Patents Assigned to Hitchi Chemical Co.
  • Patent number: 4748228
    Abstract: An organic silicon-terminated polyimide precursor having a very stable solution viscosity is produced by polycondensing 100 parts by weight of a mixture composed of 90 to 99.5% by mole of an organic diamine represented by the following general formula (I) and 10 to 0.5% by weight by mole of an organic silyl represented by the following general formula (II): ##STR1## wherein R.sup.1 and R.sup.2 are divalent organic groups; R.sup.3 and R.sup.4 are monovalent organic groups; m is 0, 1, 2, or 3, with an organic tetracarboxylic acid dianhydride represented by the following general formula (III) in a molar amount corresponding to the 100 parts by weight of the mixture of the organic diamine and the organic silyl represented by the said general formulae (I) and (II), respectively, in an organic polar solvent at 0.degree. to 40.degree. C., thereby obtaining a solution of organic silicon-terminated polyimide precursor, and heating the solution at 50.degree. to 80.degree. C.: ##STR2## wherein R.sup.
    Type: Grant
    Filed: May 14, 1986
    Date of Patent: May 31, 1988
    Assignees: Hitachi. Ltd., Hitchi Chemical Co.
    Inventors: Fusaji Shoji, Haruhiko Matsuyama, Akio Fujiwara, Fumio Kataoka, Teruji Aizawa