Abstract: Disclosed is a normally solid, high molecular weight, non-linear, substantially gel-free, propylene polymer material characterized by high melt strength due to strain hardening which is believed to be caused by free-end long chain branches of the molecular chains forming the polymer.Also disclosed is a process for making the polymer by high energy radiation of a normally solid, high molecular weight, linear, propylene polymer in a reduced active oxygen environment, maintaining the irradiated material in such environment for a specific period of time, and then deactivating free radicals in the material.Further disclosed is the use of the strain hardening polymer in extensional flow operations such as, for example, extrusion coating, film production, foaming and thermoforming.
Type:
Grant
Filed:
July 15, 1993
Date of Patent:
May 9, 1995
Assignee:
Himont Incorporated
Inventors:
Anthony J. DeNicola, Jr., Jeanine A. Smith, Massimo Felloni
Abstract: Disclosed are graft copolymers of polyolefins and a method of preparing said graft copolymers. The method comprises irradiating a mass of olefin polymer particles and thereafter treating the mass of particles with a vinyl monomer in liquid form. A nonoxidizing environment is maintained throughout the process while free radicals produced in the olefin polymer by the irradiation are present, thereby preventing degradation of the polymer. In a final step, residual free radicals are deactivated, and any unreacted monomer is removed.
Type:
Grant
Filed:
November 6, 1992
Date of Patent:
May 2, 1995
Assignee:
Himont Incorporated
Inventors:
Paolo Galli, Anthony J. DeNicola, Jr., Jeanine A. Smith
Abstract: The present invention relates to a process for the production of homopolymers of ethylene and copolymers of ethylene with olefins CH.sub.2 .dbd.CHR, wherein R is an alkyl or aryl radical having a number of carbon atoms of from 1 to 10, and having a density greater than 0.86 g/cm.sup.3, comprising at least one (co)polymerization step in the gas phase, in the presence of an active catalyst obtained from a titanium compound supported on a magnesium halide in active form and an Al-alkyl compound. The process is characterized in that a small amount compared with the polymer is fed to the gas-phase reactor of a polyfunctional compound having at least two groups, the same or different, capable of reacting with the alkyl aluminum compound and capable of selectively inhibiting the reactivity of the polymer particle fines compared with the average granulometric size of the polymer present in the bed of a gas-phase polymerization reactor.
Abstract: Disclosed are calenderable blends consisting essentially of (A) a heterophasic olefin polymer composition and (B) a broad molecular weight distribution propylene polymer material, and film or sheet materials thereof.
Abstract: Disclosed are blends comprising a graft copolymer of a propylene polymer material, a graft copolymer of olefin rubber material, and optionally an ungrafted olefin rubber, wherein the grafting monomers are selected from the group consisting of (i) aromatic vinyl compounds, (ii) acrylic compounds, (iii) mixtures of (i) and (ii), and (iv) other copolymerizable monomers with at least one (i) or at least one (ii) or mixtures of at least one (i) and at least one (ii).
Type:
Grant
Filed:
March 6, 1992
Date of Patent:
March 14, 1995
Assignee:
Himont Incorporated
Inventors:
Anthony J. DeNicola, Jr., Paul D. Tatarka
Abstract: Syndiotactic polymers of alpha-olefins selected from the group consisting of 1-butene, 4-methyl-1-pentene and 4-methyl-1-hexene and a method of preparation thereof by polymerizing said olefins with catalysts obtained from specific Zr or Hf cyclopentadienyl compounds and aluminoxane compounds.
Type:
Grant
Filed:
June 1, 1993
Date of Patent:
February 21, 1995
Assignee:
Himont Incorporated
Inventors:
Enrico Albizzati, Luigi Resconi, Adolfo Zambelli
Abstract: Process for the preparation of LLDPE with improved processability by gas phase polymerization performed in two or more reactors, wherein, whatever the order, in one of the reactors a mixture of ethylene and an alpha-olefin CH.sub.2 .dbd.CHR, where R is an alkyl having 1-10 carbon atoms, is polymerized to yield a copolymer containing up to about 20% by mole of the alpha-olefin, and in another reactor a mixture of propylene and an alpha-olefin CH.sub.2 .dbd.CHR', where R' is an alkyl radical having 2-10 carbon atoms, is polymerized to yield a copolymer containing from 5 to 40% by weight of said olefin, in an amount of 5-30% with respect to the total polymer weight and the polymer-catalyst system obtained in the first reactor is fed to the other reactors.
Abstract: Preparation of diethers of the formula ##STR1## wherein R is an alkyl, cycloalkyl, aryl, or aralkyl radical, by formation of an unsaturated aldehyde of the formula ##STR2## wherein R is as defined above, by means of an aldol condensation reaction, reduction of said aldehyde to form the corresponding saturated compound, transformation of the saturated compound into the corresponding diol, and consequent methylation of the diol into diether.
