Patents Assigned to Hexcel Composites Limited
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Publication number: 20240262790Abstract: Bisorthohydroxy aromatic urones and their use as curatives and cure accelerators in resin systems particularly epoxy resin systems provide formulations with good outlife, low curing temperatures and desirable glass transition temperatures after curing, they are particularly useful in prepregs used in the production of components for the aerospace and wind turbine industries.Type: ApplicationFiled: August 21, 2021Publication date: August 8, 2024Applicant: HEXCEL COMPOSITES LIMITEDInventor: Christopher MASON
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Publication number: 20240158627Abstract: There is provided a resin composition for producing a composite part, comprising: a) from 30 to 90 wt % by weight of the composition of an epoxy resin component; and b) from 5 to 50 wt % by weight of the composition of a curative component; wherein the epoxy resin component comprises N,N,N?,N?-tetraglycidyl-4,4?-diamino-3,3?-dimethyldiphenylmethane (M-TGDDM) in an amount of at least 30 wt % by weight of the epoxy resin component; and further wherein the curative component comprises one or more of a diaminodiphenyl sulfone, a diaminobenzophenone, a fluorene diamine, a methylene bis aniline, including hybrid methylene bis anilines, or a substituted diamine toluene. There is also provided the use of N,N,N?,N?-tetraglycidyl-4,4?-diamino-3,3?-dimethyldiphenylmethane (M-TGDDM) as a compression performance improving additive in a resin composition for producing a composite part.Type: ApplicationFiled: September 22, 2020Publication date: May 16, 2024Applicant: HEXCEL COMPOSITES LIMITEDInventors: Martin Richard SIMMONS, Scott THOMPSON, Stephen MORTIMER
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Patent number: 11939421Abstract: A curative system comprising a combination of adipic acid dihydrazide and/or isophthalic dihydrazide and a clathrate in which the guest compound of the clathrate comprises an imidazole, an imidazoline or diazabicycloalkanes (DBCA).Type: GrantFiled: August 30, 2019Date of Patent: March 26, 2024Assignee: HEXCEL COMPOSITES LIMITEDInventors: Christopher Robert Mason, Nicholas Verge
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Patent number: 11879052Abstract: The host compound in a clathrate is an amino or hydroxyl containing aromatic phosphorous compound, clathrates containing a resin curative and their use in curable resin compositions to produce moulded articles particularly fibre reinforced articles.Type: GrantFiled: April 17, 2020Date of Patent: January 23, 2024Assignee: HEXCEL COMPOSITES LIMITEDInventor: Christopher Robert Mason
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Patent number: 11873422Abstract: An adhesive composition comprising a silane-modified epoxy resin, a dicyclopentadiene novolac epoxy resin and a curing agent. The composition shows good oily steel bonding, even in the absence of CTBN rubber or rubber adducts as toughening agents, with good Tg values of the cured resin and good Tg retention after hot wet aging.Type: GrantFiled: December 3, 2019Date of Patent: January 16, 2024Assignee: HEXCEL COMPOSITES LIMITEDInventor: Michael Rhodes
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Patent number: 11702516Abstract: This invention relates to a curative composition and its use in curing epoxy resins and prepregs, adhesives and moulded materials derived therefrom. The curative composition comprises a clathrate comprising a host component and a guest component, the host comprising a carboxylic acid or ester compounds as defined or phenolphthalin and the guest comprising an imidazole or imidazoline component.Type: GrantFiled: December 20, 2018Date of Patent: July 18, 2023Assignee: HEXCEL COMPOSITES LIMITEDInventors: David Allan Tilbrook, Christopher Robert Mason, Martin Richard Simmons
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Patent number: 11697254Abstract: An assembly (113) for composite manufacture is provided. The assembly comprises a cured resin impregnated reinforcement material (112) comprising a fibre component and a resin matrix component, in which the resin matrix component comprises polyurethane, the assembly having a length to width ratio of at least 5:1, and the assembly defining a longitudinal direction (L) along its length; and a peel ply (116) in contact with the cured resin impregnated reinforcement material (112), the peel ply (116) comprising a woven layer having a plurality of longitudinal fibres (118) extending in the longitudinal direction (L); and a plurality of transverse fibres (120) extending in a transverse direction (T) normal to the longitudinal direction (L); in which the areal density of the plurality of transverse fibres (120) is higher than the areal density of the plurality of longitudinal fibres (118).Type: GrantFiled: April 2, 2020Date of Patent: July 11, 2023Assignees: Hexcel Composites Limited, Hexcel Corporation, Hexcel Holding GmbHInventors: Johannes Moser, Yu-Chen Hung, Erin Reagan
