Patents Assigned to Hexis AG
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Patent number: 11349142Abstract: A fuel cell module includes fuel cells, a gas supply system, a first accumulator, a second accumulator, and power connection. The fuel cells are arranged in a cell stack having a first axial end and a second axial end. The gas supply system is configured to supply gas for the operation of the fuel cells, the fuel cells being stacked in an axial direction. The first accumulator is arranged at the first axial end of the cell stack. The second accumulator is arranged at the second axial end of the cell stack. The power connection is electrically conductively connected to the second accumulator, and is arranged at the gas supply system. The cell stack is arranged within an insulation sheath and the gas supply system is arranged partly outside the insulation sheath and the power connection is arranged outside the insulation sheath.Type: GrantFiled: December 4, 2015Date of Patent: May 31, 2022Assignee: HEXIS AGInventors: Roland Denzler, Andreas Mai, Fabian Brogle
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Patent number: 11165070Abstract: A method for producing a metallic interconnector for a fuel cell stack, including an air guiding surface with a first gas distributor structure and a fuel gas guiding surface with a second gas distributor structure, the first gas distributor structure and the second gas distributor structure each formed by grooves and webs, includes providing a sheet metal blank, forming the sheet metal blank by a plastic molding process, the first gas distributor structure and the second gas distributor structure being formed in such a manner that the grooves and webs of the first gas distributor structure are arranged complementary to the grooves and webs of the second gas distributor structure at a predeterminable percentage of area of the air guiding surface and the fuel gas guiding surface of at least 50% and at most 99%.Type: GrantFiled: March 2, 2018Date of Patent: November 2, 2021Assignee: HEXIS AGInventors: Andreas Mai, Roland Denzler, Fleischhauer Felix
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Patent number: 11069906Abstract: A fuel cell module includes fuel cells and an air supply system. The fuel cells are arranged in a cell stack. The air supply system is configured to supply air into an air distribution space for operating or cooling the fuel cells. The fuel cells are stacked in an axial direction. The air supply system is configured such that cooling results due to the air supplied to the fuel cells not being of uniform strength in the axial direction. The air supply system is arranged completely radially outside the cell stack.Type: GrantFiled: December 4, 2015Date of Patent: July 20, 2021Assignee: HEXIS AGInventors: Roland Denzler, Andreas Mai, Christoph Meier
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Patent number: 10629931Abstract: In a method for regulating a fuel cell stack (1), a current-voltage characteristic of the fuel cell stack is detected and evaluated to determine an operating point of the fuel cell stack, wherein a current-voltage characteristic of the fuel cell stack (1) is detected at time intervals in operation whose gradient has a minimum, a characteristic value (Rmin) for the minimum of the gradient is respectively determined from the detected current-voltage characteristic and a desired value for the operating point is determined by addition of a predefined offset value (Roffset) to the characteristic value, and wherein the fuel cell stack (1) is regulated by the desired value determined in this manner.Type: GrantFiled: April 26, 2013Date of Patent: April 21, 2020Assignee: Hexis AGInventors: Andreas Mai, Boris Iwanschitz, Markus Linder, Hanspeter Kuratli
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Patent number: 10505207Abstract: A method for the combined controlled regulation of fuel gas-oxygen carriers of a gas operated energy converter plant (15), in particular of a fuel cell plant, is provided in which the mass or volume through flow of the fuel gas (1) and/or of the oxygen carrier (2) is detected in order to regulate the mixing ratio (r) of fuel gas to oxygen carrier. In the method at least two physical parameters of the fuel gas are additionally determined using a micro thermal sensor (3.1, 3.2), for example, the mass flow and/or volume through flow of the fuel gas and the thermal conductivity or thermal capacity of the fuel gas are determined and a desired value for the mixing ratio is determined from the physical parameters which depends on the fuel gas or on the composition of the fuel gas, and which desired value is used for the regulation of the mixing ratio.Type: GrantFiled: May 29, 2014Date of Patent: December 10, 2019Assignee: Hexis AGInventors: Roland Denzler, Philippe Pretre, Andreas Kempe
