Patents Assigned to Herberts Gesellschaft mit beschrankter Haftung
  • Patent number: 5453301
    Abstract: Continuous process for recovering the overspray of aqueous coating agents during spray application by collecting it in an aqueous washing liquid which is continuously circulated in a circuit (A) to the spray booth, where the solids concentration of said washing liquid is maintained within the range of 1-1.5 wt.-%, whereby a part of the washing liquid containing overspray is fed to a first ultrafiltration circuit (B) in which the solids concentration of the circulating liquid is maintained within a range of 8-15 wt.-%, a part of the circulating liquid from ultrafiltration circuit (B) being fed to a further ultrafiltration circuit (C) in which the solids concentration of the circulating liquid is maintained approximately constant within a range between 35 wt.
    Type: Grant
    Filed: October 28, 1994
    Date of Patent: September 26, 1995
    Assignee: Herberts Gesellschaft mit Beschrankter Haftung
    Inventors: Dietrich Saatweber, Waltraud Krumm, Bernhard Richter, Dirk Holfter
  • Patent number: 5426151
    Abstract: A polymeric coating agent which comprises a polymer of from 60 to 97 wt. % of one or more (meth)acrylic monomers the polymerization of which can be initiated by free radicals, from 3 to 40 wt. % of at least one .alpha., .omega.-hydroxy-, carboxy-, and/or epoxy-functional polysiloxanes of the formula (I) ##STR1## wherein R' can be the same or different and is C.sub.1-6 alkyl, and R can be the same or different and is ##STR2## wherein Alk and Alk' are C.sub.1-6 alkylene and the alkylene groups in a molecule can be the same or different, n is a cardinal number from 8 to 40, m is a cardinal number from 2 to 30, and p is a cardinal number from 1 to 20 of solids in the monomers.
    Type: Grant
    Filed: November 17, 1993
    Date of Patent: June 20, 1995
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Lutz Brandt, Carmen Flosbach, Reinhardt Kalus, Walter Schubert
  • Patent number: 5425970
    Abstract: A process is described for the production of multi-coat lacquer coatings in which at least one heat-curable clear lacquer coat is applied onto a substrate provided with a pigmented base lacquer coat and is thermally cured, on top of which is applied a further clear lacquer coat based on radiation-curable coating compositions and this is cured by the action of actinic radiation. Lacquer coatings of particularly good optical quality are obtained.
    Type: Grant
    Filed: May 6, 1993
    Date of Patent: June 20, 1995
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Edgar Lahrmann, Stefan Drueke
  • Patent number: 5426156
    Abstract: Previous two-component coatings with enamine components cured very slowly at low temperatures and led to yellowed products. A binder composition is prepared which cures rapidly at low temperatures and leads to non-yellowing products. It contains as CH-acid component a polymer with at least two enamine functions in the molecule, obtained byA) transesterification of a .beta.-keto-ester with hydroxyl-group-containing compounds or polymers which contain at least two hydroxyl groups in the molecule, with an OH value of at least 50 and a number-average molecular weight of 500 to 10,000, followed by reaction with ammonia or primary and/or secondary amines, andB) as .alpha.,.beta.-unsaturated component a compound with at least two groups of the general formula R.sub.1 R.sub.2 C.dbd.CR.sub.3 --X; in which X signifies --CO-- which is bonded via the residue of a di- or polyhydric alcohol, a di- or polyamine or an aminoalcohol to a further R.sub.1 R.sub.2 C.dbd.CR.sub.3 --X group, where R.sub.1, R.sub.2 and R.sub.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: June 20, 1995
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Klaus Bederke, Hermann Kerber, Walter Schubert, Gerhard Bremer, Thomas Brock, Fritz Sadowski
  • Patent number: 5412000
    Abstract: A coating and primer composition suitable as a primer for plastics such as a polyolefin which comprises: a) from about 1 to 5% by weight of ethylene/vinyl acetate copolymers, b) from about 0.5 to 5% by weight of chlorinated polyolefins, c) from about 0.01 to 5% by weight of an epoxy resin; and d) from about 85 to 98.49% by weight of an organic solvent, and optionally paint auxiliaries, pigments and/or fillers.A method of priming plastic surfaces of an object, especially polyolefins, and particularly polypropylene, is also provided which comprises applying the aforesaid composition to a plastic surface and drying the same prior to applying paint or finish coating.