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Patent number: 11680144Abstract: A self-adhesive prepreg comprising a fibre reinforcement layer having a first side and a second side, wherein the first side of the fibre reinforcement layer has been pre-impregnated with a self-adhesive resin composition. The self-adhesive may be used as a structural reinforcement and is especially adapted for direct bonding to oily steel or galvanized steel in the automotive, aerospace and other sheet metal fabrication industries.Type: GrantFiled: April 17, 2020Date of Patent: June 20, 2023Assignee: HEXCEL COMPOSITES LIMITEDInventor: Michael Rhodes
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Publication number: 20230167272Abstract: The host compound in a clathrate is an amino or hydroxyl containing aromatic phosphorous compound, clathrates containing a resin curative and their use in curable resin compositions to produce moulded articles particularly fibre reinforced articles.Type: ApplicationFiled: April 17, 2020Publication date: June 1, 2023Applicant: HEXCEL COMPOSITES LIMITEDInventor: Christopher Robert MASON
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Publication number: 20220388274Abstract: The present invention is concerned with a moulding material comprising: a) A primary non-woven fibre layer; b) A secondary non-woven fibre layer, and c) A resin layer; wherein the resin layer bonds the secondary non-woven fibre layer to a first surface of the primary non-woven fibre layer, and the resin layer is exposed on the second surface of the primary non-woven layer.Type: ApplicationFiled: September 23, 2020Publication date: December 8, 2022Applicant: HEXCEL COMPOSITES LIMITEDInventor: Mark WHITER
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Publication number: 20220289924Abstract: A moulding material which comprises: (a) a structural reinforcement layer comprising a fibrous reinforcement material optionally in combination with a second resin composition; and (b) a surface enhancing layer, for contacting a surface of a mould or tool, comprising a first non-woven fibre carrier in combination with a first resin composition containing a rheology modifier and a curing agent, wherein the first resin composition provides an external mould or tool-contacting surface of the moulding material. The moulding material can be cured to form a moulded article having a high quality surface finish that requires minimal preparation before painting and/or application in its intended use. The moulded article may be provided with sacrificial discontinuous indicator means to assist in uniform removal of a part of the surface enhancing layer of the moulded article for specific applications.Type: ApplicationFiled: September 23, 2020Publication date: September 15, 2022Applicant: HEXCEL COMPOSITES LIMITEDInventor: Mark WHITER
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Publication number: 20220267543Abstract: A prepreg or semipreg precursor comprising a fibre reinforcement and a resin composition fused thereto, the resin composition containing at least one epoxy resin and a latent curing agent, wherein the epoxy resin and the latent curing agent form a solid phase at ambient temperature, the latent curing agent forming a discrete phase within the epoxy resin. The stabilized uncured resin composition and prepregs and semipregs incorporating the same are easy to handle, have desirable curing temperatures and show good outlife at ambient to mid range temperatures.Type: ApplicationFiled: July 19, 2020Publication date: August 25, 2022Applicant: HEXCEL COMPOSITES LIMITEDInventors: Mark WHITER, Ben TIPLER, Mathilde MAILLOT
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Publication number: 20220212424Abstract: An assembly (113) for composite manufacture is provided. The assembly comprises a cured resin impregnated reinforcement material (112) comprising a fibre component and a resin matrix component, in which the resin matrix component comprises polyurethane, the assembly having a length to width ratio of at least 5:1, and the assembly defining a longitudinal direction (L) along its length; and a peel ply (116) in contact with the cured resin impregnated reinforcement material (112), the peel ply (116) comprising a woven layer having a plurality of longitudinal fibres (118) extending in the longitudinal direction (L); and a plurality of transverse fibres (120) extending in a transverse direction (T) normal to the longitudinal direction (L); in which the areal density of the plurality of transverse fibres (120) is higher than the areal density of the plurality of longitudinal fibres (118).Type: ApplicationFiled: April 2, 2020Publication date: July 7, 2022Applicants: Hexcel Composites Limited, Hexcel Holding GMBH, Hexcel CorporationInventors: Johannes MOSER, Yu-Chen HUNG, Erin REAGAN