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Patent number: 10411276Abstract: A device in which an environmental air flow is monitored by a monitoring element and in which a natural gas flow is interrupted by a shut-off element on recognition of an insufficient environmental air flow. To allow a continuous operation of the fuel cell battery the monitoring element is short-circuited by a bridging device and that its operability can thus be checked without the environmental air flow having to be interrupted. This allows a permanent operation of the fuel cell battery.Type: GrantFiled: November 4, 2015Date of Patent: September 10, 2019Assignee: HEXIS AGInventors: Roland Denzler, Ralf Kober, Thomas Gamper
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Patent number: 9543602Abstract: Disclosed is method of operating a fuel cell which can output an electrical maximum power dependent on the operating temperature for a given fuel gas flow, and which exhibits aging in dependence on the operating duration which brings about an increase of the electrical internal resistance with progressive operating duration. In the disclosed method, the starting value (T0) of the operating temperature for a new fuel cell or for a new fuel cell stack is typically smaller than or equal to the operating temperature, at which the electrical maximum power is achieved and the fuel cell or the fuel cell stack is regulated such that the decrease of the output electrical power as a consequence of aging is partly or completely compensated in that the operating temperature (T) of the fuel cell or of the fuel cell stack is increased with progressive aging.Type: GrantFiled: April 18, 2014Date of Patent: January 10, 2017Assignee: HEXIS AGInventors: Andreas Mai, Hanspeter Kuratli
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Patent number: 9178227Abstract: The method serves for the manufacture of contacts between electrochemically active discs (2) and interconnectors (1) in planar high temperature fuel cells. The interconnectors have air-side and gas-side surface profiles (11, 11?) with contact surfaces (100) located on raised portions (10). A layer consisting of a contacting mixture (22, 22?) is respectively applied onto the electrodes (21, 21?) of the electrochemically active discs or onto the contact surfaces. The surface profiles for the electrodes are brought into contact with the applied layer so that, at a working temperature, the raised portions penetrate into this layer. Connections are formed between the contact surfaces and electrically conductive particles in this way and thus form discrete, homogeneously structured connections between the contact surfaces and the electrodes. Finally the medium embedding the particles is removed under thermal part treatments and the discrete connections are solidified.Type: GrantFiled: May 6, 2008Date of Patent: November 3, 2015Assignee: Hexis AGInventors: Boris Iwanschitz, Josef Sfeir, Ueli Weissen, Andreas Kaiser
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Publication number: 20140356751Abstract: A method for the combined controlled regulation of fuel gas-oxygen carriers of a gas operated energy converter plant (15), in particular of a fuel cell plant, is provided in which the mass or volume through flow of the fuel gas (1) and/or of the oxygen carrier (2) is detected in order to regulate the mixing ratio (r) of fuel gas to oxygen carrier. In the method at least two physical parameters of the fuel gas are additionally determined using a micro thermal sensor (3.1, 3.2), for example, the mass flow and/or volume through flow of the fuel gas and the thermal conductivity or thermal capacity of the fuel gas are determined and a desired value for the mixing ratio is determined from the physical parameters which depends on the fuel gas or on the composition of the fuel gas, and which desired value is used for the regulation of the mixing ratio.Type: ApplicationFiled: May 29, 2014Publication date: December 4, 2014Applicants: Hexis AG, MEMS AGInventors: Roland Denzler, Philippe Pretre, Andreas Kempe
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Publication number: 20140315114Abstract: Disclosed is method of operating a fuel cell which can output an electrical maximum power dependent on the operating temperature for a given fuel gas flow, and which exhibits aging in dependence on the operating duration which brings about an increase of the electrical internal resistance with progressive operating duration. In the disclosed method, the starting value (T0) of the operating temperature for a new fuel cell or for a new fuel cell stack is typically smaller than or equal to the operating temperature, at which the electrical maximum power is achieved and the fuel cell or the fuel cell stack is regulated such that the decrease of the output electrical power as a consequence of aging is partly or completely compensated in that the operating temperature (T) of the fuel cell or of the fuel cell stack is increased with progressive aging.Type: ApplicationFiled: April 18, 2014Publication date: October 23, 2014Applicant: Hexis AGInventors: Andreas MAI, Hanspeter KURATLI
