Patents Assigned to Herberts Gesellschaft mit beschrankter
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Patent number: 6329020Abstract: Described are a method for the preparation of a multilayer coating and a coating material from an aqueous dispersion of a polymer with a particle diameter of the polymeric phase of 10 nm to 500 nm. The polymer has a number average molecular weight of 10,000 to 500,000 and an acid number of 12 to 40. The dispersion was obtained by polymerization without addition of emulsifier and in the presence of water insoluble initiators of a) 0.Type: GrantFiled: March 19, 1997Date of Patent: December 11, 2001Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Hans-Peter Patzschke, Armin Göbel, Hans Ulrich Meier
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Patent number: 6214898Abstract: New modified polyester resin/organic peroxide systems for powder coatings which are applicable to temperature sensitive and metallic substrates include (a) a polyester resin which is a hydroxylated or carbonxylated polyester with unsaturation in its chain, and (b) an organic peroxide with a minimum curing temperature of between 140° and 190° C.; the relative proportions of resin and organic peroxides being 55-60% by weight of resin based on the final composition and 0.5-3.0 by weight of organic peroxide based on the final formulation. These systems find their main application in the manufacture of powder coatings for the coating of temperature sensitive substrates like plastics and metallic substrates, especially aluminum substrates, using the systems currently existing in industry.Type: GrantFiled: October 2, 1998Date of Patent: April 10, 2001Assignee: Herberts Gesellschaft mit beschränkter HaftungInventor: José Luis Diloy Barrio
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Patent number: 6162886Abstract: This invention relates to copolymers which contain hydroxyl groups and which are based on vinyl esters of monocarboxylic acids, wherein the copolymers which contain hydroxyl groups have an OH number of 110-170 mg KOH/g, an acid number of 5-35 mg KOH/g and a number average molecular weight M.sub.n of 1500-8000 g/mole and are obtainable by the polymerisation of A) 5-20% by weight of one or more vinyl esters of saturated monocarboxylic acids, B) 10-30% by weight of one or more aromatic vinyl hydrocarbons, C) 41-55% by weight of hydroxy-functional, polymerisable, unsaturated monomers, and D) 0-40% by weight of further polymerisable, unsaturated monomers, wherein component C) contains C1) 40-70% by weight of one or more hydroxyalkyl esters of .alpha.,.beta.-unsaturated monocarboxylic acids, C2) 1-10% by weight of one or more lactones, and C3) 30-55% by weight of one or more reaction products of an .alpha.,.beta.-unsaturated monocarboxylic acid with a glycidyl ester of a saturated .alpha.,.alpha.Type: GrantFiled: January 29, 1998Date of Patent: December 19, 2000Assignee: Herberts Gesellschaft mit Beschrankter HaftungInventors: Gerhard Bremer, Hermann Kerber, Manfred Krumme, Olaf Ley, Werner Stephan, Jorg Wabbels
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Patent number: 6136445Abstract: The invention is directed to a lacquer coating for polymer sheet and a method for applying the coated polymer sheet to a molded body. The lacquer contains a binder, a metal pigment, a color pigment, organic solvent in water wherein the binder includes a combination of hard and flexible resins. The ratio of these resin is adjusted so that the elastic-plastic behavior of the lacquer coating matches that of the plastic polymer sheet. In this fashion, the coated sheet can be deformed without causing substantial blistering or cracking of the coating on the polymer sheet.Type: GrantFiled: July 16, 1996Date of Patent: October 24, 2000Assignee: Herberts Gesellschaft mit Beschrankter HaftungInventors: Christian Gruner, Reinhart Schmitt, Hans-Peter Patzschke
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Patent number: 6093299Abstract: This invention relates to a stove-enamel coating medium based on at least one binder vehicle selected from amino(meth)acrylate resins and/or epoxide-amine addition products comprising cationic groups and/or groups which can be converted into cationic groups. The binder vehicle additionally comprises cyclic carbonate groups and/or at least one crosslinking agent which comprises cyclic carbonate groups is present, and the binder vehicle also contains secondary amino groups and/or hydroxyl groups.Type: GrantFiled: February 10, 1998Date of Patent: July 25, 2000Assignee: Herberts Gesellschaft Mit Beschrankter HaftungInventors: Joachim Blum, Klausjorg Klein, Hans-Peter Patzschke, Bettina Vogt-Birnbrich
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Patent number: 6063954Abstract: This invention relates to non-ionic emulsifiers based on fatty acid esters of polyalkoxylated polyhydric alcohols as fundamental constituents. At least two fundamental constituents are linked to each other by the reaction of hydroxyl groups with a polyisocyanate, with the formation of urethane bonds.Type: GrantFiled: April 10, 1998Date of Patent: May 16, 2000Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Wolfgang Diener, Volker Duecoffre, Carmen Flosbach, Gerhard Hey, Walter Schubert
