Abstract: A catalyst for the dehydrogenation of alkanes to alkenes comprises a catalytically active material supported on a carrier, wherein the catalytically active material is a metallic sulfide (MeS) comprising Fe, Co, Ni, Cu, Mo or W or any combination of two or more metals selected from Pb, Sn, Zn, Fe, Co, Ni, Cu, Mo and W. The catalyst is regenerated in several steps. The dehydrogenation is carried out at a temperature between 450 and 650° C. and a pressure from 0.9 bar below ambient pressure to 5 bar above ambient pressure.
Type:
Grant
Filed:
March 7, 2017
Date of Patent:
July 28, 2020
Assignee:
HALDOR TOPSØE A/S
Inventors:
Poul Erik Højlund Nielsen, Rasmus Munksgård Nielsen, Lived J. Lemus-Yegres
Abstract: A combustible gas from carbon black production is utilized in a gas engine by adding an oxygen-containing gas to the combustible gas, passing said mixed gas over a selective catalyst, which is active for oxidizing H2S to SO2 but substantially inactive for oxidation of CO, H2 and other hydrocarbons with less than 4 C-atoms, passing the converted gas through an SO2 removal step, and passing the cleaned gas to a gas engine or to an energy recovery boiler. This way, the tail gas from carbon black production, which is normally combusted in a CO boiler or incinerated, can be utilized to good effect.
Type:
Grant
Filed:
September 9, 2016
Date of Patent:
July 28, 2020
Assignee:
HALDOR TOPSØE A/S
Inventors:
Niklas Bengt Jakobsson, Kurt Agerbæk Christensen
Abstract: The present invention relates to a method and a system for catalytic oxidation of a lean H2S stream. More specifically, the invention concerns a novel way of removing sulfur dioxide (SO2) formed by catalytic oxidation of hydrogen sulfide (H2S) with the purpose of removing H2S from a gas. This catalytic oxidation of H2S yields sulfur dioxide (SO2) through the use of known catalysts, so-called SMC catalysts.
Type:
Grant
Filed:
January 11, 2018
Date of Patent:
July 28, 2020
Assignee:
HALDOR TOPSØE A/S
Inventors:
Hans Qiongxiao Wu, Tommy Bian Xiang, Niklas Bengt Jakobsson, Rasmus Trane-Restrup, Souheil Saadi
Abstract: A platinum-gallium based catalyst for alkane dehydrogenation is provided with an oxidation promotor in the form of cerium that is added to the catalyst composition to improve the regeneration thereof. The cerium is preferably added to the catalyst composition in an amount from 0.001 to 0.5 wt %.
Type:
Application
Filed:
June 28, 2018
Publication date:
July 23, 2020
Applicant:
HALDOR TOPSØE A/S
Inventors:
Rasmus Munksgård NIELSEN, Roy VAN DEN BERG, Lived J. LEMUS-YEGRES, Joachim Harteg JACOBSEN, Poul Erik HØJLUND NIELSEN
Abstract: A process for producing UREA, said process comprising the steps of:—purification of a hydrocarbon feed gas removing Sulphur and/or chloride components if present, —reforming the hydrocarbon feed gas in a reforming step where the steam/carbon ratio is less than 2.6 thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O, —optionally adding H2O to the synthesis gas from the reforming step maintaining an overall steam/carbon less than 2.
Type:
Application
Filed:
March 7, 2018
Publication date:
July 23, 2020
Applicant:
Haldor Topsøe A/S
Inventors:
Christian Henrik Speth, Per Juul Dahl, Annette E. Kroll Jensen, Niels Christian Schjødt, Marcus Symreng
Abstract: Method for the preparation of a monolithic catalyst for the reduction of nitrogen oxides VOC and carbon monoxide in an off-gas, the catalyst comprises at least one platinum group metal, vanadium, titania and optionally tungsten oxide.
Type:
Grant
Filed:
June 19, 2017
Date of Patent:
July 21, 2020
Assignee:
Haldor Topsoe A/S
Inventors:
Kim Hougaard Pedersen, Viggo Lucassen Hansen, Francesco Castellino
Abstract: Process and plant for recovering LPG in a refinery process combining the use of sponge absorber, deethanizer and debutanizer. The process and plant enable high LPG recovery and removal of hydrogen sulphide in the LPG product to low levels.
Abstract: The invention relates to a catalyst material comprising a support, a first metal and a second metal on said support. The first and second metals are in the form of a chemical compound. The first metal is Fe, Co or Ni, and the second metal is selected from the group consisting of Sn, Zn and In. The invention also relates to a process for the preparation of hydrogen cyanide (HCN) from methane (CH4) and ammonia (NH3), wherein the methane and ammonia are contacted with a catalyst according to the invention.
Type:
Grant
Filed:
November 30, 2018
Date of Patent:
July 14, 2020
Assignee:
Haldor Topsoe A/S
Inventors:
Burcin Temel McKenna, Poul Erik Højlund Nielsen
Abstract: A process for co-production of methanol and ammonia in parallel based on autothermal reforming with oxygen enriched air from electrolysis of water and separation of air and preparation of ammonia with hydrogen from the electrolysis of water and nitrogen from the separation of air.
Abstract: A fuel cell stack comprises a thin process-gas-connection-endplate with a temperature expansion coefficient which is substantially the same as the temperature expansion coefficient of the plurality of fuel cells and interconnects forming the fuel cell stack, the length and width of the thin process-gas-connection-endplate is matching the length and width of the fuel cells and interconnects and the process-gas-connection-endplate is sealed to the stack of cells and interconnects so the process-gas-connection-endplate, cells and interconnects form one integrated unit, wherein process gas distribution tubes are fixed connected, e.g. welded or brazed to the process-gas-connection-endplate.