Abstract: Disclosed is a radiation resistant propylene polymer composition comprising a propylene polymer material and generally from about 0.1 to about 5 pph, of the propylene polymer material, of a rosin material. A hindered amine is present when the concentration of the rosin material is low, i.e., below 1.0 pph. At higher concentrations of rosin material, the hindered amine is optional. Radiation sterilized articles in which at least part of the material construction thereof comprises said radiation resistant propylene polymer composition are also disclosed.
Abstract: Disclosed are resin compositions comprising (a) a polyphenylene ether resin, a styrene resin or mixtures thereof, (b) a styrenic grafted propylene polymer material, (c) one or more monoalkenyl aromatic hydrocarbon-conjugated diene block copolymers, hydrogenated products thereof or mixtures thereof, and optionally, (d) a propylene polymer material.
Type:
Grant
Filed:
February 25, 1994
Date of Patent:
December 6, 1994
Assignee:
Himont Incorporated
Inventors:
Anthony J. DeNicola, Jr., Ralph A. Guyer
Abstract: Disclosed is a propylene polymer composition consisting essentially of (A) a propylene polymer resin and (B) from 0.05 to 0.2 parts of a normally solid, high molecular weight, gel-free, propylene polymer material having (1) a branching index of less than 1 and significant strain hardening elongational viscosity, or (2) at least (a) either z-average molecular weight M.sub.z of at least 1.0.times.10.sup.6 or a ratio of the z-average molecular weight M.sub.z to weight average molecular weight M.sub.w, M.sub.z /M.sub.w, of at least 3.0 and (b) either equilibrium compliance J.sub.eo of at least 12.times.10.sup.-5 cm.sup.2 /dyne or recoverable shear strain per unit stress Sr/S of at least 5.times.10.sup.-5 cm.sup.2 /dyne at 1 sec.sup.-1.
Abstract: Disclosed are polymers and copolymers of CH.sub.2 .dbd.CHR alpha olefins where R is hydrogen or a 1-6 carbon atom alkyl radical, containing in the chain from 0.1 to 40 mole % of monomeric units ##STR1## where X is selected from the group consisting of (CH.sub.2).sub.r CH.sub.2 CH.sub.2 Y ##STR2## where r=0-10, Y is a halogen atom, R.sup.1 is a hydrocarbon radical with 1-18 carbon atoms.
Abstract: Articles comprising a nonwoven polypropylene fabric bonded directly to a film of a heterophasic polymer composition comprising:A) a polypropylene homopolymer, or a crystalline copolymer of propylene with ethylene and/or another .alpha.-olefinB) an ethylene-propylene copolymer, andC) a copolymer of ethylene with propylene and/or another .alpha.-olefin, and optionally a diene.
Abstract: Disclosed are polyolefin compositions comprising (A) a propylene homopolymer or a crystalline copolymer of propylene and ethylene or a C.sub.4-8 alpha-olefin, (B) an olefin polymer composition, and optionally either, (C) a propylene polymer composition or (D) an olefin polymer rubber.
Type:
Grant
Filed:
August 30, 1993
Date of Patent:
November 1, 1994
Assignee:
HIMONT Incorporated
Inventors:
Douglas D. Mosier, Mark E. Barrera, Stephen M. Dwyer
Abstract: A mixture containing bitumen and a polymer composition, characterized in that the polymer composition comprises:A) 10-40 parts by weight of an isotactic propylene homopolymer, or a random copolymer of propylene with ethylene and/or a C.sub.4 -C.sub.10 .alpha.-olefin;B) 0-20 parts by weight of a copolymer fraction containing ethylene, which is insoluble in xylene at ambient temperature;C) 50-80 parts by weight of a copolymer fraction of ethylene with propylene and/or C.sub.4 -C.sub.10 .alpha.-olefin, said copolymer fraction being soluble in xylene at ambient temperature and having an intrinsic viscosity greater than 1.5 and up to 2.2 dl/g and having 20 to 45 wt. % ethylene.
Abstract: Polymers and copolymers of L(+) and D(-) lactic acid, with high molecular weight and in the absence of catalysts, are prepared by upgrading low molecular weight polymers in the solid state.
Abstract: Disclosed are fibers comprising a graft copolymer consisting of a propylene polymer material backbone having graft polymerized thereto an ethylenically unsaturated monomer(s) or a blend of at least two of said graft copolymers.
Type:
Grant
Filed:
July 30, 1991
Date of Patent:
September 20, 1994
Assignee:
Himont Incorporated
Inventors:
Anthony J. DeNicola, Jr., Rosemary C. Sams