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Patent number: 6037404Abstract: This invention relates to a composition, and to the preparation and use of thereof said composition being suitable as a rheology influencer for coating media and comprising the reaction product formed by reaction of a mixture of components A, B and C with components D, E and F. Components A, B and C form a mixture wherein component A is one or more (meth)acrylic copolymers and/or one or more polyesters which contain hydroxyl groups. Component B is a copolymer of ethylhexyl (meth)acrylate and one or more hydroxyalkyl (meth)acrylates, as well as .alpha.,.beta.-unsaturated monomers which are different therefrom. Component C is a hydroxy--functional microdispersion which is produced by polymerizing hydroxylalkyl (meth)acrylates in combination with unsaturated monomers in a mixture of polyesters or polyacrylates containing carboxyl and/or hydroxyl groups. Component D is one or more aliphatic polyisocyantes and component E is .epsilon.-caprolactam. The caprolactam partially blocks the polyisocyanate.Type: GrantFiled: June 2, 1998Date of Patent: March 14, 2000Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Ralf Dahm, Carmen Flosbach, Hermann Kerber, Sandra Kirchgassler, Dieter Lerch, Frank Schnodewind, Walter Schubert
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Patent number: 5985369Abstract: A method is described for the coating of substrates by the application of a liquid coating compound and subsequent curing, which is characterised in that there are added to the coating compound one or more polybutenes (C4-polyolefins) with a molecular weight of 200 to below 500, in a quantitative proportion of 0.5 to 10 wt. %, referred to the solids content of the coating compound, in order to improve the flow properties. The liquid coating compounds are also described.Type: GrantFiled: July 25, 1997Date of Patent: November 16, 1999Assignee: Herberts Gesellschaft Mit Beschrankter HaftungInventors: Christiane Kerkmann, Hans-Jurgen Schlinsog, Hans-Martin Schonrock
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Patent number: 5976343Abstract: Process for multi-coat lacquering of a substrate with a stoved first electrodeposition layer by applying a second surface coating layer of 10 to 30 .mu.m dry layer thickness consisting of a base lacquering agent containing a first, water-based, polyurethane resin, and wet-on-wet application of a third coating agent with a thinner dry layer thickness of 7 to 15 .mu.m consisting of a second water-based base lacquering agent, further application without prior stoving of a clear lacquer layer and mutual stoving, wherein the first base lacquering agent has a higher concentration of polyurethane resin than the second base lacquering agent.Type: GrantFiled: December 10, 1998Date of Patent: November 2, 1999Assignee: Herberts Gesellschaft mit beschrankter HaftungInventor: Detlef Schlaak
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Patent number: 5932282Abstract: A process for producing a repair coating This invention relates to a process for producing a multi-layer repair coating by the application of a transparent clear lacquer coat, which is unpigmented or which contains colourless pigment, to a predried or hardened colour- and/or effect-imparting base pigment coat, or by the application of a pigmented covering lacquer coat to an optionally precoated substrate. Binder vehicles which are hardenable exclusively by radical polymerisation are used for the production of the transparent clear lacquer coat or of the pigmented covering lacquer coat, and hardening is effected by means of pulsed, high-energy UV radiation.Type: GrantFiled: August 29, 1997Date of Patent: August 3, 1999Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Wolfgang Diener, Peter Klostermann, Frank-Jurgen Krumpolt, Christine Kurz, Karin Maag, Hans-Ulrich Simmrock, Werner Lenhard
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Patent number: 5908667Abstract: Process for producing a multilayer lacquer coating, in which a primer of an electrophoretically depositable aqueous coating agent (1) is electrophoretically applied on to an electrically conductive substrate and is then stoved, whereupon a color-giving and/or effect-producing base lacquer coat of an aqueous coating agent (II) is applied and stoved and this coat is then provided with one or more clear lacquer coatings, in which processa) as the coating agent (I), a coating agent which, in the stoved state, will produce an electrically conductive primary coat is used,b) the base lacquer coat is formed by an electrophoretically depositable aqueous coating agent (II) by a process of electrophoretical deposition,c) the overall dry layer thickness of the dry lacquer coat or dry lacquer coats is about 40 and 80 .mu.m, andd) the overall dry layer thickness of the multilayer lacquer coating is about 80 to 110 .mu.m.Type: GrantFiled: November 25, 1997Date of Patent: June 1, 1999Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Joachim Blum, Dieter Stranghoner, Dieter Engel, Klausjorg Klein, Walter Kuhhirt, Matthias Kimpel, Friedrich-Ludwig Siever
