Patents Assigned to Hille & Muller GmbH
  • Patent number: 11732324
    Abstract: Method of producing a low interfacial contact resistance material for use in batteries or connectors and a low interfacial contact resistance material for use in batteries or connectors produced thereby.
    Type: Grant
    Filed: July 10, 2018
    Date of Patent: August 22, 2023
    Assignee: HILLE & MÜLLER GMBH
    Inventors: Ernst Wilhelm Vom Bey, Marcel Onink, Ken-Dominic Flechtner, Maurice Jean Robert Jansen
  • Publication number: 20210087648
    Abstract: Method of producing a low interfacial contact resistance material for use in batteries or connectors and a low interfacial contact resistance material for use in batteries or connectors produced thereby.
    Type: Application
    Filed: July 10, 2018
    Publication date: March 25, 2021
    Applicant: HILLE & MÜLLER GMBH
    Inventors: Ernst Wilhelm VOM BEY, Marcel ONINK, Ken-Dominic FLECHTNER, Maurice Jean, Robert JANSEN
  • Patent number: 10337388
    Abstract: A method for producing a corrosion resistant metal substrate and corrosion resistant metal substrate provided thereby. The method involves forming a plated substrate including a metal substrate provided with a nickel layer or with a nickel and cobalt layer followed by electrodepositing a molybdenum oxide layer from an aqueous solution onto the plated substrate, which is subsequently subjected to an annealing step in a reducing atmosphere to reduce the molybdenum oxide in the molybdenum oxide layer to molybdenum metal in a reduction annealing step and to form a diffusion layer which contains nickel and molybdenum, and optionally cobalt.
    Type: Grant
    Filed: February 15, 2018
    Date of Patent: July 2, 2019
    Assignee: HILLE & MÜLLER GMBH
    Inventors: Annette Borisch, Philip Schmitz, Ken-Dominic Flechtner, Martin Schwagereit
  • Publication number: 20180171858
    Abstract: A method for producing a corrosion resistant metal substrate and corrosion resistant metal substrate provided thereby. The method involves forming a plated substrate including a metal substrate provided with a nickel layer or with a nickel and cobalt layer followed by electrodepositing a molybdenum oxide layer from an aqueous solution onto the plated substrate, which is subsequently subjected to an annealing step in a reducing atmosphere to reduce the molybdenum oxide in the molybdenum oxide layer to molybdenum metal in a reduction annealing step and to form a diffusion layer which contains nickel and molybdenum, and optionally cobalt.
    Type: Application
    Filed: February 15, 2018
    Publication date: June 21, 2018
    Applicant: Hille & Müller GmbH
    Inventors: Annette BORISCH, Philip SCHMITZ, Ken-Dominic FLECHTNER, Martin SCHWAGEREIT
  • Patent number: 9951674
    Abstract: A method for producing a corrosion resistant metal substrate and corrosion resistant metal substrate provided thereby. The method involves forming a plated substrate including a metal substrate provided with a nickel layer or with a nickel and cobalt layer followed by electrodepositing a molybdenum oxide layer from an aqueous solution onto the plated substrate, which is subsequently subjected to an annealing step in a reducing atmosphere to reduce the molybdenum oxide in the molybdenum oxide layer to molybdenum metal in a reduction annealing step and to form a diffusion layer which contains nickel and molybdenum, and optionally cobalt.
    Type: Grant
    Filed: April 19, 2016
    Date of Patent: April 24, 2018
    Assignee: HILLE & MÜLLER GMBH
    Inventors: Annette Borisch, Philip Schmitz, Ken-Dominic Flechtner, Martin Schwagereit
  • Patent number: 8551316
    Abstract: This invention relates to a method for producing a metallic coating layer comprising nickel and molybdenum on an electrically conductive substrate by electrodeposition from an aqueous solution including nickel salts, gluconate anions and citrate anions wherein the substrate acts as the cathode and wherein molybdate is added and wherein the pH of the aqueous solution is adjusted between 5.0 and 8.5. The invention also relates to an electrically conductive substrate provided with such a metallic coating layer electrodeposited from the aqueous solution.
    Type: Grant
    Filed: July 11, 2008
    Date of Patent: October 8, 2013
    Assignee: Hille & Muller GmbH
    Inventors: Jacques Hubert Olga Joseph Wijenberg, Daniël Adriaan De Vreugd, Ilja Portegies Zwart
  • Publication number: 20100167087
    Abstract: This invention relates to a method for producing a metallic coating layer comprising nickel and molybdenum on an electrically conductive substrate by electrodeposition from an aqueous solution including nickel salts, gluconate anions and citrate anions wherein the substrate acts as the cathode and wherein molybdate is added and wherein the pH of the aqueous solution is adjusted between 5.0 and 8.5. The invention also relates to an electrically conductive substrate provided with such a metallic coating layer electrodeposited from the aqueous solution.
