Patents Assigned to Hexion Specialty Chemicals, Inc.
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Patent number: 7323534Abstract: A composition is disclosed, which comprises a hydroxyaromatic-aldehyde resole resin comprising an aldehyde and a hydroxyaromatic compound, modified with a urea-aldehyde condensate. The composition has improved premix stability, improved cure efficiency, comparable tensile strength, and lower volatiles than the hydroxyaromatic-aldehyde resole resin unmodified with a urea-aldehyde condensate. Also disclosed are articles prepared therefrom.Type: GrantFiled: October 12, 2005Date of Patent: January 29, 2008Assignee: Hexion Specialty Chemicals, Inc.Inventor: Stephen W. Arbuckle
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Patent number: 7294189Abstract: An emulsion comprising water as the continuous phase, a wax as the discontinuous phase, an emulsifier and a preservative having the general structure: wherein R1 can be a heterocycle containing nitrogen and sulfur, such as thiazolyl, isothiazolyl, or thiadiazolyl, which can optionally be substituted with C1–C6 alkyl; R2 can be hydrogen or C1–C6 alkyl, specifically hydrogen; n is 0, 1, 2, or 3; each instance of R3 can independently be hydrogen, C1–C6 alkyl, phenoxy, C1–C6 alkoxy, halo, amino, C1–C6 alkylamino, di C1–C6 alkyl amino, imidazolyl, thiazolyl, isothiazolyl, thiadiazolyl, thienyl, furyl, pyrryl, naphthyl, phenyl, halophenyl, C1–C6 alkyl phenyl, or C1–C6 alkoxyphenyl. The preservative may be added to the emulsion after the emulsion is formed. The emulsion can be incorporated into a gypsum product such as gypsum board or gypsum wood fiber board. The gypsum product may be made by forming a slurry containing gypsum, water, and the emulsion into a solid product.Type: GrantFiled: September 2, 2005Date of Patent: November 13, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventor: Steven Wantling
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Patent number: 7285590Abstract: Aqueous dispersions are disclosed, having a minimum film formation temperature no greater than about 50° C., that include a multi-stage emulsion polymer made by a process that includes a first polymerization stage, in which a first monomer mixture having a calculated glass transition temperature of at least about 50° C. is polymerized via free radical emulsion polymerization to obtain a first-stage emulsion polymer, and a second polymerization stage, in which a second monomer mixture, having a calculated glass transition temperature from about ?30° C. to about 10° C., is polymerized via free radical emulsion polymerization, in the presence of the first-stage emulsion polymer. The dispersions are useful in a variety of coating compositions that exhibit improved block resistance.Type: GrantFiled: November 13, 2003Date of Patent: October 23, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventors: Pavel Holub, Edward Enns McEntire
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Patent number: 7276555Abstract: A method of dispersing pigment using an amide-modified resin or an amide-modified hydrocarbyl moiety, and the resulting pigment concentrate or coating or ink composition.Type: GrantFiled: May 19, 2003Date of Patent: October 2, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventors: Christopher J. Holmes, Richard K. Winblad, Rudolf Anthonius Maria Venderbosch, Richard Hendrikus Gerrit Brinkhuis
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Patent number: 7270879Abstract: Disclosed herein is a particle comprising a particulate substrate; and a thermoplastic elastomer present on or in the substrate as an amount sufficient to improve the dust suppression of the particle above that which would occur if the thermoplastic elastomer was absent. Disclosed herein is a particle comprising a particulate substrate; and a thermoplastic elastomer, wherein the particle has a compressive strength retention of greater than about 50% as measured by a UCS test and a turbidity of about 10 to 200 NTU after a one hour ball mill test.Type: GrantFiled: April 15, 2004Date of Patent: September 18, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventor: Avis Lloyd McCrary
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Patent number: 7262238Abstract: The present invention refers to a resin composition comprising an ester compound and a polymer, wherein the ester compound and the polymer are obtainable by reacting a diene, a dienophile and a carboxylic acid. The invention also refers to adhesive compositions comprising the resin composition.Type: GrantFiled: January 20, 2004Date of Patent: August 28, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventors: Robin Winters, Ivo Maria Johannes Erens, Patrick Peter Mario Aarts, John Hazen
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Patent number: 7262237Abstract: Curable urea formaldehyde binder compositions are provided which are useful in coated abrasive and wood engineering applications, in a time released fashion. The time released curable binder compositions include a urea formaldehyde resin and an aryl phosphite in varying concentrations. The curable binder compositions of the present invention provide desirable working times and faster curing times tinder ambient or near ambient conditions.Type: GrantFiled: June 24, 2004Date of Patent: August 28, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventor: Jimmy Pingao Chen
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Patent number: 7256226Abstract: Storage-stable acrylate-functional alkyd resin compositions are disclosed that include an acrylate-functional alkyd resin and a monofunctional mercaptan such as a chain transfer agent. The compositions disclosed exhibit excellent stability on storage, and have utility as binders for coating compositions useful as low VOC, quick dry paints.Type: GrantFiled: March 15, 2004Date of Patent: August 14, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventors: Thauming Kuo, Kimberley Carmenia Carico, Rebecca Reid Stockl, Don Leon Morris, Kevin Jude O'Callaghan