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Patent number: 5906864Abstract: Aqueous coating composition, containingI) one or more amine hardeners,II) one or more water-dilutable epoxy resins,III) one or more pigments and/or fillers andIV) water and optionally one or more solvents and/or conventional lacquer additives,wherein the composition of the coating composition is selected in such a way that a hardened free film formed from the coating composition with a coat thickness between 30 and 80 .mu.m has a storage modulus E' of 10.sup.8 Pa to 5.times.10.sup.9 Pa in a temperature range from -50.degree. C. to 150.degree. C.Type: GrantFiled: June 23, 1997Date of Patent: May 25, 1999Assignee: Herberts Gesellschaft mit Beschrankter HaftungInventors: Michael Osterhold, Werner Lenhard, Wilfried Collong, Willi Schlesing
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Patent number: 5882734Abstract: In a process for producing a multilayer lacquer coating, eg for motor vehicles, a first coating layer of an aqueous coating agent (1) is electrophoretically applied on to an electrically conductive substrate and is then stoved. As the coating agent (I), a coating agent which, in the stoved state, will produce an electrically conductive coating layer is used. An electrically insulating second coating layer of an aqueous coating agent (II), which differs from (I), is electrophoretically deposited and stoved. A third basic lacquer coating layer of a colour-giving and/or effect-producing coating agent is applied, and a fourth transparent coating layer of a clear lacquer coating agent is applied, the last-mentioned two coats being stoved together. One or more further transparent coating layers may be applied.Type: GrantFiled: November 25, 1997Date of Patent: March 16, 1999Assignee: Herberts Gesellschaft Mit Beschrankter HaftungInventors: Joachim Blum, Dieter Stranghoner, Dieter Engel, Klausjorg Klein, Walter Kuhhirt, Matthias Kimpel, Friedrich-Ludwig Siever
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Patent number: 5869198Abstract: A process for the multi-layer coating of electrically conductive substrates by the electrophoretic deposition of a first coating layer comprising an electrophoretically depositable aqueous coating medium, to which a second coating layer, comprising a first color- and/or effect-imparting base lacquer coating medium, is applied wet-into-wet, and the first and second coating layers thus obtained are stoved jointly, whereupon a third coating layer comprising a second color- and/or effect-imparting base lacquer coating medium is applied and a fourth coating layer comprising a clear lacquer coating medium is applied wet-into-wet thereto and the third and fourth coating layers are stoved jointly, wherein the total dry coat thickness of the second and third coating layers produced from the base lacquer coating media is between 15 and 40 .mu.m and the proportion of the second coating layer is between 20 and 50% of the total dry coat thickness of the second and third coating layers.Type: GrantFiled: September 30, 1997Date of Patent: February 9, 1999Assignee: Herberts Gesellschaft Mit Beschrankter HaftungInventors: Marcus Erne, Jurgen Dobert, Klausjorg Klein, Matthias Kimpel
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Patent number: 5804615Abstract: This invention relates to an aqueous coating composition based on epoxy resins for coating plastic substrates. It contains7.5 to 25 wt. % of one or more epoxy resins1.5 to 10 wt. % of one or more water-miscible polyamines0 to 10 wt. % of one or more chlorinated and/or non-chlorinated polyolefins1 to 35 wt. % of electrically conductive pigments and/or extenders5 to 25 wt. % of one or more organic solvents and35 to 60 wt. % of waterwherein the sum of the above-stated constituents amounts to 100 wt. % and the coating composition additionally contains conventional lacquer additives, pigments and/or extenders and optionally further binders.Type: GrantFiled: December 16, 1996Date of Patent: September 8, 1998Assignee: Herberts Gesellschaft Mit Beschrankter HaftungInventors: Peter Schreiber, Reinhard Windmann, Dieter Huber, Stefanie Goecke
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Patent number: 5760123Abstract: Aqueous dispersion of one or more polyurethane resins with a number average molecular weight (Mn) of 2500 to 1000000, a content of 2 to 150 mmol of siloxane linkages (--Si--O--Si--) per 100 g of solid resin, a hydroxyl value of 0 to 100 and a content of ionic groups, groups convertible into ionic groups and/or hydrophilic groups of 5 to 200 mEq per 100 g of solid resin and the process for the production thereof by chain extension of a polyurethane prepolymer containing ionic groups, groups capable of ion formation and/or hydrophilic groups which has at least one group R'OSi-- in whichR'=C.sub.1 to C.sub.8 alkyl or C(O)R"' andR"'=C.sub.1 to C.sub.10 alkylby the addition of water. The aqueous dispersion is suitable for aqueous coating compositions which are suitable in particular for multilayer lacquer coatings.Type: GrantFiled: February 13, 1996Date of Patent: June 2, 1998Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Bettina Vogt-Birnbrich, Hans-Peter Patzschke, Werner Lenhard, Jurgen Dobert, Marcus Brunner
