Abstract: A process for the production of a valve metal oxide powder, in particular an Nb2O5 or Ta2O5 powder by continuous reaction of a fluoride-containing valve metal compound with a base in the presence of water and calcination of the resultant product, wherein the reaction is performed in just one reaction vessel and at a temperature of at least 45° C. Valve metal oxide powders obtainable in said manner which exhibit a spherical morphology, a D50 value of 10 to 80 ?m and an elevated BET surface area.
Type:
Grant
Filed:
August 18, 2009
Date of Patent:
January 24, 2012
Assignee:
H.C. Starck GmbH
Inventors:
Karsten Beck, Hady Seyeda, Klaus Lerch, Bianca Agnes Balan
Abstract: The invention relates to a device and a method for the production of compounds by precipitation of solids from solutions, the physical and chemical properties of the solid particles formed on precipitation being flexible and can be independently fixable. Custom products can thus be produced with very high space-time yields and a particulate nickel/cobalt mixed hydroxide of formula NixCo1-x(OH)2, with a BET surface area of 20 m2/g and a tap density of greater than 2.4 g/cm3.
Type:
Application
Filed:
March 20, 2007
Publication date:
December 8, 2011
Applicant:
H.C. STARCK GMBH
Inventors:
Armin Olbrich, Juliane Meese-Marktscheffel, Matthias Jahn, Rüdiger Zertani, Gerd Maikowske, Sven Albrecht, Stefan Malcus, Josef Schmoll, Gabriele Christine Schmoll, Christian Peter Schmoll, Wolfgang Josef Schmoll, Volker Schmoll, Georg Wilhelm Schmoll, Michael Kruft
Abstract: The invention relates to a process for the production of electrolyte capacitors having a low equivalent series resistance and low residual current, electrolyte capacitors produced by this process and the use of such electrolyte capacitors.
Type:
Grant
Filed:
September 13, 2006
Date of Patent:
November 15, 2011
Assignee:
H. C. Starck GmbH
Inventors:
Udo Merker, Wilfried Lövenich, Klaus Wussow, Ralph Tillmann
Abstract: Process for the production of a powdered spherical tungstic acid by acidification of an aqueous alkaline tungstate solution with mineral acid at elevated temperature, preferably in a continuous stirred tank or a cascade of at least 2 continuous stirred tanks, and tungstic acid obtainable in this way, which is characterized by a high bulk density and spherical morphology.
Type:
Grant
Filed:
April 28, 2005
Date of Patent:
November 8, 2011
Assignee:
H. C. Starck GmbH
Inventors:
Sven Albrecht, Armin Olbrich, Michael Reiss, Frank Schrumpf, Juliane Meese-Marktscheffel, Uwe Kutzler
Abstract: The invention relates to compositions which include: (a) a polythiophene containing repeating units represented by the following general formula (I), wherein X represents, for example, —CH2—CH(CH2—O—(CH2)4SO3?H+)—; and (b) further polymers, that are different than polythiophene (a), and which contain SO3? M+ or COO?M+ groups. Also disclosed are electroluminescing (EL) arrangements that contain hole-injecting layers which include such compositions.
Type:
Application
Filed:
June 30, 2011
Publication date:
October 20, 2011
Applicant:
H.C. Starck GmbH & Co. KG
Inventors:
Andreas ELSCHNER, Knud REUTER, Peter Wilfried LOVENICH
Abstract: A precursor for the production of a sintered metallic component includes a core comprising one particle of a first metallic powder having a particle size d90 of at least 50 ?m. A shell layer is disposed on the core. The shell layer comprises a binder and a second powder having a particle size d90 of less than 25 ?m. The precursor is powdered.
Abstract: Porous anode bodies suitable for use in solid state capacitors, the porous anode bodies prepared by processes which include providing a niobium suboxide powder comprising niobium suboxide particles having a bulk nitrogen content of 500 to 20,000 ppm, and agglomerating and coalescing the powder; and capacitors incorporating such anode bodies.
Type:
Grant
Filed:
June 1, 2006
Date of Patent:
October 4, 2011
Assignee:
H. C. Starck GmbH
Inventors:
Christoph Schnitter, Holger Brumm, Christine Rawohl, Colin McCracken
Abstract: An amorphous or a partially crystalline magnesium diboride comprising a crystalline material content of ?25% by weight as determined by an X-ray powder diffraction.
Abstract: The invention is related to a boride of a metal of transition group four of the periodic table of the elements, wherein at least 40 wt. % of the particles have a grain size of more than 106 ?m, determined by sieve analysis according to ASTM B 214, and these particles consist of grown, monocrystalline grains. The invention also relates to a cermet, wettable powder and a surface coating which contain the boride. The invention further relates to a process to prepare the boride. The invention additionally relates to a process to prepare a cermet or a wettable powder.