Abstract: A separator system for treating a gas from a biomass gasification system, including: first and second cyclones, where the first cyclone includes an inlet for receiving a gas from a biomass gasification unit, the first cyclone being arranged for removing particulate matter from the gas from the biomass gasification unit in order to provide a first cleaner gas, piping arranged to lead the first cleaner gas to the second cyclone, where the second cyclone is arranged to remove particulate matter from the first cleaner gas in order to provide a second cleaner gas, a pipe arranged to lead the second cleaner gas to a special piping element, the latter including a burner, thereby providing a third cleaned gas, and a gas distribution unit arranged to lead the third cleaned gas to one or more tar reformer units. Also, a method of treating a gas from a biomass gasification system.
Type:
Application
Filed:
August 22, 2017
Publication date:
June 18, 2020
Applicant:
HALDOR TOPSØE A/S
Inventors:
Jørgen MADSEN, Erik GAMBARINI, Erik LØGSTED-NIELSEN
Abstract: The content of oxygen in molten metallic copper is reduced during the copper refining process by adding pure carbon monoxide, produced by electrolysis of carbon dioxide in a solid oxide electrolysis cell (SOEC), thereby removing oxygen through the reduction of CuO to Cu. This way, the purity of the metallic copper is increased.
Type:
Application
Filed:
April 16, 2018
Publication date:
June 18, 2020
Applicant:
HALDOR TOPSØE A/S
Inventors:
Artem TARASENKO, Niklas Bengt JAKOBSSON, Bengt Peter Gustav BLENNOW, Casper HADSBJERG
Abstract: The present application relates to a process for treating the off gas from a carbon black process, said process comprising the steps of: providing an off gas from a carbon black process, reacting said off gas in a first reaction step forming water and S, and condensing the S at a temperature Tcon where S is in a liquid phase and the water is in gas form thereby achieving a gaseous stream comprising water and a liquid stream comprising S, and wherein the first reaction step is carried out over a monolith catalyst.
Type:
Application
Filed:
January 25, 2018
Publication date:
June 18, 2020
Applicant:
Haldor Topsøe A/S
Inventors:
Niklas Bengt Jakobsson, Peter Bo Olsen, Janus Emil Münster-Swendsen
Abstract: A process for combined removal of siloxanes and sulfur-containing compounds from biogas streams, such as streams from landfills or anaerobic digesters, comprises heating the biogas stream and optionally mixing it with air, feeding the gas to a first filter unit with high temperature resistance, injecting a dry sorbent into the first filter unit to capture siloxanes present in the gas, recycling part of the exit gas from the first filter unit to the inlet thereof for the sulfur-containing compounds to be captured by the dry sorbent or optionally to a second filter unit inlet for the sulfur-containing compounds to be captured by a sulfur-specific sorbent and recovering clean gas from the first or optionally from the second filter unit.
Type:
Grant
Filed:
June 13, 2017
Date of Patent:
June 16, 2020
Assignee:
Haldor Topsoe A/S
Inventors:
Niklas Bengt Jakobsson, Janus Emil Münster-Swendsen
Abstract: A catalyst-containing ceramic dust filter for off-gas or exhaust gas cleaning is prepared by a method comprising the steps of making a water-based impregnation slurry, which comprises a catalytically effective amount of at least one catalytically active metal and an oxide support, to form a catalytically active metal oxide support, impregnating the filter substrate with the impregnation slurry, spraying from the inside to control the amount of liquor while leaving the outer few millimeters of the filter wall dry, and drying the impregnated filter. The impregnated filter is preferably dried by using microwave energy.
Abstract: In a process for the production of ammonia synthesis gas from a hydrocarbon-containing feedstock, comprising steam reforming of the feedstock and treatment of the synthesis gas obtained, the shift of the synthesis gas comprises two shift steps, both including stable catalysts, whereby the formation of hazardous by-products is avoided or at least reduced to an acceptable low level. The two shift steps can both be HTS, or they can be one HTS and one LTS or one HTS and one MTS. The catalyst used in the HTS and the LTS steps is based on zinc oxide and zinc aluminum spinel, and the catalyst used in the MTS and the LTS steps can be based on copper.
Type:
Application
Filed:
June 28, 2018
Publication date:
June 11, 2020
Applicant:
HALDOR TOPSØE A/S
Inventors:
Annette E. KRØLL JENSEN, Christian Henrik SPETH, Thomas ROSTRUP-NIELSEN
Abstract: Oxygen is removed from a gas feed such as a landfill gas, a digester gas or an industrial CO2 off-gas by removing sulfur-containing compounds and siloxanes from the feed gas, heating the feed gas, injecting one or more reactants for oxygen conversion into the heated feed gas, carrying out a selective catalytic oxygen conversion in at least onesuitable reactor and cleaning the resulting oxygen-depleted gas. The reactants to be injected comprise one or more of H2, CO, ammonia, urea, methanol, ethanol and dimethylether (DME).
Abstract: A process including (a) directing a hydrocarbon mixture to contact a material catalytically active in hydrocracking under hydrocracking conditions, (b) providing a first hydrocracked product, (c) directing an amount of the first hydrocracked product and an amount of a converted hydrocracked product to a product separation step separating it into one or more products and a recycle oil having a higher boiling point than the products, (d) directing the recycle oil to contact a second material catalytically active in hydrocracking under hydrocracking conditions providing a second hydrocracked product, (e) directing at least an amount of the second hydrocracked product as feed to a second separation step, separating the second hydrocracked product in at least two fractions, a converted hydrocracked product and an unconverted oil an unconverted oil having a higher average boiling point than the recycle oil, (f) withdrawing at least an amount of the unconverted oil as purge.