Abstract: A thermally-integrated lower temperature water-gas shift reactor apparatus for converting carbon monoxide in the presence steam comprises a catalyst bed that is disposed within an outer region surrounding a waste heat recovery steam generator operating at a selected pressure corresponding to the optimum temperature for conducting the catalytic water-gas shift reaction and a process for useful recovery of the exothermic heat of reaction to generate steam that is used in a process for the conversion of hydrocarbon feedstock into useful gases such as hydrogen.

Abstract: A compact endothermic catalytic reaction apparatus for converting hydrocarbon feedstock and methanol to useful gases, such as hydrogen and carbon monoxide, comprising a tubular endothermic catalytic reactor, a radiant combustion chamber and an annular convection section. Thus tubular endothermic catalytic reactor receives radiant energy from a metal fiber burner that is disposed within the radiant combustion chamber. Combustion products from the radiant chamber enter an annular convection section wherein heat is transferred by forced convection to the tubular endothermic catalytic reactor. The combination of radiant and convective heat transfer results in a compact design of high thermal efficiency.

Abstract: A fuel processor apparatus comprising a catalytic tubular reactor is heated using an infrared radiant burner to provide the endothermic heat of reaction needed to reform a mixture of hydrocarbon and steam for the production of a hydrogen-rich gas stream. The hydrogen-rich gas stream is further purified using a sequence of catalytic steps that is fed to a fuel cell whereupon a portion of the hydrogen contained in the gas stream is consumed for the production of electricity by electrochemical reaction with oxygen. An unused portion of the purified hydrogen-rich gas stream exits the fuel cell stack and is combusted in the infrared radiant burner. A fuel cell control system rapidly responds to a variable fuel cell electric demand by adjusting the feed of hydrocarbon to the catalytic tubular reactor to maintain the surface temperature of the infrared radiant burner within defined limits.

Abstract: The formation of coke on metal surfaces exposed to hydrocarbons in a thermal cracking process is reduced by ion implantation of selected antifoulants into such metal surfaces; the antifoulants being chosen from a group of primary elements consisting of aluminum, silicon, and chromium, or combinations thereof, and a group of secondary elements consisting of calcium, lithium, potassium, magnesium, cesium, hafnium, yttrium and zirconium, or combinations thereof.

Abstract: A compact endothermic catalytic reaction apparatus for converting hydrocarbon feedstock and methanol to useful gases, such as hydrogen and carbon monoxide, comprising a tubular endothermic catalytic reactor, a radiant combustion chamber and an annular convection section. Thus tubular endothermic catalytic reactor receives radiant energy from a metal fiber burner that is disposed within the radiant combustion chamber. Combustion products from the radiant chamber enter an annular convection section wherein heat is transferred by forced convection to the tubular endothermic catalytic reactor. The combination of radiant and convective heat transfer results in a compact design of high thermal efficiency.