Patents Assigned to Harwe AG
  • Patent number: 4404360
    Abstract: Molded articles of polymerized lactams are prepared by pumping of a catalyst containing partial lactam melt at a temperature of .+-.1.degree. C. of a temperature in the range of 160.degree. C. to 170.degree. C. and a lower temperature activator containing partial lactam melt at a temperature of .+-.1.degree. C. of a temperature in the range of 160.degree. C. to 170.degree. C. to which activator addition is delayed relative to catalyst addition, with separate gear pumps to a mixing zone maintained between 170.degree. and 175.degree. C., the pumps connected to the mixing zone by straight feed tubes positioned at an angle of inclination to the horizontal of a maximum of 10.degree., each feed tube having a volume of at least one-third greater than the pump to which it is connected and form the mixing zone into a mold. At least part of the gases released are returned to the mixing zone by the tube systems and gear pumps. The products formed crumble on being heated to a temperature of approximately 220.degree. C.
    Type: Grant
    Filed: November 2, 1981
    Date of Patent: September 13, 1983
    Assignee: Harwe AG
    Inventor: Werner Hartmann
  • Patent number: 4393193
    Abstract: Molded articles of polymerized lactams are prepared by pumping of a catalyst containing partial lactam melt at a temperature of .+-.1.degree. C. of a temperature in the range of 160.degree. C. to 170.degree. C. and a lower temperature activator containing partial lactam melt at a temperature of .+-.1.degree. C. of a temperature in the range of 160.degree. C. to 170.degree. C. to which activator addition is delayed relative to catalyst addition, with separate gear pumps to a mixing zone maintained between 170.degree. and 175.degree. C., the pumps connected to the mixing zone by straight feed tubes positioned at an angle of inclination to the horizontal of a maximum of 10.degree., each feed tube having a volume of at least one-third greater than the pump to which it is connected and form the mixing zone into a mold. At least part of the gases released are returned to the mixing zone by the tube systems and gear pumps. Apparatus to carry out the method is also provided.
    Type: Grant
    Filed: September 15, 1980
    Date of Patent: July 12, 1983
    Assignee: Harwe AG
    Inventor: Werner Hartmann
  • Patent number: 4349460
    Abstract: Disclosed are catalysts for the polymerization of higher lactam monomers. The catalysts comprise an essentially homogenic binary mixture of lauric-lactam and a salt of lauric-lactam.The inventive catalyst can be stored at room temperature without making special provisions to avoid any access of air and moisture.
    Type: Grant
    Filed: March 24, 1981
    Date of Patent: September 14, 1982
    Assignee: Harwe AG
    Inventor: Werner Hartmann
  • Patent number: 4233433
    Abstract: Molded articles of polymerized lactams are prepared by pumping of a catalyst containing partial lactam melt at a temperature of .+-. 1.degree. C. of a temperature in the range of 160.degree. C. to 170.degree. C. and a lower temperature activator containing partial lactam melt at a temperature of .+-. 1.degree. C. of a temperature in the range of 160.degree. C. to 170.degree. C. to which activator addition is delayed relative to catalyst addition, with separate gear pumps to a mixing zone maintained between 170 and 175.degree. C., the pumps connected to the mixing zone by straight feed tubes positioned at an angle of inclination to the horizontal of a maximum of 10.degree., each feed tube having a volume of at least one-third greater than the pump to which it is connected and form the mixing zone into a mold. At least part of the gases released are returned to themixing zone by the tube systems and gear pumps. Apparatus to carry out the method is also provided.
    Type: Grant
    Filed: June 29, 1977
    Date of Patent: November 11, 1980
    Assignee: Harwe AG
    Inventor: Werner Hartmann