Patents Assigned to Hexion Inc.
  • Patent number: 10119046
    Abstract: Compositions, methods, and coating composition using a curing agent are provided herein. In one embodiment, a curing agent for epoxy resins may be prepared using a formulation including: (a) an adduct of: (i) a diglycidyl ether of a bisphenol, and (ii) a first polyamine; (b) a second polyamine; and (c) water; wherein the composition has an amine hydrogen equivalent weight, based on solids, of less than or equal to 105.
    Type: Grant
    Filed: December 16, 2016
    Date of Patent: November 6, 2018
    Assignee: HEXION INC.
    Inventors: David Flosser, Patricia Garcia, Larry Steven Corley, Bedri Erdem, Lucy Phan
  • Patent number: 10118905
    Abstract: Triazine-arylhydroxy-aldehyde condensates are reacted with at least one alkylene carbonate to form alkoxylated triazine-arylhydroxy-aldehyde condensates.
    Type: Grant
    Filed: September 22, 2017
    Date of Patent: November 6, 2018
    Assignee: Hexion Inc.
    Inventors: Ganapathy Viswanathan, Anthony Maiorana, Stephan Schröter, Pravin Kukkala
  • Patent number: 10040914
    Abstract: Compositions and methods for forming epoxy resin are provided, and compositions and methods for forming epoxy resin composites are provided. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component comprising a glycidyl ether of an aryl substituted phenolic compound, a curing agent component, and a substrate. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component and a curing agent component comprising an aryl substituted phenolic compound, and a substrate.
    Type: Grant
    Filed: October 27, 2016
    Date of Patent: August 7, 2018
    Assignee: HEXION INC.
    Inventors: Larry Steven Corley, Robert Dale Farris, Carlton E. Ash
  • Patent number: 10040896
    Abstract: Compositions comprising Silane functionalized compounds are provided. In one embodiment, the silane functionalized compounds include an epoxy resin derived backbone having silane functional groups pendant to the backbone or serving as end caps. The compositions comprising silane functionalized compounds may be utilized in a variety of applications including in coating formulations, adhesive formulations, composite materials, and combinations thereof.
    Type: Grant
    Filed: September 23, 2015
    Date of Patent: August 7, 2018
    Assignees: HEXION, INC., MOMENTIVE PERFORMANCE MATERIALS INC.
    Inventors: Antonina Nikitenko, Matthew Pinnow, Amitabh Bansal
  • Patent number: 10017688
    Abstract: Proppant materials, and methods for making proppant materials, are provided. In one embodiment, the proppant material comprises a substrate material, a polymeric material disposed on the substrate material, a surface wettability modifier disposed on the polymeric material, and a surfactant material disposed on the surface wettability modifier. A consolidation material may also be disposed on the polymeric material or formed as part of the polymeric material.
    Type: Grant
    Filed: July 24, 2015
    Date of Patent: July 10, 2018
    Assignee: HEXION INC.
    Inventors: John W. Green, Silje V. Nordas, Mark D. Leatherman
  • Patent number: 9957410
    Abstract: The invention relates to a coated reinforcement, to a method for producing the same and to the use thereof. In order to provide a coated reinforcement, in particular to be used for large surface area components, the coating of which can be applied easily and without difficultly substantially independently of the processing-relevant properties of the components of the resin mixture, it is proposed that the surface of the reinforcement has a coating made of a composition, the composition contains a mixture 1 of at least one resin, selected from the group consisting of epoxidized phenol novolacs, epoxidized cresol novolacs, polyepoxides based on bisphenol A, epoxidized fluorenone bisphenols and/or polyepoxides bases on bisphenol-F, and/or based on triglycidyl isocyanurates, epoxidized novolac and at least one component that accelerates the curing of the resin, and said mixture is subjected to a heat treatment, so that the mixture 1 is affixed to the surface of the reinforcement by fusing it thereon.
    Type: Grant
    Filed: November 25, 2009
    Date of Patent: May 1, 2018
    Assignee: HEXION INC.
    Inventor: Christoph Scheuer
  • Patent number: 9920161
    Abstract: Compositions and methods for forming epoxy resin systems are provided. In one embodiment, a composition is provided for an epoxy resin system including a reaction product of an epoxy resin component and a curing agent component comprising a first amine compound having the formula R1R2R3N, wherein R1 and R2 are independently an aliphatic or alicyclic organic functional group and R3 is an alkyl group, having a backbone of 2-18 carbon atoms, and a second amine compound having one or more primary or secondary amine groups, with the stoichiometic ratio of —NH bonds of the second amine compound to the epoxy groups of the epoxy resin component being from 1:20 to about 21:20. The composition may be used to form composites, such as used in commercial wind turbine blade manufacturing.
