Abstract: 3-Phenoxybenzaldehyde acetals can be prepared by reacting a 3-bromobenzalkehyde acetal with an alkali metal phenolate at a temperature of about 130.degree.-165.degree. C. in the presence of a copper catalyst and a phenol as the sole solvent. The product acetals can be converted to the corresponding 3-phenoxybenzaldehydes by hydrolysis.
Abstract: 3-Bromobenzaldehydes are prepared by reacting a benzaldehyde having a free 3-position with bromine chloride in the presence of aluminum chloride and a small amount of dibromomethane.