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Patent number: 8614029Abstract: The plant with high temperature fuel cells includes a multi component sleeve for a cell stack. Axially directed chambers for an afterburning process are arranged between the periphery of the stack and an outer region of the sleeve. A construction which fixes the chambers includes a corset-like cage, the cross-section of which perpendicular to the stack axis has essentially the shape of a regular polygon. An afterburning chamber is associated with each corner of this polygon. Radial spring forces respectively act from the corners onto the associated chamber and thereby press sealing edges of the chamber onto sealing strips between chamber and stack. The sealing edges form a closed edge of a trough-like space. The trough-like space is connected via a narrow passage with an axial collection passage for exhaust gas. This collecting passage is arranged between the trough-like space and the corner.Type: GrantFiled: February 14, 2006Date of Patent: December 24, 2013Assignee: Sulzer Hexis AGInventors: Konstantin Daremas, Thomas Zaehringer
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Patent number: 8586251Abstract: A fuel cell system (1) having a cell stack (2) for the carrying out of electrochemical reactions is provided which is provided with inlets (3a, 3b) for an oxidant (5) and for fuel gas (6) and with outlets (4a, 4b) for exhaust gases (7a, 7b). The fuel cell system (1) additionally includes an apparatus (10) having a gas-permeable structure which contains a substance which reacts with gaseous chromium species, wherein the apparatus is in communication with at least one of the outlets to direct exhaust gases through the apparatus and to separate chromium species which are carried along by the exhaust gases.Type: GrantFiled: February 1, 2011Date of Patent: November 19, 2013Assignee: Hexis AGInventors: Andreas Mai, Dirk Haberstock, Roland Denzler, Josef Sfeir
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Publication number: 20130288147Abstract: In a method for regulating a fuel cell stack (1), a current-voltage characteristic of the fuel cell stack is detected and evaluated to determine an operating point of the fuel cell stack, wherein a current-voltage characteristic of the fuel cell stack (1) is detected at time intervals in operation whose gradient has a minimum, a characteristic value (Rmin) for the minimum of the gradient is respectively determined from the detected current-voltage characteristic and a desired value for the operating point is determined by addition of a predefined offset value (Roffset) to the characteristic value, and wherein the fuel cell stack (1) is regulated by the desired value determined in this manner.Type: ApplicationFiled: April 26, 2013Publication date: October 31, 2013Applicant: Hexis AGInventors: Andreas MAI, Boris Iwanschitz, Markus Linder, Hanspeter Kuratli
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Patent number: 8535848Abstract: The structured body intended for use for an anode (1) in fuel cells, includes a structure formed by macro-pores and an electrode material. The macro-pores form communicating spaces which are produced by using pore forming materials. The electrode material includes skeleton-like or net-like connected structures of particles which are connected by sintering and which form two reticular systems which interengage: a first reticular system made of ceramic material and a second reticular system which contains metals to effect an electrical conductivity. The electrode material has the properties so that, with a multiple change between oxidizing and reducing conditions, substantially no major property changes occur in the ceramic reticular system, and an oxidization or reduction of the metals occurs in the second reticular system.Type: GrantFiled: January 9, 2012Date of Patent: September 17, 2013Assignee: Hexis AGInventors: Gilles Robert, Andreas Franz-Josef Kaiser, Emad Batawi
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Patent number: 8507149Abstract: The plant (1) with high-temperature fuel cells (7) includes a clamping device for a cell stack (5) and axially aligned chambers (7) for an after-burning. Clamping bars (60) of the clamping device are disposed between the afterburning chambers. Exhaust gas passages connect the after-burning chambers to a heat exchanger (20a) acting as a heat sink. A clamping element (62) of the clamping device is in heat conducting connection with the heat exchanger. Compression springs (63) are respectively mounted on the clamping bars between an end of the clamping bar and a lug (622) of the clamping element. In this arrangement they exert a clamping force onto the clamping bars. The compression springs are shielded by the clamping element from the cell stack so that, thanks to the heat sink, the compression springs are only exposed to moderate temperature at which the clamping force is maintained.Type: GrantFiled: February 14, 2006Date of Patent: August 13, 2013Assignee: Hexis AGInventors: Alexander Schuler, Dirk Haberstock, Roland Denzler, Michael Tamas, Jeannette Clifford