    Type: Grant
    Filed: March 17, 1994
    Date of Patent: May 2, 1995
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Udo Hellmann, Werner Stephan, Fritz Sadowski
  • Patent number: 5401795
    Abstract: The description relates to a physically drying water-based coating agent. It contains water, pigments, neutralizing agents, conventional additives, small proportions of solvents and a binder mixture consisting ofA) 10 to 90 wt. % polyurethanes with carbonate groupings and a glass transition temperature of <0.degree. C. based on reaction products of polyisocyanates with polyhydroxyl compounds, with a content of polyhydroxy polycarbonates andB) 90 to 10 wt. % of reaction products of carboxy-functional polycondensates and .alpha.,.beta.-olefinically unsaturated monomers with a glass transition temperature of >0.degree. C. in the form of an aqueous dispersion.The coating agent is particularly suitable for manufacturing lacquers for repairs in the motor vehicle sector.
    Type: Grant
    Filed: April 19, 1993
    Date of Patent: March 28, 1995
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Thomas Brock, Hans-Peter Patzschke, Fritz Sadowski
  • Patent number: 5399383
    Abstract: A process for priming of plastic substrates without adverse effects on the mechanical stability by applying to a plastic substrate, particularly a polyolefin substrate, a coating composition which comprises from 10 to 35% by weight of binders having an OH number of from 40 to 150, prepared from (meth)acrylamides, hydroxyalkyl (meth) acrylates and copolymerisable, olefinically unsaturated compounds with subsequent modification by means of polyisocyanates, up to 20% by weight of further binders, from 30 to 70% by weight of organic solvents, from 15 to 45% by weight of pigments and/or fillers, from 0 to 15% by weight of additives and from 1 to 30% by weight of epoxide- or polyisocyanate-based crosslinking agents.
    Type: Grant
    Filed: February 16, 1994
    Date of Patent: March 21, 1995
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Manfred Mass, Klaus Bederke, Hermann Kerber
  • Patent number: 5391620
    Abstract: A rheology-influencing agent for coating media, containing a mixture of a (meth)acrylic copolymer containing hydroxyl groups and/or one or more polyesters containing hydroxyl groups, a hydroxy functional microdispersion obtainable by preparing a solution of one or more film-forming polyesters containing hydroxyl and/or carboxyl groups and/or (meth)acrylic copolymers containing hydroxyl and/or carboxyl groups, the foregoing mixture being reacted with a diisocyanate, and an aliphatic primary monoamine.
    Type: Grant
    Filed: October 20, 1993
    Date of Patent: February 21, 1995
    Assignee: Herberts Gesellschaft Mit Beschrankter Haftung
    Inventors: Klaus Bederke, Ralf Dahm, Hermann Kerber, Walter Schubert, Friedrich Hermann, Heinz-Walter Reifferscheidt
  • Patent number: 5389406
    Abstract: A process is described for producing multilayer coatings in which a first coating layer of a first aqueous coating medium is applied to an electrically conducting substrate by electrophoretic deposition, is provided wet-in-wet with a second coating layer of a second aqueous coating medium, followed by joint stoving, wherein a coating medium based on one or more vehicles stabilised by ionic groups and which crosslink on stoving with the formation of urethane groups is used for the second coating layer, and the coating media are selected so that the maximum pigment/vehicle weight ratio of the first coating medium is 1:1, that the ratio of the pigment/vehicle weight ratio of the first coating medium to that of the second coating medium is up to 1.
    Type: Grant
    Filed: October 14, 1993
    Date of Patent: February 14, 1995
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Klaus-Peter Doebler, Wolfgang Goldner, Matthias Kimpel, Klausjorg Klein
  • Patent number: 5381918
    Abstract: Device for securing the lid of a can, in particular a can of paint, against opening when this is not desired, with a surface at the upper end and a peripheral side wall forming a hollow body and consisting of two sections with different diameters, and with a projection arranged at a distance from the upper end of the device and on the inside of the first section of the side wall, which projection is designed so as to be largely peripheral.
