Patents Assigned to Hexion Specialty Chemicals, Inc.
  • Patent number: 7323534
    Abstract: A composition is disclosed, which comprises a hydroxyaromatic-aldehyde resole resin comprising an aldehyde and a hydroxyaromatic compound, modified with a urea-aldehyde condensate. The composition has improved premix stability, improved cure efficiency, comparable tensile strength, and lower volatiles than the hydroxyaromatic-aldehyde resole resin unmodified with a urea-aldehyde condensate. Also disclosed are articles prepared therefrom.
    Type: Grant
    Filed: October 12, 2005
    Date of Patent: January 29, 2008
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventor: Stephen W. Arbuckle
  • Patent number: 7294189
    Abstract: An emulsion comprising water as the continuous phase, a wax as the discontinuous phase, an emulsifier and a preservative having the general structure: wherein R1 can be a heterocycle containing nitrogen and sulfur, such as thiazolyl, isothiazolyl, or thiadiazolyl, which can optionally be substituted with C1–C6 alkyl; R2 can be hydrogen or C1–C6 alkyl, specifically hydrogen; n is 0, 1, 2, or 3; each instance of R3 can independently be hydrogen, C1–C6 alkyl, phenoxy, C1–C6 alkoxy, halo, amino, C1–C6 alkylamino, di C1–C6 alkyl amino, imidazolyl, thiazolyl, isothiazolyl, thiadiazolyl, thienyl, furyl, pyrryl, naphthyl, phenyl, halophenyl, C1–C6 alkyl phenyl, or C1–C6 alkoxyphenyl. The preservative may be added to the emulsion after the emulsion is formed. The emulsion can be incorporated into a gypsum product such as gypsum board or gypsum wood fiber board. The gypsum product may be made by forming a slurry containing gypsum, water, and the emulsion into a solid product.
    Type: Grant
    Filed: September 2, 2005
    Date of Patent: November 13, 2007
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventor: Steven Wantling
  • Patent number: 7285590
    Abstract: Aqueous dispersions are disclosed, having a minimum film formation temperature no greater than about 50° C., that include a multi-stage emulsion polymer made by a process that includes a first polymerization stage, in which a first monomer mixture having a calculated glass transition temperature of at least about 50° C. is polymerized via free radical emulsion polymerization to obtain a first-stage emulsion polymer, and a second polymerization stage, in which a second monomer mixture, having a calculated glass transition temperature from about ?30° C. to about 10° C., is polymerized via free radical emulsion polymerization, in the presence of the first-stage emulsion polymer. The dispersions are useful in a variety of coating compositions that exhibit improved block resistance.
    Type: Grant
    Filed: November 13, 2003
    Date of Patent: October 23, 2007
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventors: Pavel Holub, Edward Enns McEntire
  • Patent number: 7276555
    Abstract: A method of dispersing pigment using an amide-modified resin or an amide-modified hydrocarbyl moiety, and the resulting pigment concentrate or coating or ink composition.
    Type: Grant
    Filed: May 19, 2003
    Date of Patent: October 2, 2007
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventors: Christopher J. Holmes, Richard K. Winblad, Rudolf Anthonius Maria Venderbosch, Richard Hendrikus Gerrit Brinkhuis
  • Patent number: 7270879
    Abstract: Disclosed herein is a particle comprising a particulate substrate; and a thermoplastic elastomer present on or in the substrate as an amount sufficient to improve the dust suppression of the particle above that which would occur if the thermoplastic elastomer was absent. Disclosed herein is a particle comprising a particulate substrate; and a thermoplastic elastomer, wherein the particle has a compressive strength retention of greater than about 50% as measured by a UCS test and a turbidity of about 10 to 200 NTU after a one hour ball mill test.
    Type: Grant
    Filed: April 15, 2004
    Date of Patent: September 18, 2007
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventor: Avis Lloyd McCrary
  • Patent number: 7262238
    Abstract: The present invention refers to a resin composition comprising an ester compound and a polymer, wherein the ester compound and the polymer are obtainable by reacting a diene, a dienophile and a carboxylic acid. The invention also refers to adhesive compositions comprising the resin composition.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: August 28, 2007
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventors: Robin Winters, Ivo Maria Johannes Erens, Patrick Peter Mario Aarts, John Hazen
  • Patent number: 7262237
    Abstract: Curable urea formaldehyde binder compositions are provided which are useful in coated abrasive and wood engineering applications, in a time released fashion. The time released curable binder compositions include a urea formaldehyde resin and an aryl phosphite in varying concentrations. The curable binder compositions of the present invention provide desirable working times and faster curing times tinder ambient or near ambient conditions.
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: August 28, 2007
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventor: Jimmy Pingao Chen
  • Patent number: 7256226
    Abstract: Storage-stable acrylate-functional alkyd resin compositions are disclosed that include an acrylate-functional alkyd resin and a monofunctional mercaptan such as a chain transfer agent. The compositions disclosed exhibit excellent stability on storage, and have utility as binders for coating compositions useful as low VOC, quick dry paints.
