Abstract: Process and catalyst for upgrading gasoline comprising durene (1,2,4,5-tetramethylbenzene) and pseudodocumene, the process comprises hydroisomerization of durene (1,2,4,5-tetramethylbenzene) and pseudocumene (1,2,4-trimethylbenzene) contained in the gasoline in presence of a catalyst comprising a sulfided base metal supported on an acidic carrier, thereby converting durene (1,2,4,5-tetramethylbenzene) to isodurene (1,2,4,5-tetramethylbenzene) and prehnitene (1,2,3,4-tetramethylbenzene) and converting pseudocumene (1,2,4-trimethylbenzene) to mesitylene (1,3,5-trimethylbenzene).
Abstract: The present application relates to a process for production of hydrocarbons comprising the steps of—converting a feed stream comprising alcohols, ethers or mixtures hereof over a metal-containing zeolite based catalyst, active in dehydrogenation of hydrocarbons, in a conversion step thereby obtaining a conversion effluent, —separating said effluent to obtain an aqueous process condensate stream, a liquid hydrocarbon stream and a gaseous stream, —removing part of the hydrogen formed in the conversion step, and recycling at least part of the gaseous and/or liquid hydrocarbon stream to the conversion step.
Type:
Grant
Filed:
January 22, 2016
Date of Patent:
December 11, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
Finn Joensen, Uffe Vie Mentzel, Ian Menjon
Abstract: A bifunctional catalyst for conversion of oxygenates, said catalyst comprising zeolite, alumina binder and Zn, wherein the Zn is present at least partly as ZnAl2O4.
Abstract: In a process for methanol production from synthesis gas, which comprises the steps of providing a make-up gas containing hydrogen and carbon monoxide, in which the content of carbon dioxide is less than 0.1 mole %, mixing the make-up gas with a hydrogen-rich recycle gas and passing the gas mixture to a methanol synthesis reactor, optionally via a sulfur guard, and subjecting the effluent from the synthesis reactor to a separation step, thereby providing crude methanol and the hydrogen-rich recycle gas, the customary addition of carbon dioxide to the make-up gas is replaced by addition of water in an amount of 0.1 to 5 mole %. This way, a CO2 compressor is saved, and the amount of poisonous sulfur in the make-up gas is markedly reduced.
Type:
Application
Filed:
May 10, 2016
Publication date:
October 25, 2018
Applicant:
Haldor Topsøe A/S
Inventors:
Per Juul Dahl, Hassan Modarresi, Max Thorhauge
Abstract: The present application relates to a process for production of hydrocarbons comprising the steps of: converting a feed stream comprising alcohols, ethers or mixtures hereof over a Zn-containing zeolite based catalyst wherein Zn is at least partly present as ZnAl2O4, active in dehydrogenation of hydrocarbons, in a conversion step thereby obtaining a conversion effluent, separating said effluent to obtain an aqueous process condensate stream, a liquid hydrocarbon stream and a gaseous stream, removing part of the hydrogen formed in the conversion step, and recycling at least part of the gaseous and/or liquid hydrocarbon stream to the conversion step.
Abstract: The present invention relates to a process for heating an ATR or POX comprising the steps of heating a process stream by at least one heating means, admitting the heated process stream to an ATR or POX reactor through a main burner, and heating the ATR or POX reactor to or above autoignition temperature of the process stream via the heated process stream.
Type:
Grant
Filed:
April 8, 2015
Date of Patent:
October 23, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
Per Juul Dahl, Thomas Sandahl Christensen
Abstract: The present relates to a method for controlling the inlet temperature Ti to a conversion process, said method comprising the steps of: Providing a feed for a conversion process; In a first temperature control step regulating the temperature of the feed in a waste heat boiler; In a second temperature control step injecting a water stream into the feed downstream the waste heat boiler in an amount and/or at a temperature to obtain the desired inlet temperature into the conversion process.
Type:
Application
Filed:
December 7, 2016
Publication date:
October 18, 2018
Applicant:
Haldor Topsøe A/S
Inventors:
Christian Henrik Speth, Emil Andreas Tjärnehov
Abstract: A method and a system to assemble a plurality of filter bags within one another by means of a pole and a pulling guide, and a filter bag unit comprising a plurality of assembled filter bags with creases and stitches oriented relative to each other.
Abstract: A continuous flow process for the preparation of one or more esters of lactic acid and 2-hydroxy-3-butenoic acid or ?-hydroxy methionine analogs from a sugar in the presence of a solid Lewis acid catalyst and a solvent comprising an organic solvent and water. The invention provides a means for stabilizing a Lewis acid catalyst for use in a continuous reaction process wherein the water is present in an amount of up to or equal to 10 vol. % of the organic solvent.