    Type: Grant
    Filed: August 10, 2017
    Date of Patent: March 20, 2018
    Assignee: Hexion Inc.
    Inventors: Larry Steven Corley, Robert D. Farris, Carlton E. Ash
  • Patent number: 9879515
    Abstract: Proppant materials, and methods for making proppant materials, are provided. In one embodiment, the proppant material comprises a substrate material, a polymeric material disposed on the substrate material and a surface wettability modifier disposed on the polymeric material. Methods of making and using the proppant materials are also disclosed.
    Type: Grant
    Filed: September 26, 2012
    Date of Patent: January 30, 2018
    Assignee: HEXION INC.
    Inventors: John William Green, John Mario Terracina, Jerry Francis Borges, Scott Edward Spillars, Samantha Huixian Mah
  • Patent number: 9879113
    Abstract: The invention relates to compositions of ?,?-branched alkane carboxylic acids glycidyl esters with a define isomeric composition where the sum of the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75% on total composition.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: January 30, 2018
    Assignee: HEXION INC.
    Inventors: Christophe Steinbrecher, Cedric Le Fevere De Ten Hove, Robert Van't Sand, Denis Heymans, Aleksandra Joanna Kotlewska
  • Patent number: 9840588
    Abstract: Disclosed are epoxy resins exhibiting a highly favorable combination of tensile strength and elongation with respect to prior art epoxy systems. The elastomeric epoxy resin systems of the invention are prepared utilizing a curing agent containing at least one monoprimary amine, and are particularly useful in applications such as, for example, castings, potting, composites, crack sealing, coatings, adhesives, roofing materials, flooring or reinforced membranes.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: December 12, 2017
    Assignee: HEXION INC.
    Inventors: Larry Steven Corley, Carlton E. Ash
  • Patent number: 9803051
    Abstract: The invention relates to compositions of hydroxyl functional acrylic resins (acrylic polyols) comprising a mixture of ?,?-branched alkane carboxylic glycidyl esters derived from butene oligomers characterized in that the sum of the concentration of the blocked and of the highly branched isomers is at least 50%, preferably above 60% and most preferably above 75% on total composition.
    Type: Grant
    Filed: October 16, 2012
    Date of Patent: October 31, 2017
    Assignee: HEXION INC.
    Inventors: Denis Heymans, Christophe Steinbrecher, Cédric Le Fevere De Ten Hove
  • Patent number: 9790313
    Abstract: Disclosed are curing compositions for resin systems and in particular for phenolic resin systems and epoxy resin systems, to methods of preparing the curing compositions and to resin systems incorporating same. The curing compositions of the invention are the reaction product of an aldehyde with an amine in the presence of an aprotic solvent.
    Type: Grant
    Filed: August 20, 2015
    Date of Patent: October 17, 2017
    Assignee: HEXION INC.
    Inventors: Ganapathy S. Viswanathan, Craig M. Zirkle
  • Patent number: 9783709
    Abstract: The invention relates to a process for the manufacture of ?,?-branched carboxylic acids vinyl esters comprising the following steps: isomerising and converting an olefin feed with CO and water under Koch reaction conditions to make an acid with a ratio of Non Blocking isomers (NB) versus Blocking isomers (B) of NB/B above 1.5, wherein a blocking isomer has always a tertiary carbon atom in alpha position of the carboxylic acid and in the beta position of the carboxylic acid, whereas a non-blocking isomer has primary carbon atoms in the beta position of the carboxylic acid converting the resulting acid into a vinyl ester.
    Type: Grant
    Filed: January 6, 2016
    Date of Patent: October 10, 2017
    Assignee: HEXION INC.
    Inventor: Denis Heymans
  • Patent number: 9751973
    Abstract: Compositions and methods for forming epoxy resin systems are provided. In one embodiment, a composition is provided for an epoxy resin system including a reaction product of an epoxy resin component and a curing agent component comprising a first amine compound having the formula R1R2R3N, wherein R1 and R2 are independently an aliphatic or alicyclic organic functional group and R3 is an alkyl group, having a backbone of 2-18 carbon atoms, and a second amine compound having one or more primary or secondary amine groups, with the stoichiometic ratio of —NH bonds of the second amine compound to the epoxy groups of the epoxy resin component being from 1:20 to about 21:20. The composition may be used to form composites, such as used in commercial wind turbine blade manufacturing.
    Type: Grant
    Filed: March 3, 2016
    Date of Patent: September 5, 2017
    Assignee: HEXION INC.