    Type: Grant
    Filed: December 10, 1993
    Date of Patent: January 17, 1995
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventor: Jurgen Dahl
  • Patent number: 5219957
    Abstract: Vehicles, which are water dilutable after neutralization with bases, have an acid number of 5 to 60 and are obtainable by polymerization or copolymerization of 10 to 90 parts by weight of one or several acidic, phosphoric acid-functional unsaturated monomers, which are polymerizable by a free radical mechanism and can be present in admixture with one or several ethylenically unsaturated monomers, which are also polymerizable by a free radical mechanism, with addition of a free radical initiator, in the presence of 90 to 10 parts by weight of one or several epoxide resins or modified epoxide resins, in one or several solvents. Methods of synthesizing them, aqueous coating materials containing them and their use.
    Type: Grant
    Filed: June 14, 1991
    Date of Patent: June 15, 1993
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Hans-Peter Patzschke, Joachim Blum, Gerhard Friederichs, Wolfgang Bogdan, deceased
  • Patent number: 5176804
    Abstract: 1 Process for producing a catalyst paste for cathodically separable electrophoretic dipping lacquers.2.1 Use was made of dibutyltin oxide by way of a catalyst paste for electrophoretic dipping lacquers, dispersed in pasting binders. An object is to provide a new process for producing such catalyst pastes while saving time and energy.2.2 A process is provided for producing a catalyst paste for cathodically separable electrophoretic dipping lacquers, wherein the dibutyltin oxide is first pre-dispersed with an organic solvent and an organic acid such as is commonly used for neutralizing cathodically separable electrophoretic dipping lacquers, whereupon it is dispersed with the pasting binder and water and ground.2.3 Cathodic electrophoretic dip lacquering making use of catalyst pastes containing dibutyltin oxide.
    Type: Grant
    Filed: December 5, 1990
    Date of Patent: January 5, 1993
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Gabriele Buttner, Norbert David, Klausjorg Klein
  • Patent number: 5136004
    Abstract: The invention concerns a binder suitable for clear or pigmented coating agents. Binders based on copolymers containing hydroxyl groups have hitherto a high solvent content. The solids content of the new binders is improved without affecting the viscosity; gloss, body, flow and processing properties of coatings containing the new binders are improved. The binders consist essentially of a copolymer containing hydroxyl groups, made from specific quantities of styrol, tertbutacrylate, isobutyl methacrylate, 2-ethylhexyl methacrylate, 2-hydroxypropyl methacrylate, butanediol-1, 4-monoacrylate, acrylic acid and glycidyl esters of .alpha.-alkylalkane monocarboxylic acids and/or .alpha.,.alpha.-dialkylalkane monocarboxylic acids.
    Type: Grant
    Filed: November 13, 1990
    Date of Patent: August 4, 1992
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Klaus Bederke, Hermann Kerber, Manfred Krumme, Fritz Sadowski, Werner Stephan
  • Patent number: 5109040
    Abstract: Aqueous cathodic electrodeposition lacquer coating compositions are provided which comprise (A) certain water soluble synthetic resin binders containing amino groups; (B) crosslinking reagents which react with resin (A), and (C) certain soluble or insoluble transesterification catalysts for the crosslinking reagents. Methods of forming baked finish coatings which are cathodically deposited on electrically conductive surfaces using the lacquer coatings are also disclosed.
    Type: Grant
    Filed: March 21, 1990
    Date of Patent: April 28, 1992
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Helmut Honig, Kurt E. Jaeger, Klausjorg Klein, Dietrich Saatweber
  • Patent number: 5098537
    Abstract: Aqueous electrodeposition coating baths containing cathodically depositable binders and having a content of homopolymers or copolymers of an alkyl vinyl ether, characterized in that the baths contain the following surface-improving additives:0.1 to 5 wt. % of one or more homopolymers or copolymers of an alkyl vinyl ether with 1 to 5 carbon atoms in the alkyl radical and having a weight average molecular weight of 500 to 10000, together with0.1 to 2 wt. % of one or more polyesters comprising .beta.-hydroxyalkyl ester groups, with an acid number of 0 to 3 and a weight average molecular weight of 1000 to 10000,the percentages by weight relating to the solids in the binders, and the proportions by weight of alkyl vinyl ether homopolymers or copolymers to polyester being in the ratio 1:10 to 10:1, relative in each case to the resin solids.
