Patents Assigned to Haldor Topsoe, S.A.
  • Patent number: 11088372
    Abstract: Improved contact between interconnect and oxygen electrode material in solid oxide cell (SOC) stacks is achieved through a contact point between the oxygen electrode or an oxygen-side contact layer of the SOC and a coated ferritic stainless steel interconnect in the SOC stack, where the coating on the metallic interconnect comprises Cu.
    Type: Grant
    Filed: December 1, 2017
    Date of Patent: August 10, 2021
    Assignee: Haldor Topsoe A/S
    Inventors: Tobias Holt Nørby, Bengt Peter Gustav Blennow, Rainer Küngas, Jeppe Rass-Hansen, Thomas Heiredal-Clausen
  • Publication number: 20210238035
    Abstract: A hydrogen plant for producing hydrogen, including: a reforming reactor system including a first catalyst bed including an electrically conductive material and a catalytically active material, a heat insulation layer between the first catalyst bed and the pressure shell, and at least two conductors electrically connected to the electrically conductive material and to an electrical power supply placed outside the pressure shell, wherein the electrical power supply is dimensioned to heat at least part of the first catalyst bed to a temperature of at least 500° C. by passing an electrical current through the electrically conductive material, where the pressure shell has a design pressure of between 5 and 200 bar; a water gas shift unit downstream the reforming reactor system; and a gas separation unit downstream the water gas shift unit. A process for producing hydrogen from a feed gas including hydrocarbons.
    Type: Application
    Filed: May 15, 2019
    Publication date: August 5, 2021
    Applicant: HALDOR TOPSØE A/S
    Inventors: Peter Mølgaard MORTENSEN, Kim AASBERG-PETERSEN, Robert KLEIN
  • Publication number: 20210238488
    Abstract: A process for hydrodesulfurizing an olefinic naphtha feedstock while retaining a substantial amount of the olefins, which feedstock has a T95 boiling point below 250° C. and contains at least 50 ppmw of organically bound sulfur and from 5% to 60% olefins, the process including hydrodesulfurizing the feedstock in a sulfur removal stage in the presence of a gas including hydrogen and a hydrodesulfurization catalyst, at hydrodesulfurization reaction conditions, to convert at least 60% of the organically bound sulfur to hydrogen sulfide and to produce a desulfurized product stream wherein the gas to oil ratio and the pressure are configured for the selectivity slope, (% HDS?% OSAT)/(% OSAT*(100?% HDS)), to be above 0.55, and to provide a lower octane loss at all severities above 60% HDS, compared to compared to all prior reported processes with similar conversion of organic sulfur with a lower gas to oil ratio, as measured by the selectivity slope.
    Type: Application
    Filed: May 28, 2019
    Publication date: August 5, 2021
    Applicant: HALDOR TOPSØE A/S
    Inventor: Christian Ejersbo STREBEL
  • Patent number: 11078131
    Abstract: A fuel cell reactor, preferably a solid oxide fuel cell (SOFC) reactor, for performing direct conversion of a hydrocarbon-containing gas to a higher hydrocarbons product is confined by walls, where reactants are flown in the anode compartments and air is introduced to the cathode compartments, and where oxygen is transferred from one side of the walls to the other side to promote or inhibit a chemical reaction. The process for direct conversion of a hydrocarbon-containing gas to a higher hydrocarbons product takes place in the anode compartment of the reactor, in which produced hydrogen, limiting the conversion to the equilibrium, is reacted in situ with oxygen ions transferred from the cathode compartment to produce steam, thereby removing the equilibrium-limiting hydrogen from the reaction.
    Type: Grant
    Filed: August 21, 2019
    Date of Patent: August 3, 2021
    Assignee: Haldor Topsoe A/S
    Inventor: Hassan Modarresi
  • Patent number: 11077431
    Abstract: A bifunctional catalyst for example for conversion of oxygenates, said bifunctional catalyst comprising zeolite, alumina binder, Zn and P, wherein Zn is present at least partly as ZnAl2O4.
    Type: Grant
    Filed: November 30, 2016
    Date of Patent: August 3, 2021
    Assignee: Haldor Topsoe A/S
    Inventors: Uffe Vie Mentzel, Finn Joensen
  • Publication number: 20210221758
    Abstract: The deterioration of methanol synthesis catalysts that is caused by iron poisoning of the catalyst is counteracted by using a catalyst containing a maximum of 100 ppmw Fe in the synthesis process. The method is especially useful in a methanol synthesis plant comprising a make-up gas compressor and a synthesis reactor in a methanol loop with a once-through pre-converter installed between the make-up gas compressor and the methanol loop.