    Type: Grant
    Filed: March 15, 2004
    Date of Patent: August 14, 2007
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventors: Thauming Kuo, Kimberley Carmenia Carico, Rebecca Reid Stockl, Don Leon Morris, Kevin Jude O'Callaghan
  • Patent number: 7238386
    Abstract: A method is provided to manufacture a coated substrate, such as an optical fiber, without undesirable point lumps. The method filters a coating composition while controlling the filtering temperature, pressure drop across a filtering assembly, and filter pore size to achieve a resulting filtration factor not greater than 250,000 s?1. The filtration factor is a function of filtering temperature and pressure drop across the filtering assembly. Typically, the coating composition is filtered by passing the coating composition through one or more filters of the filtering assembly, having an absolute pore size rating in the range from approximately 0.05 to approximately 5 microns, at a temperature less than approximately 105° F. (40° C.), and at a pressure drop ?P across the filtering assembly of at most approximately 80 psig, wherein the ratio of pressure drop (mPa) to viscosity (mPa·s), which is dependent upon filtering temperature, minimizes the filtration factor to ?250,000 s?1.
    Type: Grant
    Filed: April 23, 2003
    Date of Patent: July 3, 2007
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventors: Gregory Lee Workman, II, Don Leon King, Camille Jeanette Rechel, Timothy Edward Myers
  • Patent number: 7189780
    Abstract: A process to produce an acid-treated aqueous dispersion is provided. The process comprises contacting a polymer, a water dispersible polyester, water, and at least one acid-generating compound; wherein said polymer comprises repeating units from at least one fluoroalkyl monomer and optionally, at least one ethylenically unsaturated monomer; wherein the acid-generating compound is at least one acid or acid salt.
    Type: Grant
    Filed: August 12, 2003
    Date of Patent: March 13, 2007
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventors: James Foster Von Schmittou, Darrell Scott Nasser
  • Patent number: 7186769
    Abstract: In this invention, an aqueous dispersion is provided to improve the oil and water repellency of materials. The aqueous dispersion comprises a polymer, at least one water dispersible polyester, and water; wherein the polymer comprises the repeating units from at least one fluoroalkyl monomer and optionally, at least one ethylenically unsaturated monomer. This invention also provides an article coated with the aqueous dispersion.
    Type: Grant
    Filed: August 12, 2003
    Date of Patent: March 6, 2007
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventors: James Foster Von Schmittou, Darrell Scott Nasser
  • Patent number: 7173081
    Abstract: A process is provided to produce an aqueous dispersion wherein the aqueous dispersion enhances the water and oil repellency of materials. The process comprises: 1) contacting at least one fluoroalkyl monomer, at least one water-dispersible polyester, water, and optionally an ethylenically unsaturated monomer to form a pre-emulsion; and 2) polymerizing the pre-emulsion in a polymerization zone in the presence of an initiator to produce the aqueous dispersion. In another embodiment, a process to produce an aqueous dispersion is provided. The process comprises: 1) contacting at least one fluoroalkyl monomer, at least one water-dispersible polyester, water, and optionally an ethylenically unsaturated monomer to form a pre-emulsion; 2) shearing the pre-emulsion to produce a mini-emulsion; and 3) polymerizing the miniemulsion in a polymerization zone to produce the aqueous dispersion.
    Type: Grant
    Filed: August 12, 2003
    Date of Patent: February 6, 2007
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventors: James Foster Von Schmittou, Darrell Scott Nasser
  • Patent number: 7151192
    Abstract: A manufacturing process for the preparation of ?,?-branched alkane carboxylic acids, by reacting a mono-olefin or a precursor thereof, with carbon monoxide in the presence of a strong acid catalyst characterized in that the starting olefin is a dimmer C8 or trimer C12 derived from n-butene, which predominantly comprise 2-butene, that the acid catalyst is composed of BF3/H3PO4 in a molar ratio of BF3:H3PO4 in the range of from 0.5:1.0 to 5.0:1.0, or of CF3SO 3H, that the weight ratio of the catalyst relative to the mono-olefin is in the range of from 1:1 to 10:1, that the reaction is carried out at a temperature in the range of from 60 to 140° C., and with an initial water content in the catalyst system in the range of from 8 to 25 wt %; and vinyl esters and glycidyl esters derived from said carboxylic acids.
    Type: Grant
    Filed: July 2, 2002
    Date of Patent: December 19, 2006
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventors: Hendrik Stichter, Leonardus Petrus, Hans Arie Stil
  • Patent number: 7129286
    Abstract: A process for preparing an acrylic-modified alkyd resin comprising the steps of: d) preparing a sulfonated alkyd resin product; e) preparing an acrylated fatty acid product; and f) reacting the product of step a) and the product of step b) under appropriate polymerization conditions, and for preparing a waterbome composition on the basis thereof as well as products obtainable by those processes.
    Type: Grant
    Filed: November 12, 2001
    Date of Patent: October 31, 2006
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventor: Bernd Kuhneweg
  • Patent number: 7073586
    Abstract: A method of treating an underground formation of an oil reservoir, comprising the sequential steps of (a) contacting the formation with an aqueous medium, (b) contacting the underground formation with a hydrocarbon fluid, (c) contacting the underground formation with a solvent in the form of a glycol ether, (d) contacting the underground formation with a first consolidation constituent solution, mainly comprising a poly epoxy resin, (e) contacting the underground formation with second consolidation constituent substantially homogenous solution mainly comprising a curing agent in a solvent.
    Type: Grant
    Filed: April 29, 2003
    Date of Patent: July 11, 2006
    Assignee: Hexion Specialty Chemicals, Inc.
    Inventors: Jan Dirk Bossaerts, Marc Jozef Rans