Type:
Application
Filed:
February 18, 2011
Publication date:
September 1, 2011
Applicant:
H. C. Starck GmbH & Co. KG
Inventors:
Frank Schrumpf, Wolfgang Kiliani, Stefan Frässle, Thomas Schmidt
Abstract: The invention relates to a process for the purification of thiophenes by means of precipitation. The purified thiophenes are liquid at room temperature, have a purity of at least 99.50 wt. %, and are represented by the following general formula (I), wherein R1 and R2 independently of each other are, for example, a linear or branched C1-C20-alkyl group, or together form a fused C1-C20-dioxyalylene ring. The process involves: (I) precipitating the thiophene by cooling a solution of the thiophene and at least one solvent; or (II) precipitating the thiophene by adding the thiophene to a cooled solution of solvent and optionally the thiophene. The solutions are cooled to a temperature below the melting point of the thiophene.
Abstract: The invention is directed to a pulverulent compound of the formula NiaM1bM2bOx(OH)y where M1 is at least one element selected from the group consisting of Fe, Co, Zn, Cu and mixtures thereof, M2 is at least one element selected from the group consisting of Mn, Al, Cr, B, Mg, Ca, Sr, Ba, Si and mixtures thereof, 0.3?a?0.83, 0.1?b?0.5, 0.01?c?0.5, 0.01?x?0.99 and 1.01?y?1.99, wherein the ratio of tapped density measured in accordance with ASTM B 527 to the D50 of the particle size distribution measured in accordance with ASTM B 822 is at least 0.2 g/cm3·?m. The invention is also directed to a method for the production of the pulverulent compound and the use as a precursor material for producing lithium compounds for use in lithium secondary batteries.
Abstract: Elemental boron with a boron content of at least 96.8% by weight, an oxygen content of at most 1.6% by weight, a nitrogen content of at most 0.2% by weight, a crystallinity of 30% by weight or less, and a particle size distribution with a d100 value of 9 ?m or less.
Abstract: At least one of a valve metal sintered capacitor anode body and a suboxide valve metal sintered capacitor anode body with a particle density of >88% of a theoretical density.
Abstract: The present invention provides a method for the production of an aqueous dispersion containing an electroconductive polymer component which enables electroconductive thin films which are outstanding in their transparency and electroconductivity to be formed, together with the aqueous dispersion obtained by said method. This method includes a stage in which a 3,4-dialkoxythiophene is polymerized in an aqueous solvent using an oxidizing agent in the presence of a polyanion and, in this stage, said oxidizing agent is added by the dropwise addition of a solution or dispersion containing said oxidizing agent to the reaction solution or, alternatively, in the polymerization stage, the alkali metal ion concentration in the reaction liquid is maintained at no more than 400 ppm.
Abstract: Process for preparing specific oxidants which in mixtures with precursors for preparing conductive polymers display a long processing time during the polymerization; oxidants obtainable by this process; mixtures comprising such specific (retarding) oxidants and the use of said oxidants for preparing solid electrolyte capacitors and conductive layers.
Type:
Grant
Filed:
March 20, 2004
Date of Patent:
July 5, 2011
Assignee:
H. C. Starck GmbH
Inventors:
Udo Merker, Stephan Kirchmeyer, Klaus Wussow
Abstract: A formulation of at least one of a partially and a fully stabilized zirconium oxide powder includes at least one organic auxiliary substance wherein a pressing pressure so as to obtain a green density of at least 50% of a theoretical density is 200 MPa or less and a cohesiveness is 0.7 or more.
Abstract: Process for producing a capacitor anode based on at least one of a valve metal and a compound having properties comparable to a valve metal includes providing a pressing or cutting tool which is at least one of made of and coated with a pressing or cutting tool material comprising at least one of a metal carbide, an oxide, a boride, a nitride, a silicide, a carbonitride or alloys thereof, a ceramic material, a hardened steel, an alloy steel, and a capacitor anode material. Particles of the at least one of a valve metal and a compound having properties comparable to a valve metal are pressed or cut with the pressing or cutting tool so as to produce a porous electrode body and form the capacitor anode.
Abstract: The production of electrically conductive polythiophenes by reaction of 2,5-dihalogen-3,4-ethylene dioxythiophenes with 3,4-ethylene dioxythiophenes in a solvent or liquid phase is provided. These polythiophenes can be used as a plastic or lacquer additive to provide antistatic properties.
Type:
Grant
Filed:
June 29, 2006
Date of Patent:
May 31, 2011
Assignee:
H. C. Starck GmbH
Inventors:
Knud Reuter, Stephan Kirchmeyer, Friedrich Jonas