    Inventors: Larry Steven Corley, Robert D. Farris, Carlton E. Ash
  • Patent number: 9751982
    Abstract: The invention relates to compositions of polyether polyol resins (hydroxyfunctional oligo or poly ether) comprising a mixture of ?,?-branched alkane carboxylic glycidyl esters derived from butene oligomers characterized in that the sum of the concentration of the blocked and of the highly branched isomers is maximum 55%, preferably below 40%, and most preferably below 30% weight on total composition.
    Type: Grant
    Filed: October 16, 2012
    Date of Patent: September 5, 2017
    Assignee: HEXION INC
    Inventors: Denis Heymans, Christophe Steinbrecher, Cédric Le Fevere De Ten Hove
  • Patent number: 9708503
    Abstract: An aqueous binder system including a mixture of urea-formaldehyde resin and water-dispersible polyester resin. A combination of the binder system applied to fiber insulation, a composite glass mat, glass/polyester mat, polyester mat, or substrate of a coated abrasive product. Fiber insulation, a composite glass mat, glass/polyester mat, polyester mat, or coated abrasive product with the binder system including urea-formaldehyde resin and water-dispersible polyester.
    Type: Grant
    Filed: May 15, 2015
    Date of Patent: July 18, 2017
    Assignee: HEXION INC.
    Inventors: Jeremiah D. Bear, Gregory D. Briner, Thomas L. McNeal
  • Patent number: 9598580
    Abstract: Polymeric materials and methods for making the polymeric materials utilizing bisphenolic stillbottoms, lignosulfonates, or both are disclosed. In one embodiment, a polymer is provided that includes a condensate of bisphenolic stillbottoms, an optional phenolic compound independent of bisphenolic stillbottoms, an aldehyde, and a lignosulfonate compound. The condensate may further include an amino compound, a catalyst, or combinations thereof. Alternatively, the polymer may be free of a phenolic compound independent of bisphenolic stillbottoms. The polymers may be used in the manufacture of articles including composites, laminates and paper products.
    Type: Grant
    Filed: March 9, 2015
    Date of Patent: March 21, 2017
    Assignee: HEXION INC.
    Inventors: Adam Daniel Dowden, Harden Christopher Wren, Todd Ross Miller
  • Patent number: 9587149
    Abstract: This invention relates to a copolymer composition comprising vinyl ester of 2-ethyl hexanoic acid (VEHA), and particularly to pressure-sensitive adhesive compositions based on VEHA reacted with (meth)acrylate monomers. The present adhesive compositions provide a film with high cohesion and adhesion values, and more particularly to pressure-sensitive adhesive compositions based on VEHA reacted with (meth)acrylate monomers and VeoVa 10. The present adhesive compositions provide a film with high cohesion and adhesion values with Peel on Teflon of at least 2 N/inch.
    Type: Grant
    Filed: May 10, 2012
    Date of Patent: March 7, 2017
    Assignee: HEXION INC.
    Inventors: Nathalie Havaux, François Simal, Olga Kameneva
  • Patent number: 9574152
    Abstract: A diesel fuel and additive mixture is useful for reducing particulate matter emissions while improving or at least not aggravating oxidative stability during combustion. The additive includes at least one compound having a general formula selected from the group consisting of: and combinations thereof, wherein: R is a saturated or unsaturated hydrocarbon having from about 1 to about 6 carbons. The additive is effective in diesel at concentrations as low as from about 50 to about 1000 ppm by weight.
    Type: Grant
    Filed: February 19, 2015
    Date of Patent: February 21, 2017
    Assignee: HEXION INC.
    Inventors: Zhen Lai, Richard R. Jacobson, Gilberto Edson Ferreira Saboia, Carlos Nuila
  • Patent number: 9550894
    Abstract: Polyester materials, methods for making polyesters materials, and uses of the polyester materials in binder materials and articles of manufacture are disclosed. In one embodiment, a process is provided for preparing a polyester solution, including mixing monomers of at least one organic acid containing at least three carboxylic groups and at least one multi-hydroxyl alcohol containing at least three hydroxyl groups to form a reaction mixture, heating the reaction mixture to a first temperature, polymerizing the monomers at the first temperature until reaching an acid value from about 200 to about 400 mg KOH/g, adjusting the temperature to a second temperature less than the first temperature, and forming the polyester solution. The polyester materials may be mixed with cross-linking materials to form binder materials. The binder material may then be used to form articles of manufacture.
    Type: Grant
    Filed: January 30, 2015
    Date of Patent: January 24, 2017
    Assignee: HEXION INC.
    Inventors: Yingchao Zhang, Raman C. Subrayan, Vinay Malhotra, David A. Snover