Abstract: Process for the production of synthesis gas by catalytic steam reforming of a hydrocarbon containing feedstock in parallel in an autothermal steam reformer and heat exchange reformer, the heat for the steam reforming reactions in the heat exchange reformer being provided by indirect heat exchange with the combined effluent of the heat exchange reformer and a portion of the autothermal steam reformer.
Abstract: Method for the preparation of a metal-exchanged zeolites or mixtures of metal-exchanged zeolites, such as Cu-SSZ-13, Cu-ZSM-5, Cu-beta, or Fe-beta, comprising the steps of providing a dry mixture of a) one or more microporous zeotype materials that exhibit ion exchange capacity and b) one or more metal compounds; heating the mixture in a gaseous atmosphere containing ammonia to a temperature lower than 300° C. for a time sufficient to initiate and perform a solid state ion exchange of ions of the metal compound and ions of the zeolite material; and obtaining the metal-exchanged zeolite material.
Type:
Grant
Filed:
October 15, 2014
Date of Patent:
September 25, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
Ton V. W. Janssens, Peter N. R. Vennestrøm
Abstract: A burner with a plurality of oxidant gas pipes distributed throughout the cross section of the burner and process gas in plug flow provides even mixing of the oxidant and the process gas.
Abstract: A process for the preparation of ethylene glycol comprising the steps of pyrolyzing a monosaccharide and hydrogenating the product composition in the presence of a catalyst and a solvent, wherein the pressure of the hydrogenation reaction is 40 bar or greater.
Abstract: In a broad aspect the present disclosure relates to a process plant and a process for upgrading a hydrocarbon mixture, withdrawn as a direct stream from a crude distillation unit and an initial boiling point below 200° C., and a fraction of at least 5% boiling above 500° C., 550° C. or 650° C. comprising the steps of a. directing said hydrocarbon mixture to a vacuum flasher unit, b. withdrawing a heavy hydrocarbon fraction from said vacuum flasher unit, c. withdrawing a light hydrocarbon mixture for hydrocrackingfrom said vacuum flasher unit, d. directing said light hydrocarbon mixture for hydrocracking and a stream rich in hydrogen to con-tact a material catalytically active in hydrocracking, e. withdrawing a hydrocracked stream of hydrocarbon from said hydrocracker. with the associated benefit of limiting the amount of asphaltenes, metals and other heavy components contacting said material catalytically active in hydrocracking.
Abstract: A catalyst-containing ceramic dust filter for off-gas or exhaust gas cleaning is prepared by a method comprising the steps of making a water-based impregnation slurry, which comprises a catalytically effective amount of at least one catalytically active metal and an oxide support, to form a catalytically active metal oxide support, impregnating the filter substrate with the impregnation slurry, spraying from the inside to control the amount of liquor while leaving the outer few millimeters of the filter wall dry, and drying the impregnated filter. The impregnated filter is preferably dried by using microwave energy.
Abstract: In a novel process for methanol production from low quality synthesis gas, in which relatively smaller adiabatic reactors can be operated more efficiently, some of the inherent disadvantages of adiabatic reactors for methanol production are avoided. This is done by controlling the outlet temperature in the pre-converter by rapid adjustment of the recycle gas, i.e. by manipulating the gas hourly space velocity in the pre-converter.
Abstract: A heat exchanger has a pass baffle which is formed as an enclosure with two openings, one opening for connection to a shell-side fluid opening and one opening for passing heat exchanger tubes.
Abstract: The invention concerns a process for monitoring failure situations related to feed and/or purge flow in electrolyzer cells, stacks or systems, said monitoring process being combined with appropriate actions to be taken in case of such failure situations, wherein (a) the current and/or the voltage are monitored and controlled over a single cell, over all the cells or over one or more selected cells in a stack or a system of stacks, (b) in case the current, the voltage or the ratio between voltage and current crosses its pre-defined threshold value, a failure mode is detected and communicated to the control system, and c) the voltage levels of the system are adjusted to be within safe limits (safe-mode limits).
Abstract: A catalyzed fabric filter substrate and a method of preparing the substrate comprising the steps of a) providing a fabric filter substrate b) providing an aqueous impregnation liquid comprising an aqueous hydrosol of one or more catalyst metal precursor compounds dispersed on nanoparticles of an oxidic metal carrier, a surfactant and a dispersing agent selected from the group of primary amines; c) impregnating the fabric filter substrate with the impregnation liquid; and d) drying and thermal activating the impregnated fabric filter substrate at a temperature below 300° C. to convert the one or more metal compounds of the catalyst precursor to their catalytically active form.
Type:
Application
Filed:
June 25, 2015
Publication date:
August 16, 2018
Applicant:
Haldor Topsøe A/S
Inventors:
Francesco Castellino, Thomas Holten Kollin