    Type: Application
    Filed: June 11, 2019
    Publication date: July 22, 2021
    Applicant: HALDOR TOPSØE A/S
    Inventors: Søren Grønborg ESKESEN, Per Juul DAHL, Emil Andreas TJÄRNEHOV, Max THORHAUGE
  • Patent number: 11065591
    Abstract: A method and reactor for performing exothermic reactions with parallel operated catalyst modules arranged in stacked order within a pressure shell and adapted to axial flow of process gas through one or more catalyst layers and at least one catalyst layer cooled by an intrabed heat exchanger.
    Type: Grant
    Filed: December 19, 2018
    Date of Patent: July 20, 2021
    Assignee: Haldor Topsoe A/S
    Inventors: Christian Henrik Speth, Tommy Lykke Wind, Uffe Bach Thomsen, Anders Helbo Hansen
  • Publication number: 20210214849
    Abstract: In a method for generating various synthesis gases by electrolysis, comprising feeding steam and compressed air to the cathode and anode, respectively, of the electrolysis unit or of the first of a series of electrolysis units into the first of a series of electrolysis units, the electrolysis units are operated under an elevated gas pressure, and the oxygen-rich gas leaving the anode is subsequently expanded down to approximately ambient pressure using a gas expander. The electrolysis units are preferably solid oxide electrolysis cell (SOEC) stacks.
    Type: Application
    Filed: July 9, 2019
    Publication date: July 15, 2021
    Applicant: Haldor Topsøe A/S
    Inventor: John Bøgild HANSEN
  • Patent number: 11059719
    Abstract: In a process for producing hydrogen or syngas by methanol cracking, whereby methanol is catalytically decomposed into hydrogen and carbon monoxide in an endothermal reaction, said reaction takes place in a reactor with direct inductive heating in the reaction zone. The heating is obtained by passing an alternating current through a metallic coil located inside the reactor or by using induction heated catalyzed hardware in the shape of a ferromagnetic structure, which is coated with an oxide impregnated with the catalytically active phase.
    Type: Grant
    Filed: April 24, 2017
    Date of Patent: July 13, 2021
    Assignee: HALDOR TOPSØE A/S
    Inventors: Peter Mølgaard Mortensen, Martin Østberg, Poul Erik Højlund Nielsen
  • Patent number: 11060036
    Abstract: Process for the conversion of oxygenates to C5+ hydrocarbons boiling in the gasoline boiling range, comprising the steps of continuously a) providing one or more feed streams of one or more oxygenate compounds; b) heating the one or more feed streams to an inlet temperature of one or more downstream conversion reactors; c) introducing the one or more heated feed stream into inlet of the one or more conversion reactors; d) converting in the one or more conversion reactors the one or more heated feed stream in presence of catalyst to a converted oxygenate product comprising C5+ hydrocarbons; e) withdrawing from the one or more conversion reactors the converted oxygenate product; f) determining at outlet of the one or more conversion reactors amount of the one or more unconverted oxygenate compounds in the withdrawn converted oxygenate product; g) separating the converted oxygenate product into a C4? hydrocarbon fraction, a fraction with the C5+ hydrocarbons boiling in the gasoline boiling range and a fraction c
    Type: Grant
    Filed: May 2, 2019
    Date of Patent: July 13, 2021
    Assignee: Haldor Topsoe A/S
    Inventor: Martin Dan Palis Sørensen
  • Publication number: 20210207804
    Abstract: A method and an apparatus for protection of a combustion unit of a chemical process against over firing, the burner(s) of the combustion unit are limited by a fuel and duty limiter which limits the duty based on process feeds, combustion gas and fuel flows.
    Type: Application
    Filed: February 20, 2017
    Publication date: July 8, 2021
    Applicant: HALDOR TOPSØE A/S
    Inventors: Emil Andreas Tjärnehov, Anne Krog Jensen, Christian Henrik Speth, Peter Bruun Jensen
  • Publication number: 20210206634
    Abstract: The present invention relates to a revamp method for increasing the front-end capacity of a plant comprising a reforming section, wherein a feed is reformed in at least one reforming step to a reformed stream comprising CH4, CO, CO2, H2 and H2O a shift section wherein the reformed stream is shifted in a shift reaction in at least a high temperature shift step, said method comprising the steps of In the High temperature shift step exchanging an original Fe-based catalyst with a non-Fe-based catalyst Increasing the feed flow to the reforming section, and The HTS step is carried out at a reduced steam/dry-gas ratio (S/DG) compared to an original S/DG in the original HTS step with the original Fe-based catalyst.
    Type: Application
    Filed: February 28, 2017
    Publication date: July 8, 2021
    Applicant: HALDOR TOPSØE A/S
    Inventors: Annette E. Krøll Jensen, Christian Henrik Speth, Thomas Rostrup-Nielsen, Niels Christian Schjødt
  • Patent number: 11053130
    Abstract: A process for the combined preparation of methanol and ammonia based on primary steam reforming a hydrocarbon feed stock and adiabatic secondary reforming with oxygen enriched air from electrolysis of water.