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Patent number: 8366906Abstract: A lambda probe in which a measuring point for oxygen in a sensor is connected via a diffusion gap with a reaction chamber. The reaction chamber drives oxygen along the diffusion gap. A desired oxygen partial pressure is set in the reaction chamber. The pump current, which is proportional to the strength of the stream of oxygen driven along the diffusion gap, can be used as a measurement for the partial pressure of the residual oxygen in the exhaust gas during a normal operating phase. The lambda probe can be operated for test purposes intermittently in a high or low phase, in which the oxygen partial pressure in the reaction chamber is a minimum or maximum value. While changing between the operating phases, by comparing the pump currents with empirical values, conclusions with regard to the ability of the probe to function can be derived.Type: GrantFiled: September 11, 2008Date of Patent: February 5, 2013Assignee: Sulzer Hexis AGInventors: Philip Holoch, Thomas Gamper
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Publication number: 20120141916Abstract: The structured body intended for use for an anode (1) in fuel cells, includes a structure formed by macro-pores and an electrode material. The macro-pores form communicating spaces which are produced by using pore forming materials. The electrode material includes skeleton-like or net-like connected structures of particles which are connected by sintering and which form two reticular systems which interengage: a first reticular system made of ceramic material and a second reticular system which contains metals to effect an electrical conductivity. The electrode material has the properties so that, with a multiple change between oxidizing and reducing conditions, substantially no major property changes occur in the ceramic reticular system, and an oxidization or reduction of the metals occurs in the second reticular system.Type: ApplicationFiled: January 9, 2012Publication date: June 7, 2012Applicant: Sulzer Hexis AGInventors: Gilles Robert, Andreas Franz-Josef Kaiser, Emad Batawi
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Patent number: 8114551Abstract: The structured body intended for use for an anode (1) in fuel cells, includes a structure formed by macro-pores and an electrode material. The macro-pores form communicating spaces which are produced by using pore forming materials. The electrode material includes skeleton-like or net-like connected structures of particles which are connected by sintering and which form two reticular systems which interengage: a first reticular system made of ceramic material and a second reticular system which contains metals to effect an electrical conductivity. The electrode material has the properties so that, with a multiple change between oxidizing and reducing conditions, substantially no major property changes occur in the ceramic reticular system, and an oxidization or reduction of the metals occurs in the second reticular system.Type: GrantFiled: January 31, 2003Date of Patent: February 14, 2012Assignee: Sulzer Hexis AGInventors: Gilles Robert, Andreas Franz-Josef Kaiser, Emad Batawi
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Publication number: 20110200894Abstract: A fuel cell system (1) having a cell stack (2) for the carrying out of electrochemical reactions is provided which is provided with inlets (3a, 3b) for an oxidant (5) and for fuel gas (6) and with outlets (4a, 4b) for exhaust gases (7a, 7b). The fuel cell system (1) additionally includes an apparatus (10) having a gas-permeable structure which contains a substance which reacts with gaseous chromium species, wherein the apparatus is in communication with at least one of the outlets to direct exhaust gases through the apparatus and to separate chromium species which are carried along by the exhaust gases.Type: ApplicationFiled: February 1, 2011Publication date: August 18, 2011Applicant: Hexis AGInventors: Andreas Mai, Dirk Haberstock, Roland Denzler, Josef Sfeir
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Patent number: 7691524Abstract: Anode material for a fuel cell which is to be operated at a high temperature above 700° C.Type: GrantFiled: March 15, 2005Date of Patent: April 6, 2010Assignee: Hexis AGInventors: Gilles Robert, Andreas Franz-Josef Kaiser, Emad Batawi