    Type: Application
    Filed: July 11, 2008
    Publication date: July 1, 2010
    Applicant: Hille & muller GMBH
    Inventors: Jacques Hubert Olga Joseph Wijenberg, Daniël Adriaan De Vreugd, Ilja Portegies Zwart
  • Publication number: 20090038718
    Abstract: A process for manufacturing a containment device including: providing steel slab including (in wt. %) C: 0.05%-0.4%; Si: ?2.0%; Mn: ?2.0%; P: ?0.1%; N: ?200 ppm; remainder iron and inevitable impurities; hot rolling the slab to steel strip after reheating the slab, or utilizing the casting heat by hot-charging the slab, or by direct rolling the slab after casting, followed by cooling the strip to coiling temperature and coiling; cold rolling the strip at between 40 and 95% thickness reduction to form cold-rolled strip; continuous annealing by reheating to temperature above Ac1, homogenising at least 5 seconds, followed by rapid cooling; producing the device. The device has steel at least 10 vol. % martensite and/or bainite and reduced properties of anisotropy. Containment device manufactured by the process and producing isolation barrier material for high temperature and/or pressure sealing for containment devices are also disclosed.
    Type: Application
    Filed: October 26, 2005
    Publication date: February 12, 2009
    Applicant: HILLE & MÜLLER GMBH
    Inventors: Markus Helmut Maria Dotsch, Ruediger Hartung, Marcel Onink
  • Publication number: 20070082215
    Abstract: The invention relates to a double walled metal tube comprising a tubular roll formed metal band having a brazing layer between the metal layers of the tubular roll formed metal band, wherein the brazing layer consists of a copper alloy. According to the invention, the copper alloy is a copper-tin alloy, wherein the copper-tin alloy contains 3-12 wt % tin. The invention also relates to a metal band for forming such a double walled metal tube and to a metal strip for producing such metal bands, and to a method of coating a metal band and strip.
    Type: Application
    Filed: June 16, 2004
    Publication date: April 12, 2007
    Applicant: Hille & Müller GMBH
    Inventors: Dieter Junkers, Peter Boehmer
  • Patent number: 7179541
    Abstract: A method for heat treatment of a cold rolled strip with a surface coating of Ni and/or Co and incorporated non-metallic elements C and/or S, if need be with the addition of Fe, In, Pd, Au and/or Bi, whereby the cold rolled strip has a low carbon content. Since the compounds of C, S, N and P deposited on the grain boundaries bring about the most micro-cracks with the surface coating metal if no recrystallization takes place, the temperature of the heat treatment should be selected lower than the recrystallization temperature and higher than the precipitation temperature. With a recrystallization, the grain sizes would easily attain the thickness of the coating so that the embrittled compounds would migrate with the grain boundaries out of the coating. Due to the choice of temperature of the heat treatment of the surface coating of the invention, in contrast, an optimal embrittlement of the grain boundaries is guaranteed, which is especially advantageous in the manufacture of battery cans.
    Type: Grant
    Filed: June 12, 2002
    Date of Patent: February 20, 2007
    Assignee: Hille & Muller GmbH
    Inventors: Werner Olberding, Beate Monscheuer, Claudia Dahmen, Karlfried Pfeifenbring
  • Publication number: 20060266444
    Abstract: Disclosed is a cold-rolled strip, at least one face of which is provided with an electrolytically applied coating, preferably to be used for producing battery shells by means of deep drawing and/or ironing. The electrolytically applied coating comprises two layers, i.e. a hard and brittle bright nickel layer and a cobalt-containing layer that is applied thereupon. The aim of the invention is to be able to produce such a cold-rolled strip in a more economic manner while a battery shell produced by reshaping said cold-rolled strip is to have good contact resistance to the electrolyte and good storage stability. Said aim is achieved by using a matte cobalt layer which is removed from an electrolyte bath without adding brighteners, or a matte cobalt alloy layer as the cobalt-containing layer. Also disclosed are a method for electrolytically coating a cold-rolled strip and a battery shell which is produced from such a cold-rolled strip by means of a reshaping process.
    Type: Application
    Filed: April 8, 2004
    Publication date: November 30, 2006
    Applicant: HILLE & MULLER GMBH
    Inventors: Helmut Kosslers, Tilman Strotbek
  • Publication number: 20060094309
    Abstract: Electrical connector or electrical switching element including a metallic core and a galvanically deposited metal containing coating layer is presented. The metal containing coating layer is deposited by electrolytic composite plating and the coating layer includes a metal matrix and distributed therein particles selected from the group of particles having electrically conductive properties, particles having lubricating properties, particles having wear resistance properties and particles having properties of increasing the temperature durability or combinations of particles from those groups. The electrical connector or electrical switching element has been made from a continuously coated metal strip comprising a metallic core and a galvanically deposited metal containing coating layer. A continuously coated metal strip for manufacturing such electrical connectors is also presented.
    Type: Application
    Filed: June 5, 2003
    Publication date: May 4, 2006
    Applicant: Hille & Muller GMBH
    Inventors: Johannes Henricus Holtkamp, Martin Giesler, Jean-Pierre Paul Julien Celis