co
Inventors:
Mathias Benz, Wolfgang Kummer, Evelyn Pross, Josef Schmoll, Wolfgang Schweda, Daniel Duff, Ricarda Leiberich, Christoph Schild, Ulrich Krynitz, Juliane Meese-Marktscheffel, Viktor Stoller
Abstract: The invention relates to a process for the production of metallic and metal-ceramic composite components by powder injection molding of a system comprising a metal composite powder, a binder and optionally a ceramic component, where the metal composite powder used is mixed with a protecting liquid in an inert atmosphere before the mixing with the binder. The invention furthermore relates to molybdenum/copper and tungsten/copper composite powders which have a primary metal particle size of predominantly <2 ?m, an oxygen content of <0.8% by weight and optionally a ceramic component, to the use of these composite powders for the production of composite components by powder injection molding, and to a process for the preparation of composite powders in which oxides of molybdenum or tungsten and of copper are mixed, dry-ground and reduced using hydrogen at a temperature of from 800 to 1050° C., and a ceramic component is optionally admixed with the resultant metal composite powder.
Type:
Grant
Filed:
November 21, 2002
Date of Patent:
February 22, 2005
Assignee:
H. C. Starck GmbH & Co. KG
Inventors:
Helmut Meinhardt, Bernd Meyer, Matthias Knüwer, Dietmar Fister, Wolfgang Wiezoreck
Abstract: The invention relates to a nickel mixed hydroxide with Ni as the main element and with a layer structure, comprising at least one element Ma from the group comprising Fe, Cr, Co, Ti, Zr and Cu which is present in two different oxidation states which differ by one electron in terms of the number of outer electrons; at least one element Mb from the group comprising B, Al, Ga, In and RE (rare earth metals) present in the trivalent oxidation state; optionally at least one element Mc from the group comprising Mg, Ca, Sr, Ba and Zn present in the divalent oxidation state; apart from the hydroxide, at least one additional anion from the group comprising halides, carbonate, sulfate, oxalate, acetate, borate and phosphate in a quantity sufficient to preserve the electroneutrality of the mixed hydroxide; and water of hydration in a quantity which stabilizes the relevant structure of the mixed hydroxide.
Type:
Grant
Filed:
December 14, 1999
Date of Patent:
February 1, 2005
Assignee:
H. C. Starck GmbH
Inventors:
Viktor Stoller, Armin Olbrich, Juliane Meese-Marktscheffel, Margret Wohlfahrt-Mehrens, Peter Axmann, Herbert Dittrich, Sandra Ströbele
Abstract: An electrolyte capacitor containing a niobium anode, a niobium oxide barrier layer, a semiconducting cathode and an electrolyte is described, where the niobium oxide barrier comprises a least one metal from the group consisting of Al, Si, Ti, Zr, Mo, W, Y and Ta.
Type:
Grant
Filed:
May 7, 2002
Date of Patent:
November 23, 2004
Assignee:
H. C. Starck GmbH
Inventors:
Karlheinz Reichert, Oliver Thomas, Christoph Schnitter
Abstract: A nickel hydroxide for rechargeable batteries which is provided with a cobalt hydroxide coating which is stable to oxidation is described. The stability to oxidation is achieved by covering the surface of the cobalt hydroxide layer with anions of weak inorganic oxygen acids.
Type:
Grant
Filed:
December 18, 2001
Date of Patent:
October 5, 2004
Assignee:
H. C. Starck GmbH
Inventors:
Viktor Stoller, Michael Erb, Armin Olbrich, Juliane Meese-Marktscheffel
Abstract: An anode is described that has a niobium-based barrier layer, which includes a niobium metal core, a conducting niobium suboxide layer and a dielectric barrier layer of niobium pentoxide.
Type:
Grant
Filed:
August 23, 2001
Date of Patent:
July 13, 2004
Assignee:
H.C. Starck GmbH & Co. KG
Inventors:
Christoph Schnitter, Karlheinz Reichert
Abstract: A process is described for the production of spherical nickel hydroxide by anodic dissolution of a nickel electrode and precipitation of nickel hydroxide in a completely intermixed electrolysis cell, wherein an electrolysis brine is used which has a content of 20 to 50 g/l of chloride ions and 1 to 7 g/l of ammonia with a pH value of 9.5 to 11.5 and a temperature of 45 to 60° C.
Type:
Grant
Filed:
November 5, 2001
Date of Patent:
June 22, 2004
Assignee:
H. C. Starck GmbH
Inventors:
Armin Olbrich, Viktor Stoller, Juliane Meese-Marktscheffel, Frank Schrumpf, Josef Schmoll, Gerhard Gille
Abstract: A process is described for the preparation of tungsten and/or molybdenum metal powder or carbide by reducing and optionally carburizing treatment of tungsten and/or molybdenum oxide powder in the presence of alkali metal compounds, wherein at least two alkali metal compounds are used in a ratio so that mixed alkali tungstate or molybdate potentially formed in an intermediate step ((Li, Na, K)2 WOZ, (Li, Na, K)2MoOZ) has a melting point of less than 550° C., wherein z is from 3 to 4.
Type:
Grant
Filed:
August 30, 2001
Date of Patent:
June 15, 2004
Assignee:
H.C. Starck GmbH
Inventors:
Jörg Bredthauer, Benno Gries, Bernhard Szesny
Abstract: The invention relates to a method of extracting anions based on metals of groups IV B to VIII of the periodic table from aqueous solutions thereof, wherein compounds of general formula
are used as extractants, in which a maximum of two of the R1, R2, R3 and R4 substituents represent hydrogen atoms and the remaining substituents represent identical or different alkyl or aminoakyl groups, which are optionally branched and which contain on average at least 5 C atoms.