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Patent number: 7238386Abstract: A method is provided to manufacture a coated substrate, such as an optical fiber, without undesirable point lumps. The method filters a coating composition while controlling the filtering temperature, pressure drop across a filtering assembly, and filter pore size to achieve a resulting filtration factor not greater than 250,000 s?1. The filtration factor is a function of filtering temperature and pressure drop across the filtering assembly. Typically, the coating composition is filtered by passing the coating composition through one or more filters of the filtering assembly, having an absolute pore size rating in the range from approximately 0.05 to approximately 5 microns, at a temperature less than approximately 105° F. (40° C.), and at a pressure drop ?P across the filtering assembly of at most approximately 80 psig, wherein the ratio of pressure drop (mPa) to viscosity (mPa·s), which is dependent upon filtering temperature, minimizes the filtration factor to ?250,000 s?1.Type: GrantFiled: April 23, 2003Date of Patent: July 3, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventors: Gregory Lee Workman, II, Don Leon King, Camille Jeanette Rechel, Timothy Edward Myers
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Patent number: 7189780Abstract: A process to produce an acid-treated aqueous dispersion is provided. The process comprises contacting a polymer, a water dispersible polyester, water, and at least one acid-generating compound; wherein said polymer comprises repeating units from at least one fluoroalkyl monomer and optionally, at least one ethylenically unsaturated monomer; wherein the acid-generating compound is at least one acid or acid salt.Type: GrantFiled: August 12, 2003Date of Patent: March 13, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventors: James Foster Von Schmittou, Darrell Scott Nasser
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Patent number: 7186769Abstract: In this invention, an aqueous dispersion is provided to improve the oil and water repellency of materials. The aqueous dispersion comprises a polymer, at least one water dispersible polyester, and water; wherein the polymer comprises the repeating units from at least one fluoroalkyl monomer and optionally, at least one ethylenically unsaturated monomer. This invention also provides an article coated with the aqueous dispersion.Type: GrantFiled: August 12, 2003Date of Patent: March 6, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventors: James Foster Von Schmittou, Darrell Scott Nasser
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Patent number: 7173081Abstract: A process is provided to produce an aqueous dispersion wherein the aqueous dispersion enhances the water and oil repellency of materials. The process comprises: 1) contacting at least one fluoroalkyl monomer, at least one water-dispersible polyester, water, and optionally an ethylenically unsaturated monomer to form a pre-emulsion; and 2) polymerizing the pre-emulsion in a polymerization zone in the presence of an initiator to produce the aqueous dispersion. In another embodiment, a process to produce an aqueous dispersion is provided. The process comprises: 1) contacting at least one fluoroalkyl monomer, at least one water-dispersible polyester, water, and optionally an ethylenically unsaturated monomer to form a pre-emulsion; 2) shearing the pre-emulsion to produce a mini-emulsion; and 3) polymerizing the miniemulsion in a polymerization zone to produce the aqueous dispersion.Type: GrantFiled: August 12, 2003Date of Patent: February 6, 2007Assignee: Hexion Specialty Chemicals, Inc.Inventors: James Foster Von Schmittou, Darrell Scott Nasser
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Patent number: 7151192Abstract: A manufacturing process for the preparation of ?,?-branched alkane carboxylic acids, by reacting a mono-olefin or a precursor thereof, with carbon monoxide in the presence of a strong acid catalyst characterized in that the starting olefin is a dimmer C8 or trimer C12 derived from n-butene, which predominantly comprise 2-butene, that the acid catalyst is composed of BF3/H3PO4 in a molar ratio of BF3:H3PO4 in the range of from 0.5:1.0 to 5.0:1.0, or of CF3SO 3H, that the weight ratio of the catalyst relative to the mono-olefin is in the range of from 1:1 to 10:1, that the reaction is carried out at a temperature in the range of from 60 to 140° C., and with an initial water content in the catalyst system in the range of from 8 to 25 wt %; and vinyl esters and glycidyl esters derived from said carboxylic acids.Type: GrantFiled: July 2, 2002Date of Patent: December 19, 2006Assignee: Hexion Specialty Chemicals, Inc.Inventors: Hendrik Stichter, Leonardus Petrus, Hans Arie Stil
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Patent number: 7129286Abstract: A process for preparing an acrylic-modified alkyd resin comprising the steps of: d) preparing a sulfonated alkyd resin product; e) preparing an acrylated fatty acid product; and f) reacting the product of step a) and the product of step b) under appropriate polymerization conditions, and for preparing a waterbome composition on the basis thereof as well as products obtainable by those processes.Type: GrantFiled: November 12, 2001Date of Patent: October 31, 2006Assignee: Hexion Specialty Chemicals, Inc.Inventor: Bernd Kuhneweg
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Patent number: 7073586Abstract: A method of treating an underground formation of an oil reservoir, comprising the sequential steps of (a) contacting the formation with an aqueous medium, (b) contacting the underground formation with a hydrocarbon fluid, (c) contacting the underground formation with a solvent in the form of a glycol ether, (d) contacting the underground formation with a first consolidation constituent solution, mainly comprising a poly epoxy resin, (e) contacting the underground formation with second consolidation constituent substantially homogenous solution mainly comprising a curing agent in a solvent.Type: GrantFiled: April 29, 2003Date of Patent: July 11, 2006Assignee: Hexion Specialty Chemicals, Inc.Inventors: Jan Dirk Bossaerts, Marc Jozef Rans