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Publication number: 20220213285Abstract: A self-adhesive prepreg comprising a fibre reinforcement layer having a first side and a second side, wherein the first side of the fibre reinforcement layer has been pre-impregnated with a self-adhesive resin composition. The self-adhesive may be used as a structural reinforcement and is especially adapted for direct bonding to oily steel or galvanized steel in the automotive, aerospace and other sheet metal fabrication industries.Type: ApplicationFiled: April 17, 2020Publication date: July 7, 2022Applicant: HEXCEL COMPOSITES LIMITEDInventor: Michael RHODES
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Patent number: 11358828Abstract: There is provide a process for unwinding material from a spool (2) wherein the angle (?) of take off at the first contact point (4) for the unwind is always in the range 0±20°, and wherein the first contact point (4) for the unwind is no more than 600 mm from the axis (3) of rotation of the spool (2). There is also provided an apparatus for the unwinding of material from a spool (2) comprising an axis (3) upon which a spool (2) may be rotatably mounted and a static first contact point (4) for the unwound material positioned no more than 600 mm from the centre of the axis (3), wherein the angle (?) of take off at the first contact point (4) for the unwind is always in the range 0±20°.Type: GrantFiled: October 18, 2018Date of Patent: June 14, 2022Assignees: HEXCEL COMPOSITES LIMITED, HEXCEL CORPORATIONInventors: John Ellis, Anthony Loccisano
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Patent number: 11358349Abstract: A method of manufacture of a composite component is provided, the method comprising the steps of providing two layers of pre-preg composite material, one of which has an edge adjacent a surface of the other. Pressure and, optionally, vibrational energy is applied to the edge to thereby smooth the ply drop.Type: GrantFiled: November 8, 2019Date of Patent: June 14, 2022Assignee: HEXCEL COMPOSITES LIMITEDInventor: Marco Arcidiacono
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Patent number: 11332607Abstract: Formulations comprising from 10 to 80% by weight of the formulation of a halogenated epoxy resin; from 1 to 15% by weight of the formulation of an antimony based fire retardant; from 1 to 10% by weight of the formulation of an inorganic or non-polymeric organic phosphorous containing fire retardant; and from 1 to 30% by weight of the formulation of a curative system are provided. The formulations are particularly suitable for producing aircraft interior composite components having good fire retarding properties, low smoke emission, low smoke toxicity and low heat release properties. The formulations also have excellent processing and mechanical properties. Further components may be included in the compositions to improve various properties, including the fire retarding, low smoke emission, low smoke toxicity and low heat release properties and to also further improve the processing and mechanical properties, including toughness.Type: GrantFiled: June 13, 2019Date of Patent: May 17, 2022Assignee: HEXCEL COMPOSITES LIMITEDInventor: Dana Blair
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Publication number: 20220017797Abstract: An adhesive composition comprising a silane-modified epoxy resin, a dicyclopentadiene novolac epoxy resin and a curing agent. The composition shows good oily steel bonding, even in the absence of CTBN rubber or rubber adducts as toughening agents, with good Tg values of the cured resin and good Tg retention after hot wet aging.Type: ApplicationFiled: December 3, 2019Publication date: January 20, 2022Applicant: HEXCEL COMPOSITES LIMITEDInventor: Michael RHODES
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Publication number: 20220009183Abstract: A method of manufacture of a composite component is provided, the method comprising the steps of providing two layers of pre-preg composite material, one of which has an edge adjacent a surface of the other. Pressure and, optionally, vibrational energy is applied to the edge to thereby smooth the ply drop.Type: ApplicationFiled: November 8, 2019Publication date: January 13, 2022Applicant: HEXCEL COMPOSITES LIMITEDInventor: Marco ARCIDIACONO
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Publication number: 20210246276Abstract: A curative resin containing at least 50 wt % of an epoxy phenolic resin comprising a mixture of a carboxylic hydrazide and a hydroxy substituted urone.Type: ApplicationFiled: May 17, 2019Publication date: August 12, 2021Applicants: HEXCEL COMPOSITES LIMITED, HEXCEL HOLDING GMBHInventors: Nicholas VERGE, Thorsten GANGLBERGER