Abstract: The present invention relates to basic cobalt(II) carbonate, agglomerated from fine primary particles and of general composition Co[(OH)2]a[CO3]1−a, where 0.1≦a≦0.9, and to spheroidal cobalt(II) hydroxide, to a process for producing them and to their use.
Type:
Grant
Filed:
November 24, 1997
Date of Patent:
March 2, 2004
Assignee:
H.C. Starck GmbH & Co KG
Inventors:
Astrid Görge, Juliane Meese-Marktscheffel, Dirk Naumann, Armin Olbrich, Frank Schrumpf
Abstract: The present invention relates to cutting tool insert consisting of a tungsten carbide based hard metal substrate and a coating. The hard metal consists of about 4-15 wt-% binder phase with face centered cubic structure and a composition of 35-65 wt-% Fe and 35-65 wt-% Ni in addition to dissolved elements. As a result, inserts have been produced with at least as good performance in machining as conventional state-of-the-art inserts with Co-based binder phase. The insert can be applied in milling and turning of low and medium alloyed steels as well as stainless steels.
Type:
Grant
Filed:
November 20, 2001
Date of Patent:
December 23, 2003
Assignees:
Seco Tools AB, H.C. Starck GmbH & Co. KG
Abstract: The invention relates to a method for producing a homogeneous mixture of hard material powders and binder metal powders without using grinding bodies, liquid grinding auxiliary agents and suspending media. According to the invention, the mixture components are mixed at close range while generating a high shearing collision velocity of the powder particles and are remotely mixed by rotating the mixing bed without resulting in a particle size reduction of the hard material powders.
Abstract: A process is described for the production of metal powder and alloy powders containing at least one of the metals iron, copper, tin, cobalt or nickel, by mixing aqueous metal salt solutions with an aqueous carboxylic acid solution, separating the precipitation product from the mother liquor and reducing the precipitation product to the metal.
Type:
Grant
Filed:
November 15, 2000
Date of Patent:
April 29, 2003
Assignee:
H. C. Starck GmbH
Inventors:
Bernd Mende, Gerhard Gille, Benno Gries, Peter Aulich, Jörg Münchow
Abstract: The invention relates to a process for preparing niobium(V) alkoxides and tantalum(V) alkoxides, in particular niobium(V) ethoxide and tantalum(V) ethoxide, by reacting NbCl5 or TaCl5 with an appropriate alcohol in the presence of ammonia, wherein NbCl5 or TaCl5 is dissolved at a temperature of from about 0° C. to −50° C. in the alcohol containing from about 5 to about 7 mol of ammonia per mol of NbCl5 or TaCl5 to be reacted.
Abstract: A paste is described for the production of sintered refractory metal layers, particularly for electrolytic capacitor anodes, consisting of 40 to 92% by weight of a refractory metal powder as a discrete phase, and of a continuous phase which substantially consists of organic compounds which are synthesised from carbon, oxygen and hydrogen only, wherein the ratio of the number of oxygen atoms to carbon atoms is at least 0.5, and optionally consisting of a solvent which evaporates below 150° C.
Abstract: The invention relates to a method for producing lithium transition metalates of the general formula (I): Lix(M1yM21−y)nOnz, where M1 represents lithium, cobalt or manganese; M2 represents cobalt, iron, manganese or aluminium and is not equal to M1; n is equal to 2 if M1=M, and 1 in all other cases; x is a number between 0.9 and 1.2; y is a number between 0.5 and 1.0; and z is a number between 1.9 and 2.1. According to the method, an intimate solid mixture is produced of oxygen-containing compounds of the transition metals and oxygen-containing lithium compounds and this mixture calcinated in a reactor, whereby calcination takes place at least partly at an absolute pressure of less than 0.5 bar.
Type:
Grant
Filed:
August 19, 1999
Date of Patent:
September 10, 2002
Assignee:
H.C. Starck GmbH & Co. KG
Inventors:
Ulrich Krynitz, Wolfgang Kummer, Mathias Benz, Juliane Meese-Marktscheffel, Evelyn Pross, Viktor Stoller
Abstract: Ultrafine cobalt metal powder consisting of fine crystallites, wherein the crystallites, wherein the crystallitex exhibit a rice-grain shaped to spherical habit and more than 90% of the crystallites have a diameter in the range of from 0.5 to 2 &mgr;m, a process for the production of the cobalt metal powder via an intermediate stage of cobalt carbonate production, and processes and products re certain uses of the cobalt metal powder and the cobalt carbonate and an intermediate oxide so produced.
Abstract: The present invention relates to cobalt(II) oxide containing metallic cobalt, to a process for the production thereof and to the use thereof.
Type:
Grant
Filed:
December 17, 1999
Date of Patent:
August 21, 2001
Assignee:
H. C. Starck GmbH & Co. KG
Inventors:
Astrid Görge, Juliane Meese-Marktscheffel, Dirk Naumann, Armin Olbrich, Frank Schrumpf
Abstract: The present invention discloses a tantalum powder for capacitors and a method for making said tantalum powder wherein agglomerated tantalum powder is produced by means of thermal agglomeration of starting tantalum powders in the presence of hydrogen.
Abstract: The invention relates a tantalum powder free of alkali and fluorine, which for a relatively small primary particle size has comparatively large secondary particles and is suitable for producing capacitors with a specific charge of between 100,000 and 180,000 &mgr;FV/g at specific residual currents of less than 2nA/&mgr;FV.