    Type: Grant
    Filed: June 4, 1991
    Date of Patent: March 24, 1992
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Johann Hirtl, Heinz-Peter Katzmann, Klausjorg Klein
  • Patent number: 5021502
    Abstract: An aqueous electrodeposition lacquer coating composition containing as binder(A) from 95 to 50% by weight of an organic externally crosslinkable synthetic resin binder containing primary and/or secondary hydroxyl groups and primary, secondary and/or tertiary amino groups and(B) from 5 to 50% by weight of a crosslinking agent mixture of(a) blocked isocyanates and(b) transesterifiable crosslinking agents containing more than two ester groups and(c) optionally up to 30% by weight of hydroxyfunctional resins.The invention also relates to the use of this electrodeposition coating composition for coating objects, particularly objects having electrically conductive surfaces.
    Type: Grant
    Filed: January 10, 1990
    Date of Patent: June 4, 1991
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Hans-Peter Patzschke, Peter W. Cerny, Dietrich Saatweber, Georg H. L. Hendrikx
  • Patent number: 4943359
    Abstract: Aqueous, heat-curable coating material, containing as vehicle 85 to 40 weight percent of a mixture of a fatty acid-free, acidic epoxide resin phosphate ester with an acid number of 10 to 150, prepared from an epoxide group-containing polyglycidyl ether and/or a polyglycidyl methacrylate resin with more than 1.3 epoxide groups per molecule and an epoxide equivalent weight of 180 to 5,000 and a phenolic resin-modified, carboxyl group-containing, oil-free polyester with an acid number of 15 to 175 and an OH number of 15 to 175, 0 to 25 weight percent of an epoxide resin graft copolymer with an acid number of 30 to 200, prepared from an epoxide group-free reaction product of fatty acid-free polyglycidyl ethers with more than 1.3 epoxide groups per molecule and an epoxide equivalent weight of 1,000 to 5,000 with .alpha.,.beta.
    Type: Grant
    Filed: April 6, 1988
    Date of Patent: July 24, 1990
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Hans-Peter Patzschke, Albrecht Luttenberg, Hans-Jurgen Schlinsog, Wolfgang Bogdan
  • Patent number: 4865705
    Abstract: A non-autocrosslinking binder composition for water dilutable lacquers is described, containing from 95 to 50 parts by weight of a water dilutable poly(meth)acrylate resin containing amino and hydroxyl groups and from 5 to 50% by weight of crosslinking agents is described. An aqueous electrodip lacquer coating composition capable of being deposited at the cathode and its use for coating articles having an electrically conductive surface at the cathode are also described.
    Type: Grant
    Filed: August 18, 1987
    Date of Patent: September 12, 1989
    Assignee: Herberts Gesellschaft mit beschrankter Haftung
    Inventors: Georg Hendrikx, Hans-Peter Patzschke, Armin Gobel
  • Patent number: 4865704
    Abstract: A non-autocrosslinking binder composition for water-dilutable lacquers containing 1 to 99% by weight of a hydroxyl group-containing and amino group-containing epoxide resin and 99 to 1% by weight of an amino groupcontaining synthetic resin binder prepared from free radically polymerizable monomers is described. Aqueous electrodip lacquer coatings containing this binder composition and capable of being deposited at the cathode and their use for coating articles having an electrically conductive surface at the cathode are also described.
    Type: Grant
    Filed: August 18, 1987
    Date of Patent: September 12, 1989
    Assignee: Herberts Gesellschaft mit Beschrankter Haftung
    Inventors: Dietrich Saatweber, Hans-Peter Patzschke, Georg Hendrikx, Klausjorg Klein
  • Patent number: 4851460
    Abstract: An aqueous coating composition is described, containing, as binder, a mixture of (A) 50 to 95% by weight of a reaction product of a carboxy functional polycondensate containing epoxy groups, at least one copolymerisable o,-olefinically unsaturated monomer and conventional auxiliary agents, and (B) 50 to 5% by weight of a polyurethane dispersion, optionally together with a grinding resin. The process for the preparation of the aqueous coating compound and its use for the formation of coatings are also described.
    Type: Grant
    Filed: August 18, 1987
    Date of Patent: July 25, 1989
    Assignee: Herberts Gesellschaft mit Beschrankter Haftung
    Inventors: Dieter Stranghoner, Hans-Peter Patzschke, Christa Luhmann