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Patent number: 5747114Abstract: A process for the effect coating of polar plastics parts having a grained surface, characterised in thata) a first coating layer, which is free from effect pigments and modified polyolefines and which comprises a coating medium based on physically drying binder vehicle systems which contain one or more polyurethane resins and/or oligomeric urethanes and which do not chemically crosslink at the temperatures employed in process step f), is applied at a dry coat thickness of 5 to 40 .mu.m,b) is dried at 20.degree. to 80.degree. C. down to a residual content of 3 to 20% by weight of the volatile fractions which are contained in the applied coating film at the temperature employed,c) is overcoated wet-into-wet with an effect base lacquer,d) is dried at 20.degree. to 80.degree. C.Type: GrantFiled: September 18, 1996Date of Patent: May 5, 1998Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Helga Stegen, Joachim Blum, Klaus-Gunter Kerlin
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Patent number: 5739216Abstract: Binder composition, coating compositions produced therefrom and use thereof, in particular for multi-layer lacquer coatings. The binder composition contains:A) 25 to 75 wt. % of the reaction product of one or more carboxy-functionalised (meth) acrylic copolymers containing urethane groups and/or of one or more carboxy-functionalised polyesters containing urethane groups, each having an acid value of 30 to 200 mg of KOH/g, with one or more lactones,B) 25 to 75 wt. % of one or more epoxy-functionalised crosslinking agents having at least two epoxy functions per molecule with a number average molecular weight (Mn) of 200 to 10000 g/mol,C) 0 to 60 wt. % of one or more polyols having at least two hydroxyl functions per molecule,D.sub.1) 0 to 20 wt. % of one or more melamine resins,D.sub.2) 0 to 40 wt. % of one or more free or capped polyisocyanates, wherein the sum of the weight percentages of components A), B), C), D.sub.1) and D.sub.2) amounts to 100 wt. %, together withE) 0 to 10 wt.Type: GrantFiled: January 2, 1997Date of Patent: April 14, 1998Assignee: Herberts Gesellschaft Mit Beschrankter HaftungInventors: Volker Duecoffre, Carmen Flosbach, Friedrich Herrmann, Heinz-Walter Reifferscheidt, Walter Schubert
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Patent number: 5723537Abstract: Pigment pastes are produced by pasting or blending one or several pigments and/or fillers in a paste resin based on a polyester oligomer polyacrylate which is obtainable by radical polymerisation ofA) 80-50 wt % ofa) one or several hydroxyfunctional acrylic acid esters and/or methacrylic acid esters andb) one or several monofunctional ethylenically unsaturated acids, as well as, optionally,c) one or several alpha,beta-ethylenically unsaturated monomers without functional groups inB) 20-50 wt % of one or several hydroxyfunctional polyester oligomers with a calculated molecular weight of 200-1000, a hydroxy number of 280-600 and an acid number of 0-1.5, obtainable by polycondensation of one or several diols, polyols and dicarboxylic acids and derivatives thereof,whereby the monomers a), b) and c) are used in such quantities as to ensure that the polyester oligomer polyacrylate obtained has a hydroxyl number of 150-390 and an acid number of 16-40.Type: GrantFiled: June 5, 1995Date of Patent: March 3, 1998Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Gerda Bajorat, Claudia Hamel, Hartmut Kern
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Patent number: 5721018Abstract: A process for preparing a multi-layer coating on an electrically nonconductive surface of a substrate, which comprises(A) applying over the surface an aqueous dispersion having a pH of from 5 to 8 when not containing a metallic pigment, the dispersion containing of from 15% to 20% wt. based on the dispersion of a base coat resin without metallic pigments then having a nonvolatile content of from about 30% to about 50% wt. based on the base coat resin of(i) from 75% to 98% wt. based on base coat resin solids of one or more partially or completely acid neutralized cationic, polyurethane, and polyurethane-urea resins, having a OH number of up to 450, and an amine number of from 20 to 200, and(ii) from 2% to 25% wt. based on base coat resin solids of one or more of an amine-formaldehyde condensation resin alone or in admixture with a blocked polyiisocyanate in either case having at least two groups per molecule being reactive with one or more of amino, OH.sup.Type: GrantFiled: April 26, 1996Date of Patent: February 24, 1998Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Wolfgang Goldner, Werner Lenhard, Albrecht Luttenberg, Hans-Peter Patzschke