Abstract: Phosphoric acid, essentially free from impurities, is prepared by reacting aqueous hydrofluoric acid with phosphate in particles of calcium bearing phosphate rock to form a calcium fluoride pseudomorph solid from which filter-grade phosphoric acid is separated. By reacting the pseudomorph solid with sulfuric acid and thermally treating the reaction product, the HF can be liberated and recycled back to the reaction step of the process. All of the impurities from the phosphate rock are contained in the resulting CaSO4.
Type:
Grant
Filed:
June 9, 2000
Date of Patent:
January 13, 2004
Assignee:
HF Extraction, LLC
Inventors:
Samuel Franklin Sweat, Claude E. Breed, Kenneth E. McGill