    Type: Grant
    Filed: July 20, 2018
    Date of Patent: July 6, 2021
    Assignee: Haldor Topsoe A/S
    Inventor: Pat A. Han
  • Publication number: 20210198104
    Abstract: Method for the preparation of ammonia synthesis gas by a combination of ATR or secondary reforming process using oxygen from an air separation unit and electrolysis of water for the production of ammonia synthesis gas.
    Type: Application
    Filed: July 11, 2018
    Publication date: July 1, 2021
    Applicant: Haldor Topsøe A/S
    Inventors: Pat A. Han, Annette E. Krøll Jensen
  • Patent number: 11045763
    Abstract: The present application relates to a process for treating the off gas from a carbon black process, said process comprising the steps of: providing an off gas from a carbon black process, reacting said off gas in a first reaction step forming water and S, and condensing the S at a temperature Tcon where S is in a liquid phase and the water is in gas form thereby achieving a gaseous stream comprising water and a liquid stream comprising S, and wherein the first reaction step is carried out over a monolith catalyst.
    Type: Grant
    Filed: January 25, 2018
    Date of Patent: June 29, 2021
    Assignee: Haldor Topsoe A/S
    Inventors: Niklas Bengt Jakobsson, Peter Bo Olsen, Janus Emil Münster-Swendsen
  • Publication number: 20210188747
    Abstract: A process for the production of methanol from synthesis gas via an equilibrium reaction is conducted in a methanol preconverter within a certain operational window, said operational window being defined by the area below an approximately linear curve of the partial pressure of carbon monoxide vs. the boiling water temperature for water temperatures between 210 and 270° C. Methanol of different product grades may be obtained by operating in specific areas of the operational window.
    Type: Application
    Filed: June 11, 2019
    Publication date: June 24, 2021
    Applicant: HALDOR TOPSØE A/S
    Inventors: Søren Grønborg ESKESEN, Per Juul DAHL, Emil Andreas TJÄRNEHOV, Max THORHAUGE
  • Patent number: 11040321
    Abstract: In an adiabatic axial flow converter, in which process gas passes from an outer annulus via a catalyst bed, wherein the process gas is converted to a product, to an inner centre tube, the catalyst bed comprises at least one module comprising one or more catalyst layers. Feed means are arranged to provide a flow of process gas from the outer annulus to an inlet part of one or more modules, and collector means are arranged to provide a flow of product stream of converted process gas which passes axially through the catalyst bed of one or more of the modules to the centre tube.
    Type: Grant
    Filed: December 19, 2018
    Date of Patent: June 22, 2021
    Assignee: Haldor Topsoe A/S
    Inventors: Christian Henrik Speth, Per Juul Dahl
  • Patent number: 11040934
    Abstract: Preparation of 2,5,6-trihydroxy-3-hexenoic acid and 2,5-dihydroxy-3-pentenoic acid and esters thereof from C6 and C5 sugars in the presence of a Lewis Acid material, wherein the yield of the 2,5,6-trihydroxy-3-hexenoic acid or 2,5-dihydroxy-3-pentenoic acid or esters thereof exceeds 15%. The process including the steps of contacting a saccharide composition including one or more C6 and/or C5 saccharide units with a Lewis Acid material; and recovering 2,5,6-trihydroxy-3-hexenoic acid and/or 2,5-dihydroxy-3-pentenoic acid or the esters thereof.
    Type: Grant
    Filed: April 25, 2019
    Date of Patent: June 22, 2021
    Assignee: HALDOR TOPSØE A/S
    Inventors: Esben Taarning, Irantzu Sadaba Zubiri, Sebastian Meier
  • Publication number: 20210179436
    Abstract: The invention concerns a process for producing carbon mon-oxide (CO) from a feed stream comprising carbon dioxide (CO2) and natural gas and/or naphtha the process comprising a syngas generation step, a CO2 removal step and a CO purification step and the process further comprises an SOEC unit which produces CO from a CO2 stream, the process is especially suited for increasing the capacity of existing known CO production plants.
    Type: Application
    Filed: February 20, 2017
    Publication date: June 17, 2021
    Applicant: HALDOR TOPSØE A/S
    Inventor: Henrik C.O. Wene
  • Patent number: 11034713
    Abstract: A process for the preparation of C4 oxygenate compounds such as threose, erythrose or erythrulose starting from a composition comprising C1-3 oxygenate compounds such as formaldehyde, glycolaldehyde, glyoxal, pyruvaldehyde or acetol, wherein the process is carried out in the presence of a crystalline microporous material having a ring pore structure selected from an eight-membered ring pore structure or a ten-membered ring pore structure.
    Type: Grant
    Filed: June 18, 2015
    Date of Patent: June 15, 2021
    Assignee: Haldor Topsoe A/S
    Inventors: Saravanamurugan Shunmugavel, Irantzu Sadaba Zubiri, Esben Taarning, Martin Spangsberg Holm